Characterisation of passive films formed on low carbon steel in borate buffer solution (pH 9.2) by electrochemical impedance spectroscopy

2005 ◽  
Vol 252 (5) ◽  
pp. 1510-1519 ◽  
Author(s):  
L. Hamadou ◽  
A. Kadri ◽  
N. Benbrahim
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Carbon Steel ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Low Carbon Steel ◽  
Passive Films ◽  
Borate Buffer Solution ◽  
Low Carbon ◽  
Buffer Solution ◽  
Solution Ph

scholarly journals Nano-TiO2 Phosphate Conversion Coatings – A Chemical Approach

2018 ◽  
Vol 4 (1) ◽  
pp. 47-54 ◽  
Author(s):  
Nilesh S. Bagal ◽  
Vaibhav S. Kathavate ◽  
Pravin P. Deshpande
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance Spectroscopy ◽  
Carbon Steel ◽  
Impedance Spectroscopy ◽  
Zinc Phosphate ◽  
Electrochemical Impedance ◽  
Low Carbon Steel ◽  
Low Carbon ◽  
Phosphate Coatings ◽  
Coating Weight

AbstractThe present study aims at deposition of zinc phosphate coatings on low carbon steel with incorporated nano- TiO2 particles by chemical phosphating method. The coated low carbon steel samples were assessed in corrosion studies using electrochemical impedance spectroscopy and potentiodynamic polarization techniques (Tafel) in 3.5% NaCl solution. Morphology and chemical composition of the coatings were analyzed by scanning electron microscopy and energy dispersive X-ray spectroscopy in order to observe growth of coating. Significant variations in the coating weight, porosity and corrosion resistance were observed with the addition of nano- TiO2 in the phosphating bath. Corrosion rate of nano-TiO2 chemical phosphate coated samples was found to be 3.5 milli inches per year which was 3 times less than the normal phosphate-coated sample (8 mpy). Electrochemical impedance spectroscopy studies reveal reduction of porosity of nano-TiO2 phosphate coated samples. It was found that nano-TiO2 particles in the phosphating solution yielded uniform phosphate coatings of higher coating weight, fewer defects and enhanced corrosion resistance than the normal zinc phosphate coatings (developed using normal phosphating bath).

Inhibition of anodic dissolution of low-carbon steel with alkyl phosphonates in borate buffer solution

2012 ◽  
Vol 48 (7) ◽  
pp. 769-772 ◽  
Author(s):  
A. A. Chirkunov ◽  
A. S. Gorbachev ◽  
Yu. I. Kuznetsov ◽  
Kh. S. Shikhaliev
Keyword(s):  
Carbon Steel ◽  
Anodic Dissolution ◽  
Low Carbon Steel ◽  
Borate Buffer ◽  
Borate Buffer Solution ◽  
Low Carbon ◽  
Buffer Solution

scholarly journals Nano Metal Dioxide Incorporated Conversion Phosphate Coatings—A Chemical Approach

2016 ◽  
Author(s):  
Nilesh S. Bagal ◽  
Vaibhav S. Kathavate ◽  
Pravin P. Deshpande
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance Spectroscopy ◽  
Carbon Steel ◽  
Zinc Phosphate ◽  
Electrochemical Impedance ◽  
Low Carbon Steel ◽  
Low Carbon ◽  
Nano Tio2 ◽  
Phosphate Coatings ◽  
Coating Weight

The present study aims at deposition of zinc phosphate coatings with the incorporation of nano Titanium dioxide particles by chemical phosphating method. Zinc phosphate coatings were developed on low carbon steel by using nano TiO2 in the standard phosphating bath. The Coated low carbon steel samples were assessed for corrosion studies using electrochemical impedance spectroscopy and potentiodynamic polarisation techniques in 3.5% NaCl solution. Chemical composition of the coatings was analysed by energy dispersive X-ray spectroscopy (EDX). Significant variations in the coating weight, porosity and corrosion resistance were observed with the addition of nano TiO2 in the phosphating bath. Corrosion rate of nano TiO2 incorporated chemical phosphate coated samples was found to be 3.5 mpy which was 4 times less than the bare uncoated low carbon steel (~14 mpy). Electrochemical impedance spectroscopy studies revels in the reduction of porosity in nano TiO2 phosphate coated samples. It was found that nano TiO2 particles in the phosphating solution yielded phosphate coatings of higher coating weight, greater surface coverage and enhanced corrosion resistance than the normal zinc phosphate coatings (developed using normal phosphating bath).

