Fabrication of poly(lactic acid)/Ti composite scaffolds with enhanced mechanical properties and biocompatibility via fused filament fabrication (FFF)–based 3D printing

2019 ◽  
Vol 30 ◽  
pp. 100883 ◽  
Author(s):  
Jina Lee ◽  
Hyun Lee ◽  
Kwang-Hee Cheon ◽  
Cheonil Park ◽  
Tae-Sik Jang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
3D Printing ◽  
Poly Lactic Acid ◽  
Fused Filament Fabrication ◽  
Composite Scaffolds

scholarly journals Poly(Lactic) Acid Reinforced with Alkaline Lignin Biocomposites Prepared by Thermal Extrusion for Sustainable 3D Printing Process

2021 ◽  
Vol 2129 (1) ◽  
pp. 012003
Author(s):  
Nurul Amirah Abd Rahman ◽  
Hazleen Anuar ◽  
Fathilah Ali ◽  
Jonghwan Suhr
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
3D Printing ◽  
Natural Fiber ◽  
Tensile Tests ◽  
Poly Lactic Acid ◽  
Fused Filament Fabrication ◽  
3D Printed ◽  
Functional Components ◽  
Thermal Extrusion

Abstract The focus of this work is the mechanical characterization of biomaterials produced by 3D printing based on fused filament fabrication (FFF) process that has been mainly used for prototype rather than functional components due to the limited mechanical properties of pure thermoplastics parts. Addition of reinforcements from natural fiber has been adopted to improve the mechanical properties of the 3D printed parts. In this study, alkaline lignin powder that has been extracted from oil palm empty fruit bunches (OPEFB) via alkaline extraction process were used as filler in the production of biocomposites with poly(lactic) acid (PLA). Poly(lactic) acid filaments filled with 1% of alkaline lignin powder and has been compared with the presence of 5% of epoxidized palm oil (EPO) by means of thermal extrusion and further proceed with 3D printing. The samples were mechanically characterized using tensile tests and the fractography were observed. Tensile test that has been done on the filaments reveal that the filament with addition of lignin and EPO shows improved mechanical properties with higher tensile strength as well as lower stiffness. The 3D printed samples of the filament compositions also exhibit similar trend where the said filament has the best mechanical properties when the EPO is incorporated in the filament.

scholarly journals Evaluation of the Deterioration of the Mechanical Properties of Poly(lactic acid) Structures Fabricated by a Fused Filament Fabrication 3D Printer

Inventions ◽  
2019 ◽  
Vol 4 (1) ◽  
pp. 21 ◽  
Author(s):  
Miho Suzuki ◽  
Asahi Yonezawa ◽  
Kohei Takeda ◽  
Akira Yamada
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
Tensile Tests ◽  
Poly Lactic Acid ◽  
3D Printer ◽  
Fused Filament Fabrication ◽  
Tensile Direction ◽  
Test Pieces ◽  
3D Printers ◽  
Scan Pattern

A fused filament fabrication (FFF) 3D printer is a simple device capable of manufacturing three-dimensional structures in a series of easy steps. Commercial-level FFF 3D printers have spread rapidly in many fields in recent years. Poly(lactic acid) (PLA) is a biodegradable thermoplastic polymer used as a typical printing medium for FFF 3D printers. The FFF printer constructs an object with melted polymer extruded from a tiny scanning nozzle. The mechanical properties of FFF 3D structures printed with different scan patterns can therefore vary in accordance with the directions from which forces act upon them. The nozzle scan pattern also influences the deterioration of the mechanical properties of the structures in accordance with the degradation caused by the hydrolysis of PLA. In this study we conducted tensile tests to evaluate the strength characteristics of 3D printed test pieces formed from PLA using four different scan patterns: parallel, vertical, parallel-and-vertical, and cross-hatched at opposing diagonal angles to the tensile direction. We also formed test pieces by an injection molding method using the same material, for further comparison. We evaluated the deterioration of the test pieces after immersing them in saline for certain periods. After the test pieces formed by different nozzle scan patterns were immersed, they exhibited differences in the rates by which their maximum tensile stresses deteriorated and their masses increased through water uptake. The influences of the scan patterns could be classified into two types: the unidirectional scan pattern influence and bidirectional scan pattern influence. The data obtained in this research will be applied to structural design when the FFF 3D printer is employed for the fabrication of structures with PLA filament.

scholarly journals Biodegradable Poly(Lactic Acid) Nanocomposites for Fused Deposition Modeling 3D Printing

Nanomaterials ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 2567
Author(s):  
Madison Bardot ◽  
Michael D. Schulz
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
3D Printing ◽  
Fused Deposition Modeling ◽  
Ecological Crisis ◽  
Poly Lactic Acid ◽  
Fused Deposition Modelling ◽  
Fused Deposition ◽  
Biodegradable Poly ◽  
Deposition Modeling

3D printing by fused deposition modelling (FDM) enables rapid prototyping and fabrication of parts with complex geometries. Unfortunately, most materials suitable for FDM 3D printing are non-degradable, petroleum-based polymers. The current ecological crisis caused by plastic waste has produced great interest in biodegradable materials for many applications, including 3D printing. Poly(lactic acid) (PLA), in particular, has been extensively investigated for FDM applications. However, most biodegradable polymers, including PLA, have insufficient mechanical properties for many applications. One approach to overcoming this challenge is to introduce additives that enhance the mechanical properties of PLA while maintaining FDM 3D printability. This review focuses on PLA-based nanocomposites with cellulose, metal-based nanoparticles, continuous fibers, carbon-based nanoparticles, or other additives. These additives impact both the physical properties and printability of the resulting nanocomposites. We also detail the optimal conditions for using these materials in FDM 3D printing. These approaches demonstrate the promise of developing nanocomposites that are both biodegradable and mechanically robust.

