Corrosion Behavior of Al-Si-Cr-Cu Bearing Low Carbon Steel in A Cyclic Dry/Wet Laboratory Test

2009 ◽  
Vol 79-82 ◽  
pp. 1017-1020 ◽  
Author(s):  
Hui Shu Zhang ◽  
Dong Ping Zhan ◽  
Song Lian Bai ◽  
Zhou Hua Jiang
Keyword(s):  
Carbon Steel ◽  
Electrochemical Impedance ◽  
Low Carbon Steel ◽  
Optical Microscope ◽  
Low Carbon ◽  
Rust Layer ◽  
Electrochemical Behaviors ◽  
Corrosion Rates ◽  
The Matrix ◽  
Corrosion Behaviors

The corrosion behaviors of Al-Si-Cr-Cu bearing low carbon steel and a reference steel Q235 were tested in a cyclic dry/wet environment containing 0.01mol/L NaHSO3 in laboratory. Rust layers were observed by optical microscope (OM), scanning electron microscopy (SEM) and XRD. The electrochemical behaviors of the steels were studied on the polarization curves and electrochemical impedance spectroscopy (EIS). The results indicate that after 120h corrosion test, the annual corrosion rates of the designed steels reduce 42 % than Q235 at least. The corrosion products are generally iron oxyhydroxides and oxides such as FeOOH, γ-FeOOH, α-FeOOH, γ-Fe2O3, Fe3O4. The α-FeOOH possesses good stabilization mainly exits and can improve the corrosion resistance. There are the enrichments of Cu, Cr, Si and Al in the rust layer close to the matrix, which make the rust layer be more compact and protected. The corrosion currents of the two designed steels are lower than that of Q235, the corrosion potentials are higher than that of Q235 after Tafel fitting. The rust layer impedances of the designed steels are higher than that of Q235.

Corrosion behaviors of iron, chromium, nickel, low-carbon steel and four types of stainless steels in liquid antimony-tin alloy

CORROSION ◽  
10.5006/3820 ◽  
2021 ◽  
Author(s):  
Wei Liu ◽  
Huayi Yin ◽  
Kaifa Du ◽  
Bing Yang ◽  
Dihua Wang
Keyword(s):  
Carbon Steel ◽  
Corrosion Rate ◽  
Stainless Steels ◽  
Liquid Metals ◽  
Low Carbon Steel ◽  
Solid Substrate ◽  
Low Carbon ◽  
Corrosion Resistant ◽  
Corrosion Behaviors ◽  
Iron Chromium

Corrosion-resistant metals and alloys towards liquid metals determine the service performances and lifetime of the devices employing liquid metals. This paper studies the static corrosion behaviors of iron, chromium, nickel, low carbon steel, and four types of stainless steels (SS410, SS430, SS304, SS316L) in liquid Sb-Sn at 500 oC, aiming to screen corrosion-resistant SS for Li||Sb-Sn liquid metal batteries (LMBs). The corrosion rates of Fe and Ni are 0.94 μm h-1 and 6.03 μm h-1 after 160 h’s measurement, respectively. Cr shows a low corrosion rate of < 0.05μm h-1, which is due to the formation of a relatively stable Cr-Sb layer that may be able to prevent the interdiffusion between the solid substrate and liquid Sb-Sn. Ni has a high corrosion rate because the formed Ni-Sb and Ni-Sn compounds are soluble in the liquid Sb-Sn. The corrosion products of both pure metals and SS can be predicted by thermodynamic and phase diagram analysis. Among the four types of SS, SS430 shows the best corrosion resistance towards liquid Sb-Sb with a corrosion rate of 0.19 μm h-1. Therefore, a liquid Sb-Sn resistant material should have a high Cr content and a low Ni content, and this principle is applicable to design metallic materials not only for LMBs but also for other devices employing liquid Sb- and Sn-containing liquid metals.

The Corrosion of Carbon Steel and Stainless Steel in Simulated Geothermal Media

1985 ◽  
Vol 38 (8) ◽  
pp. 1133 ◽  
Author(s):  
BG Pound ◽  
MH Abdurrahman ◽  
MP Glucina ◽  
GA Wright ◽  
RM Sharp
Keyword(s):  
Carbon Steel ◽  
Corrosion Rate ◽  
Stainless Steels ◽  
Polarization Resistance ◽  
Iron Sulfide ◽  
Low Carbon Steel ◽  
Passive Films ◽  
Low Carbon ◽  
Corrosion Rates ◽  
Good Agreement

The corrosion rates of low-carbon steel, and 304, 316 and 410/420 stainless steels in simulated geothermal media containing hydrogen sulfide have been measured by means of the polarization resistance technique. Good agreement was found between weight-loss and polarization resistance measurements of the corrosion rate for all the metals tested. Carbon steel formed a non-adherent film of mackinawite (Fe1 + xS). The lack of protection afforded to the steel by the film resulted in an approximately constant corrosion rate. The stainless steels also exhibited corrosion rates that were independent of time. However, the 410 and 420 alloys formed an adherent film consisting mainly of troilite ( FeS ) which provided only limited passivity. In contrast, the 304 and 316 alloys appeared to be essentially protected by a passive film which did not seem to involve an iron sulfide phase. However, all the stainless steels, particularly the 410 and 420 alloys, showed pitting, which indicated that some breakdown of the passive films occurred.