scholarly journals Nano Metal Dioxide Incorporated Conversion Phosphate Coatings—A Chemical Approach

2016 ◽  
Author(s):  
Nilesh S. Bagal ◽  
Vaibhav S. Kathavate ◽  
Pravin P. Deshpande
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance Spectroscopy ◽  
Carbon Steel ◽  
Zinc Phosphate ◽  
Electrochemical Impedance ◽  
Low Carbon Steel ◽  
Low Carbon ◽  
Nano Tio2 ◽  
Phosphate Coatings ◽  
Coating Weight

The present study aims at deposition of zinc phosphate coatings with the incorporation of nano Titanium dioxide particles by chemical phosphating method. Zinc phosphate coatings were developed on low carbon steel by using nano TiO2 in the standard phosphating bath. The Coated low carbon steel samples were assessed for corrosion studies using electrochemical impedance spectroscopy and potentiodynamic polarisation techniques in 3.5% NaCl solution. Chemical composition of the coatings was analysed by energy dispersive X-ray spectroscopy (EDX). Significant variations in the coating weight, porosity and corrosion resistance were observed with the addition of nano TiO2 in the phosphating bath. Corrosion rate of nano TiO2 incorporated chemical phosphate coated samples was found to be 3.5 mpy which was 4 times less than the bare uncoated low carbon steel (~14 mpy). Electrochemical impedance spectroscopy studies revels in the reduction of porosity in nano TiO2 phosphate coated samples. It was found that nano TiO2 particles in the phosphating solution yielded phosphate coatings of higher coating weight, greater surface coverage and enhanced corrosion resistance than the normal zinc phosphate coatings (developed using normal phosphating bath).

The Corrosion of Carbon Steel and Stainless Steel in Simulated Geothermal Media

1985 ◽  
Vol 38 (8) ◽  
pp. 1133 ◽  
Author(s):  
BG Pound ◽  
MH Abdurrahman ◽  
MP Glucina ◽  
GA Wright ◽  
RM Sharp
Keyword(s):  
Carbon Steel ◽  
Corrosion Rate ◽  
Stainless Steels ◽  
Polarization Resistance ◽  
Iron Sulfide ◽  
Low Carbon Steel ◽  
Passive Films ◽  
Low Carbon ◽  
Corrosion Rates ◽  
Good Agreement

The corrosion rates of low-carbon steel, and 304, 316 and 410/420 stainless steels in simulated geothermal media containing hydrogen sulfide have been measured by means of the polarization resistance technique. Good agreement was found between weight-loss and polarization resistance measurements of the corrosion rate for all the metals tested. Carbon steel formed a non-adherent film of mackinawite (Fe1 + xS). The lack of protection afforded to the steel by the film resulted in an approximately constant corrosion rate. The stainless steels also exhibited corrosion rates that were independent of time. However, the 410 and 420 alloys formed an adherent film consisting mainly of troilite ( FeS ) which provided only limited passivity. In contrast, the 304 and 316 alloys appeared to be essentially protected by a passive film which did not seem to involve an iron sulfide phase. However, all the stainless steels, particularly the 410 and 420 alloys, showed pitting, which indicated that some breakdown of the passive films occurred.

