scholarly journals Inside the reaction mechanism of direct CO2 conversion to DME over zeolite-based hybrid catalysts

2021 ◽  
Vol 294 ◽  
pp. 120255
Author(s):  
G. Bonura ◽  
S. Todaro ◽  
L. Frusteri ◽  
I. Majchrzak-Kucęba ◽  
D. Wawrzyńczak ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Co2 Conversion ◽  
Hybrid Catalysts

scholarly journals Mechanism of CO2 conversion to methanol over Cu(110) and Cu(100) surfaces

2020 ◽  
Vol 49 (25) ◽  
pp. 8478-8497 ◽  
Author(s):  
Michael D. Higham ◽  
Matthew G. Quesne ◽  
C. Richard A. Catlow
Keyword(s):  
Reaction Mechanism ◽  
Density Functional ◽  
Co2 Conversion ◽  
Density Functional Methods ◽  
Functional Methods

Density functional methods are applied to explore the reaction mechanism for CO2 hydrogenation to methanol over low-index Cu surfaces, namely Cu(110) and Cu(100).

CO2 conversion to methanol on Cu(i) oxide nanolayers and clusters: an electronic structure insight into the reaction mechanism

2015 ◽  
Vol 17 (16) ◽  
pp. 11088-11094 ◽  
Author(s):  
Ellie L. Uzunova ◽  
Nicola Seriani ◽  
Hans Mikosch
Keyword(s):  
Electronic Structure ◽  
Reaction Mechanism ◽  
Formic Acid ◽  
Co2 Conversion ◽  
Insight Into

The CO2 hydrogenation to methanol using dissociated water as the hydrogen source proceeds via stable carboxyl, formic acid and formaldehyde intermediates.

Promoting Direct CO2 Conversion to DME over Zeolite-based Hybrid Catalysts

2020 ◽  
Vol 60 (4) ◽  
pp. 508-515
Author(s):  
L. Frusteri ◽  
G. Bonura ◽  
C. Cannilla ◽  
S. Todaro ◽  
G. Giordano ◽  
...  
Keyword(s):  
Co2 Conversion ◽  
Hybrid Catalysts

scholarly journals Hybrid Catalysts for CO2 Conversion into Cyclic Carbonates

Catalysts ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 325 ◽  
Author(s):  
Carla Calabrese ◽  
Francesco Giacalone ◽  
Carmela Aprile
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Activity ◽  
Scientific Community ◽  
Heterogeneous Catalysts ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Co2 Conversion ◽  
Cyclic Carbonates ◽  
Hybrid Catalysts ◽  
Metal Organic

The conversion of carbon dioxide into valuable chemicals such as cyclic carbonates is an appealing topic for the scientific community due to the possibility of valorizing waste into an inexpensive, available, nontoxic, and renewable carbon feedstock. In this regard, last-generation heterogeneous catalysts are of great interest owing to their high catalytic activity, robustness, and easy recovery and recycling. In the present review, recent advances on CO2 cycloaddition to epoxide mediated by hybrid catalysts through organometallic or organo-catalytic species supported onto silica-, nanocarbon-, and metal–organic framework (MOF)-based heterogeneous materials, are highlighted and discussed.

scholarly journals Erratum to: Promoting Direct CO2 Conversion to DME over Zeolite-based Hybrid Catalysts

2021 ◽  
Vol 61 (9) ◽  
pp. 1081-1081
Author(s):  
L. Frusteri ◽  
G. Bonura ◽  
C. Cannilla ◽  
S. Todaro ◽  
G. Giordano ◽  
...  
Keyword(s):  
Co2 Conversion ◽  
Hybrid Catalysts

Arylation of enelactams using TIPSOTf: reaction scope and mechanistic insight

2021 ◽  
Author(s):  
Tomasz J. Idzik ◽  
Zofia M. Myk ◽  
Łukasz Struk ◽  
Magdalena Perużyńska ◽  
Gabriela Maciejewska ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Multinuclear Nmr ◽  
Mechanistic Insight ◽  
Nmr Study ◽  
Wide Range

Triisopropylsilyltrifluoromethanesulfonate can be effectively used for the arylation of a wide range of enelactams. The multinuclear NMR study provided deep insights into the reaction mechanism.

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