scholarly journals Deterioration of the Mechanical Properties of FFF 3D-Printed PLA Structures

Inventions ◽  
2020 ◽  
Vol 6 (1) ◽  
pp. 1
Author(s):  
Asahi Yonezawa ◽  
Akira Yamada
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Test Piece ◽  
Tensile Tests ◽  
Poly Lactic Acid ◽  
Uniaxial Tensile ◽  
Layer By Layer ◽  
Fused Filament Fabrication ◽  
Test Pieces ◽  
3D Printed

Poly(lactic acid) (PLA) is a biodegradable polymer material used for the fabrication of objects by fused filament fabrication (FFF) 3D printing. FFF 3D printing technology has been quickly spreading over the past few years. An FFF-3D-printed object is formed from melted polymer extruded from a nozzle layer-by-layer. The mechanical properties of the object, and the changes in those properties as the object degrades, differ from the properties and changes observed in bulk objects. In this study we evaluated FFF-3D-printed objects by uniaxial tensile tests and four-point flexural tests to characterize the changes of three mechanical properties, namely, the maximum stress, elastic modulus, and breaking energy. Eight types of test pieces printed directly by an FFF 3D printer using two scan patterns and two interior fill percentages (IFPs) were tested by the aforesaid methods. The test pieces were immersed in saline and kept in an incubator at 37 °C for 30, 60, or 90 days before the mechanical testing. The changes in the mechanical properties differed largely between the test piece types. In some of the test pieces, transient increases in strength were observed before the immersion degraded the strength. Several of the test piece types were found to have superior specific strength in the tests. The results obtained in this research will be helpful for the design of PLA structures fabricated by FFF 3D printing.

scholarly journals Influence of Internal Innovative Architecture on the Mechanical Properties of 3D Polymer Printed Parts

Polymers ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 1129 ◽  
Author(s):  
Mihai Alin Pop ◽  
Cătălin Croitoru ◽  
Tibor Bedo ◽  
Virgil Geamăn ◽  
Irinel Radomir ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Lactic Acid ◽  
Wood Flour ◽  
Poly Lactic Acid ◽  
Fused Filament Fabrication ◽  
Strength Performance ◽  
Simple Support ◽  
3D Printed ◽  
Internal Architecture

The utilization of polymer-based materials is quickly expanding. The enterprises of today are progressively seeking techniques to supplant metal parts with polymer-based materials as a result of their light weight, simple support and modest costs. The ceaselessly developing requirement for composite materials with new or enhanced properties brings about the preparation of different polymer mixes with various arrangements, morphologies and properties. Fused filament fabrication processes such as 3D-printing are nowadays shaping the actual pathway to a full pallet of materials, from art–craft to biomaterials. In this study, the structural and mechanical behavior of three types of commercially available filaments comprised of synthetic poly(acrylonitrile-co-butadiene-co-styrene) (ABS), poly(lactic acid) (PLA) and poly(lactic acid)/polyhydroxyalkanoate reinforced with bamboo wood flour composite (PLA/PHA BambooFill) were assessed through mechanical testing and optical microscopy, aiming to understand how the modifications that occur in the printed models with internal architecture are influencing the mechanical properties of the 3D-printed material. It has been determined that the material printed from PLA presents the highest compression strength, three-point bending and shock resistance, while the ABS shows the best tensile strength performance. A probability plot was used to verify the normality hypothesis of data for the tensile strength, in conjunction with the Anderson–Darling statistic test. The results of the statistic indicated that the data were normally distributed and that there is a marked influence of the internal architecture of the 3D-printed models on the mechanical properties of the printed material.

scholarly journals A Review: Research Progress in Modification of Poly (Lactic Acid) by Lignin and Cellulose

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 776
Author(s):  
Sixiang Zhai ◽  
Qingying Liu ◽  
Yuelong Zhao ◽  
Hui Sun ◽  
Biao Yang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
Composite Materials ◽  
Crystallization Rate ◽  
Research Progress ◽  
Poly Lactic Acid ◽  
Green Composite ◽  
Materials Development ◽  
Research Attention ◽  
Biomass Components

With the depletion of petroleum energy, the possibility of prices of petroleum-based materials increasing, and increased environmental awareness, biodegradable materials as a kind of green alternative have attracted more and more research attention. In this context, poly (lactic acid) has shown a unique combination of properties such as nontoxicity, biodegradability, biocompatibility, and good workability. However, examples of its known drawbacks include poor tensile strength, low elongation at break, poor thermal properties, and low crystallization rate. Lignocellulosic materials such as lignin and cellulose have excellent biodegradability and mechanical properties. Compounding such biomass components with poly (lactic acid) is expected to prepare green composite materials with improved properties of poly (lactic acid). This paper is aimed at summarizing the research progress of modification of poly (lactic acid) with lignin and cellulose made in in recent years, with emphasis on effects of lignin and cellulose on mechanical properties, thermal stability and crystallinity on poly (lactic acid) composite materials. Development of poly (lactic acid) composite materials in this respect is forecasted.

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