Phenylcoumarin Glucoside as a Natural Inhibitor in the Protection of Low Carbon Steel Against Corrosion

MRS Advances ◽  
2017 ◽  
Vol 2 (62) ◽  
pp. 3909-3915
Author(s):  
Héctor M. Barbosa Cásarez ◽  
Araceli Espinoza Vázquez ◽  
Francisco J. Rodríguez-Gomez
Keyword(s):  
Carbon Steel ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Low Carbon Steel ◽  
Steel Corrosion ◽  
Low Carbon ◽  
Low Concentrations ◽  
Natural Inhibitor ◽  
Polarization Studies

AbstractPhenylcoumarin glucoside (4-PC) is a compound extracted from the plant Hintona latiflora and was studied as inhibitor for AISI 1018 steel corrosion in 3% NaCl solution using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques, which may find application as eco-friendly corrosion inhibitors. The 4-PC provides inhibitor properties that protect AISI 1018 low carbon steel against corrosion at low concentrations (5 ppm) obtained by EIS. Polarization studies showed that the inhibitor was of mixed type. The inhibition efficiency by the two electrochemical techniques shows similar results. The inhibitor adsorption was demonstrated to be a combined process (physisorption and chemisorption) according to the Langmuir isotherm.

Effect of Nanoparticle Addition in Hybrid Sol-Gel Silane Coating on Corrosion Resistance of Low Carbon Steel

2013 ◽  
Vol 686 ◽  
pp. 244-249 ◽  
Author(s):  
Poovarasi Balan ◽  
Aaron Ng ◽  
Chee Beng Siang ◽  
R.K. Singh Raman ◽  
Eng Seng Chan
Keyword(s):  
Corrosion Resistance ◽  
Carbon Steel ◽  
Electrochemical Impedance ◽  
Sol Gel ◽  
Low Carbon Steel ◽  
Electrochemical Corrosion ◽  
Alumina Nanoparticles ◽  
Low Carbon ◽  
Silane Coating ◽  
Sol Gel Films

Chromium pre-treatments of metal have been replaced by silane pre-treatments as more environmental friendly option. Nanoparticles can be added in the silane sol-gel network have been reported to improve corrosion resistance. In this work, the electrochemical corrosion resistance of low carbon steel coated with hybrid organic-inorganic sol-gel film filled with nanoparticles was evaluated. The sol-gel films have been synthesized from 3-glycidoxy-propyl-trimethoxy-silane (3-GPTMS) and tetra-ethyl-ortho-silicate (TEOS) precursors. These films have been impregnated with 300 ppm of silica or alumina nanoparticles. The electrochemical behavior of the coated steel was evaluated by means of electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM). Equivalent circuit modeling, used for quantifying the EIS measurements showed that sol-gel films containing silica nanoparticles improved the barrier properties of the silane coating. The silica nanoparticle-containing films showed highest initial pore resistance over the five days of immersion in 0.05M NaCl.

Effect of Ti, Al and Mg Addition on the Impact Toughness of Heat Affected Zone in Low Carbon Steel

2009 ◽  
Vol 79-82 ◽  
pp. 143-146
Author(s):  
Jiang Hua Ma ◽  
Dong Ping Zhan ◽  
Zhou Hua Jiang ◽  
Ji Cheng He
Keyword(s):  
Carbon Steel ◽  
Impact Toughness ◽  
Heat Affected Zone ◽  
Low Carbon Steel ◽  
Optical Microscope ◽  
Carbon Steels ◽  
Low Carbon ◽  
Welding Simulation ◽  
Mg Addition ◽  
The Impact

In order to understand the effects of deoxidizer such as aluminium, titanium and magnesium on the impact toughness of heat affected zone (HAZ), three low carbon steels deoxidized by Ti-Al, Mg and Ti-Mg were obtained. After smelting, forging, rolling and welding simulation, the effects of Al, Ti and Mg addition on the impact toughness of HAZ in low carbon steel were studied. The inclusion characteristics (size, morphology and chemistry) of samples before welding and the fracture pattern of the specimens after the Charpy-type test were respectively analyzed using optical microscope and scanning electron microscopy (SEM). The following results were found. The density of inclusion in Ti-Mg deoxidized steel is bigger than Ti-Al deoxidized steel. The average diameter is decreased for the former than the latter. The addition of Ti-Mg can enhance the impact toughness of the HAZ after welding simulation. The maximal value of the impact toughness is 66.5J/cm2. The complex particles of MgO-TiOx-SiO2-MnS are most benefit to enhance impact toughness. The improvement of HAZ is attributable to the role of particle pinning and the formation of intergranular ferrite.

