X-ray Broadening and Optical Properties of NiO Nanoparticles Prepared via Co-precipitation Method by Varying Temperature

2017 ◽  
Vol 42 (4) ◽  
pp. 2345-2348 ◽  
Author(s):  
L. Umaralikhan ◽  
M. Jamal Mohamed Jaffar
2014 ◽  
Vol 1033-1034 ◽  
pp. 1172-1175
Author(s):  
Li Ping Lin ◽  
Feng Hua Huang ◽  
Pei Feng Chen

The water-soluble ZnSe:Ag quantum dots were synthesized in aqueous medium by chemical co-precipitation method with L-cysteine as surface modifier. The crystal structure and optical properties of the obtained ZnSe:Ag quantum dots have been characterized by X-ray power diffraction, infrared spectrum, UV-Vis absorption spectrum and photoluminescence spectrum. Results indicate that ZnSe:Ag quantum dots belong to the cubic blende structure and have good fluorescent characteristics. The L-cysteine modified on the surface of ZnSe:Ag quantum dots renders the quantum dots water-soluble, biocompatible.


2014 ◽  
Vol 879 ◽  
pp. 155-163 ◽  
Author(s):  
Rahizana Mohd Ibrahim ◽  
Markom Masturah ◽  
Huda Abdullah

Nanoparticles of Zn1-xFexS ( x=0.0,0.1,0.2 and 0.3) were prepared by chemical co-precipitation method from homogenous solution of zinc and ferum salt at room temperature with controlled parameter. These nanoparticles were sterically stabilized using Sodium Hexamethaphospate (SHMP). Here, a study of the effect of Fe doping on structure, morphological and optical properties of nanoparticles was undertaken. Elemental analysis, morphological and optical properties have been investigated by Fourier-Transform-Infrared spectroscopy (FT-IR), X-Ray Fluorescence (XRF), Field Emmision Scanning Electron Microscopy (FESEM), X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM) and UV-Visible Spectroscopy. FTIR measurement confirmed the presence of SHMP in the nanoparticles structure with the FESEM images depicting considerable less agglomeration of particles with the presence of SHMP. While XRF results confirm the presence of Fe2+ ion as prepared in the experiment. The particles sizes of the nanoparticles lay in the range of 2-10 nm obtained from the TEM image were in agreement with the XRD results. The absorption edge shifted to lower wavelengths with an increase in Fe concentration shown in the UV-Vis spectroscopy. The band gap energy value was in the range of 4.95 5.15 eV. The blueshift is attributed to the quantum confinement effect.


Crystals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 124
Author(s):  
Srihasam Saiganesh ◽  
Thyagarajan Krishnan ◽  
Golla Narasimha ◽  
Hesham S. Almoallim ◽  
Sulaiman Ali Alhari ◽  
...  

Over the past few years, the photogenic fabrication of metal oxide nanoparticles has attracted considerable attention, owing to the simple, eco-friendly, and non-toxic procedure. Herein, we fabricated NiO nanoparticles and altered their optical properties by doping with a rare earth element (lanthanum) using Sesbania grandiflora broth for antibacterial applications. The doping of lanthanum with NiO was systematically studied. The optical properties of the prepared nanomaterials were investigated through UV-Vis diffuse reflectance spectra (UV-DRS) analysis, and their structures were studied using X-ray diffraction analysis. The morphological features of the prepared nanomaterials were examined by scanning electron microscopy and transmission electron microscopy, their elemental structure was analyzed by energy-dispersive X-ray spectral analysis, and their oxidation states were analyzed by X-ray photoelectron spectroscopy. Furthermore, the antibacterial action of NiO and La-doped NiO nanoparticles was studied by the zone of inhibition method for Gram-negative and Gram-positive bacterial strains such as Escherichia coli and Bacillus sublitis. It was evident from the obtained results that the optimized compound NiOLa-04 performed better than the other prepared compounds. To the best of our knowledge, this is the first report on the phytosynthetic fabrication of rare-earth ion Lanthanum (La3+)-doped Nickel Oxide (NiO) nanoparticles and their anti-microbial studies.


Crystals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 832
Author(s):  
Edna X. Figueroa-Rosales ◽  
Javier Martínez-Juárez ◽  
Esmeralda García-Díaz ◽  
Daniel Hernández-Cruz ◽  
Sergio A. Sabinas-Hernández ◽  
...  

Hydroxyapatite (HAp) and hydroxyapatite/multi-walled carbon nanotube (MWCNT) composites were obtained by the co-precipitation method, followed by ultrasound-assisted and microwave radiation and thermal treatment at 250 °C. X-ray diffraction (XRD) confirmed the presence of a hexagonal phase in all the samples, while Fourier-transform infrared (FTIR) spectroscopy elucidated the interaction between HAp and MWCNTs. The photoluminescent technique revealed that HAp and the composite with non-functionalized MWCNTs present a blue luminescence, while the composite with functionalized MWCNTs, under UV-vis radiation shows an intense white emission. These findings allowed presentation of a proposal for the use of HAp and HAp with functionalized MWCNTs as potential materials for optoelectronic and medical applications.


Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 805
Author(s):  
Saif Ullah Khan ◽  
Rumman Zaidi ◽  
Feroz Shaik ◽  
Izharul Haq Farooqi ◽  
Ameer Azam ◽  
...  

Nanotechnology has received much attention in treating contaminated waters. In the present study, a facile co-precipitation method was employed to synthesize a novel iron and magnesium based binary metal oxide using a stoichiometrically fixed amount of FeNO3.9H2O and MgNO3.6H2O in a proportion of molar concentration 1:1 and was later evaluated in removing As (III) from contaminated waters. Characterization of the prepared nanomaterial was done using X-ray diffraction (XRD), scanning electron microscopy (SEM), Energy Dispersive X-Ray Analysis (EDAX) and ultraviolet–visible spectrophotometry (UV-VIS). Experimental studies on batch scale were carried out, examining the effect of varying initial concentrations of metal, adsorbent dosage, application time and initial pH on removal efficiency. Arsenic removal increased on increasing adsorbent dosage (0.1–1 g/L) but trend reversed on increasing initial arsenic concentration attaining qmax of 263.20 mg/g. Adsorption was quite efficient in pH range 4–8. Freundlich fitted better for adsorption isotherm along with following Pseudo-2nd order kinetics. The reusability and effect of co-existing ions on arsenic adsorption, namely SO42−, CO32− and PO43− were also explored with reusability in 1st and 2nd cycles attained adsorptive removal up to 77% and 64% respectively. The prepared nano-adsorbent showed promising results in terms of high arsenic uptake (qmax of 263.20 mg/g) along with facile and cost-effective synthesis. Thus, the co-precipitation technique used in this work is a simple one step procedure without any use of any precursor as compared to most of the other procedures used for synthesis.


2015 ◽  
Vol 827 ◽  
pp. 19-24 ◽  
Author(s):  
Nur Afifah ◽  
Nadia Febiana Djaja ◽  
Rosari Saleh

In this study, the photocatalytic activity of pure Fe- doped ZnO and Fe- doped ZnO/Montmorillonite nanocomposite has been investigated for the degradation of malachite green under UV light irradiation. Both photocatalysts were synthesized using co-precipitation method and characterized by X-ray diffraction, energy dispersive X-ray spectroscopy, Fourier-transform infrared absorption, and electron spin resonance. The results showed that the photocatalytic efficiency is better in the presence of montmorillonite compared to pure Fe- doped ZnO. To detect the possible reactive species involved in degradation of organic dyes control experiments with introducing scavengers into the solution of organic dyes were carried out. It is found that electron plays an important role in the degradation of malachite green.


2011 ◽  
Vol 311-313 ◽  
pp. 1713-1716 ◽  
Author(s):  
Yan Rong Sun ◽  
Tao Fan ◽  
Chang An Wang ◽  
Li Guo Ma ◽  
Feng Liu

Nano-hydroxyapatite with different morphology was synthesized by the co-precipitation method coupled with biomineralization using Ca(NO3)2•4H2O and (NH4)2HPO4 as reagents, adding chondroitin sulfate, agarose and aspartic acid as template. The structure and morphology of the prepared powders were characterized by X-ray diffraction (XRD) and transmission electron microscope (TEM).


2015 ◽  
Vol 645-646 ◽  
pp. 1339-1344 ◽  
Author(s):  
Yan Ting Yin ◽  
Qing Hua Chen ◽  
Ting Ting Yan ◽  
Qing Hua Chen

The objective of this study was to develop a novel silica modified large-sized hydroxyapatite whiskers with improved properties for use in bone repair applications. Large-sized whiskers with a mean length of 250μm were obtained by a hydrothermal co-precipitation method at 150°C, 7.5Mpa in high-pressure reactor. Silica modified hydroxyapatite whiskers were prepared by dissolving TEOS in ethanol solution, then sintering with hydroxyapatite. The compositional and morphological properties of prepared whiskers were studied by means of x-ray diffraction (XRD), Fouier transform infrared (FT-IR), scanning electron microscopy (SEM). The results indicated the evidence of nanosilicon dioxide particles on the surface of HAP whiskers. The size of nanosilicon dioxide particles depends on dropping and stirring rate. Hence, this new type of silica modified large-sized hydroxyapatite whiskers is a valuable candidate for biomedical applications.Key words: hydroxyapatite, hydrothermal co-precipitation, surface modified, whiskers


2019 ◽  
Vol 224 ◽  
pp. 65-72 ◽  
Author(s):  
Hadi Eslami ◽  
Mohammad Hassan Ehrampoush ◽  
Abbas Esmaeili ◽  
Ali Asghar Ebrahimi ◽  
Mohammad Taghi Ghaneian ◽  
...  

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