Phenylcoumarin Glucoside as a Natural Inhibitor in the Protection of Low Carbon Steel Against Corrosion

MRS Advances ◽  
2017 ◽  
Vol 2 (62) ◽  
pp. 3909-3915
Author(s):  
Héctor M. Barbosa Cásarez ◽  
Araceli Espinoza Vázquez ◽  
Francisco J. Rodríguez-Gomez
Keyword(s):  
Carbon Steel ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Low Carbon Steel ◽  
Steel Corrosion ◽  
Low Carbon ◽  
Low Concentrations ◽  
Natural Inhibitor ◽  
Polarization Studies

AbstractPhenylcoumarin glucoside (4-PC) is a compound extracted from the plant Hintona latiflora and was studied as inhibitor for AISI 1018 steel corrosion in 3% NaCl solution using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques, which may find application as eco-friendly corrosion inhibitors. The 4-PC provides inhibitor properties that protect AISI 1018 low carbon steel against corrosion at low concentrations (5 ppm) obtained by EIS. Polarization studies showed that the inhibitor was of mixed type. The inhibition efficiency by the two electrochemical techniques shows similar results. The inhibitor adsorption was demonstrated to be a combined process (physisorption and chemisorption) according to the Langmuir isotherm.

Corrosion Behavior of Al-Si-Cr-Cu Bearing Low Carbon Steel in A Cyclic Dry/Wet Laboratory Test

2009 ◽  
Vol 79-82 ◽  
pp. 1017-1020 ◽  
Author(s):  
Hui Shu Zhang ◽  
Dong Ping Zhan ◽  
Song Lian Bai ◽  
Zhou Hua Jiang
Keyword(s):  
Carbon Steel ◽  
Electrochemical Impedance ◽  
Low Carbon Steel ◽  
Optical Microscope ◽  
Low Carbon ◽  
Rust Layer ◽  
Electrochemical Behaviors ◽  
Corrosion Rates ◽  
The Matrix ◽  
Corrosion Behaviors

The corrosion behaviors of Al-Si-Cr-Cu bearing low carbon steel and a reference steel Q235 were tested in a cyclic dry/wet environment containing 0.01mol/L NaHSO3 in laboratory. Rust layers were observed by optical microscope (OM), scanning electron microscopy (SEM) and XRD. The electrochemical behaviors of the steels were studied on the polarization curves and electrochemical impedance spectroscopy (EIS). The results indicate that after 120h corrosion test, the annual corrosion rates of the designed steels reduce 42 % than Q235 at least. The corrosion products are generally iron oxyhydroxides and oxides such as FeOOH, γ-FeOOH, α-FeOOH, γ-Fe2O3, Fe3O4. The α-FeOOH possesses good stabilization mainly exits and can improve the corrosion resistance. There are the enrichments of Cu, Cr, Si and Al in the rust layer close to the matrix, which make the rust layer be more compact and protected. The corrosion currents of the two designed steels are lower than that of Q235, the corrosion potentials are higher than that of Q235 after Tafel fitting. The rust layer impedances of the designed steels are higher than that of Q235.

Effect of Nanoparticle Addition in Hybrid Sol-Gel Silane Coating on Corrosion Resistance of Low Carbon Steel

2013 ◽  
Vol 686 ◽  
pp. 244-249 ◽  
Author(s):  
Poovarasi Balan ◽  
Aaron Ng ◽  
Chee Beng Siang ◽  
R.K. Singh Raman ◽  
Eng Seng Chan
Keyword(s):  
Corrosion Resistance ◽  
Carbon Steel ◽  
Electrochemical Impedance ◽  
Sol Gel ◽  
Low Carbon Steel ◽  
Electrochemical Corrosion ◽  
Alumina Nanoparticles ◽  
Low Carbon ◽  
Silane Coating ◽  
Sol Gel Films

Chromium pre-treatments of metal have been replaced by silane pre-treatments as more environmental friendly option. Nanoparticles can be added in the silane sol-gel network have been reported to improve corrosion resistance. In this work, the electrochemical corrosion resistance of low carbon steel coated with hybrid organic-inorganic sol-gel film filled with nanoparticles was evaluated. The sol-gel films have been synthesized from 3-glycidoxy-propyl-trimethoxy-silane (3-GPTMS) and tetra-ethyl-ortho-silicate (TEOS) precursors. These films have been impregnated with 300 ppm of silica or alumina nanoparticles. The electrochemical behavior of the coated steel was evaluated by means of electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM). Equivalent circuit modeling, used for quantifying the EIS measurements showed that sol-gel films containing silica nanoparticles improved the barrier properties of the silane coating. The silica nanoparticle-containing films showed highest initial pore resistance over the five days of immersion in 0.05M NaCl.

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