Study of Corrosion Behavior of Friction Surfacing AA6351 Aluminium Alloy Coating on AISI 1020 Low Carbon Steel

2020 ◽  
Vol 1012 ◽  
pp. 401-406
Author(s):  
Carlos Trivellato de Carvalho Filho ◽  
Pedro Paiva Brito
Keyword(s):  
Surface Roughness ◽  
Corrosion Resistance ◽  
Carbon Steel ◽  
Corrosion Behavior ◽  
Electrochemical Impedance ◽  
Low Carbon Steel ◽  
Alloy Coating ◽  
Low Carbon ◽  
Friction Surfacing ◽  
Finishing Process

In the present work, the friction surfacing process was applied to manufacture aluminum alloy (AA6351) coatings on low carbon steel (AISI 1020) substrates. After friction surfacing the AA6351 deposited coatings were submitted to two finishing process in order to adjust surface roughness: milling and milling followed by sanding. The corrosion behavior of the two finishing process was compared with the as-deposited condition in order to determine the influence of surface roughness on the corrosion resistance of friction surfacing coatings. The corrosion behavior was examined by electrochemical impedance spectroscopy and potentiodynamic polarization in a 3.5wt.%NaCl solution containing naturally dissolved O2. The results obtained indicated that the elevated surface roughness observed in the as-deposited condition led to relatively lower corrosion resistance in comparison, with lower values for polarization resistance and more anodic corrosion potential.

Nucleation of Bainite on Allotriomorphic Ferrite/Austenite Interface in a Low Carbon Steel

2010 ◽  
Vol 654-656 ◽  
pp. 2326-2329 ◽  
Author(s):  
Hui Guo ◽  
Yin Bai ◽  
Shan Wu Yang ◽  
Xin Lai He
Keyword(s):  
Carbon Steel ◽  
Low Carbon Steel ◽  
Optical Microscope ◽  
Type I ◽  
Type Ii ◽  
Low Carbon ◽  
Austenite Grain Size ◽  
Type Iii ◽  
Forming Temperature ◽  
Allotriomorphic Ferrite

. A low carbon steel is austenitized and isothermally held at 680°C to form allotriomorphic ferrite and followed by a holding at lower temperature to form bainite. The morphology of allotriomorphic ferrite/bainite interfaces is studied using optical microscope. Three kinds of combination are observed: Type I: interface on one side is clear while on the other side, unclear; Type II: unclear on both sides; Type III: clear on both sides. Clear interface indicates a large difference in the orientation between the bainite and the ferrite, and unclear interface, a very small difference. The statistical counting shows that the ratio of Type I is about 80-82%, and that of Type II, 7-8%, and Type III, 9-11%. It is observed that this ratio does not change with the austenite grain size and bainite forming temperature. And the clear and unclear side of allotriomorphic ferrite may have different influence on the nucleation rate of bainite at allotriomorhic ferrite/prior austenite interface.

scholarly journals Nano-TiO2 Phosphate Conversion Coatings – A Chemical Approach

2018 ◽  
Vol 4 (1) ◽  
pp. 47-54 ◽  
Author(s):  
Nilesh S. Bagal ◽  
Vaibhav S. Kathavate ◽  
Pravin P. Deshpande
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance Spectroscopy ◽  
Carbon Steel ◽  
Impedance Spectroscopy ◽  
Zinc Phosphate ◽  
Electrochemical Impedance ◽  
Low Carbon Steel ◽  
Low Carbon ◽  
Phosphate Coatings ◽  
Coating Weight

AbstractThe present study aims at deposition of zinc phosphate coatings on low carbon steel with incorporated nano- TiO2 particles by chemical phosphating method. The coated low carbon steel samples were assessed in corrosion studies using electrochemical impedance spectroscopy and potentiodynamic polarization techniques (Tafel) in 3.5% NaCl solution. Morphology and chemical composition of the coatings were analyzed by scanning electron microscopy and energy dispersive X-ray spectroscopy in order to observe growth of coating. Significant variations in the coating weight, porosity and corrosion resistance were observed with the addition of nano- TiO2 in the phosphating bath. Corrosion rate of nano-TiO2 chemical phosphate coated samples was found to be 3.5 milli inches per year which was 3 times less than the normal phosphate-coated sample (8 mpy). Electrochemical impedance spectroscopy studies reveal reduction of porosity of nano-TiO2 phosphate coated samples. It was found that nano-TiO2 particles in the phosphating solution yielded uniform phosphate coatings of higher coating weight, fewer defects and enhanced corrosion resistance than the normal zinc phosphate coatings (developed using normal phosphating bath).

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