Homogeneous dispersion of boron nitride nanoplatelets in powder feedstocks for plasma spraying

Boron nitride materials have some excellent features, such as high temperature resistance, chemical resistance, good electric performance and radiation resistance . Along with the development of science and technology, boron nitride materials are made into coating widely, put it in the surface of metallic materials or non-metallic materials, can extend their service life significantly[1]. Atomic force microscope (AFM) is widely used for nanoscale morphology characterization and submicron scale structure material, simple sample preparation is its advantage. [2] Based on the domestic boron nitride coating as the research background, using AFM simulate the surface nanostructures of three dimensional, and evaluate the flatness of boron nitride ceramic coating which made by plasma spraying method and chemical vapor phase precipitation method respectively. The results show that the coating prepared with plasma spraying is more dense, surface flatness is smaller, surface roughness uniformity is better.

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Homogeneous Dispersion of Gallium Nitride Nanoparticles in a Boron Nitride Matrix by Nitridation with Urea

Journal of Nanoscience and Nanotechnology ◽

10.1166/jnn.2010.2206 ◽

2010 ◽

Vol 10 (7) ◽

pp. 4312-4316

Author(s):

Takafumi Kusunose ◽

Tohru Sekino ◽

Yoichi Ando

Keyword(s):

Gallium Nitride ◽

Boron Nitride ◽

Homogeneous Dispersion ◽

Gallium Nitride Nanoparticles

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Observations of nanocrystalline cubic boron nitride formed with plasma spraying

Acta Materialia ◽

10.1016/j.actamat.2016.06.038 ◽

2016 ◽

Vol 116 ◽

pp. 155-165 ◽

Cited By ~ 16

Author(s):

K. Madhav Reddy ◽

Chawon Hwang ◽

Metin Ornek ◽

Steven L. Miller ◽

William E. Mayo ◽

...

Keyword(s):

Boron Nitride ◽

Plasma Spraying ◽

Cubic Boron Nitride

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Electron microscopy studies of plasma-sprayed materials

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100074276 ◽

1983 ◽

Vol 41 ◽

pp. 70-71

Author(s):

K.R. Subramanian ◽

A.H. King ◽

H. Herman

Keyword(s):

Plasma Spraying ◽

Substrate Surface ◽

Flame Temperature ◽

Ceramic Coatings ◽

Metallic Substrates ◽

Hot Plasma ◽

Almost All ◽

Plasma Sprayed ◽

Hostile Environments ◽

Plasma Spraying Process

Plasma spraying is a technique which is used to apply coatings to metallic substrates for a variety of purposes, including hardfacing, corrosion resistance and thermal barrier applications. Almost all of the applications of this somewhat esoteric fabrication technique involve materials in hostile environments and the integrity of the coatings is of paramount importance: the effects of process variables on such properties as adhesive strength, cohesive strength and hardness of the substrate/coating system, however, are poorly understood.Briefly, the plasma spraying process involves forming a hot plasma jet with a maximum flame temperature of approximately 20,000K and a gas velocity of about 40m/s. Into this jet the coating material is injected, in powder form, so it is heated and projected at the substrate surface. Relatively thick metallic or ceramic coatings may be speedily built up using this technique.

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Development of Crystallinity in Turbostratic Boron Nitride Derived from Polymeric Precursors

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100089081 ◽

1991 ◽

Vol 49 ◽

pp. 954-955

Author(s):

X. Qiu ◽

A. K. Datye ◽

T. T. Borek ◽

R. T. Paine

Keyword(s):

Thermal Treatment ◽

Boron Nitride ◽

Diffraction Pattern ◽

Polymeric Precursors ◽

Polymer Precursors ◽

Diffuse Ring

Boron nitride derived from polymer precursors is of great interest for applications such as fibers, coatings and novel forms such as aerogels. The BN is prepared by the polymerization of functionalized borazine and thermal treatment in nitrogen at 1200°C. The BN powders obtained by this route are invariably trubostratic wherein the sheets of hexagonal BN are randomly oriented to yield the so-called turbostratic modification. Fib 1a and 1b show images of BN powder with the corresponding diffraction pattern in fig. 1c. The (0002) reflection from BN is seen as a diffuse ring with occational spots that come from crystals of BN such as those shown in fig. 1b. The (0002) lattice fringes of BN seen in these powders are the most characteristic indication of the crystallinity of the BN.

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Structural relationships in the synthesis of cubic boron nitride thin films by ion-assisted deposition

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s042482010017092x ◽

1994 ◽

Vol 52 ◽

pp. 638-639

Author(s):

D. L. Medlin ◽

T. A. Friedmann ◽

P. B. Mirkarimi ◽

M. J. Mills ◽

K. F. McCarty

Keyword(s):

Boron Nitride ◽

Ion Irradiation ◽

Cubic Boron Nitride ◽

Film Stress ◽

Bonded Phases ◽

Structural Relationships ◽

Precursor Material ◽

Pressure Synthesis ◽

Microstructure Of The Material

The allotropes of boron nitride include two sp2-bonded phases with hexagonal and rhombohedral structures (hBN and rBN) and two sp3-bonded phases with cubic (zincblende) and hexagonal (wurtzitic) structures (cBN and wBN) (Fig. 1). Although cBN is synthesized in bulk form by conversion of hBN at high temperatures and pressures, low-pressure synthesis of cBN as a thin film is more difficult and succeeds only when the growing film is simultaneously irradiated with a high flux of ions. Only sp2-bonded material, which generally has a disordered, turbostratic microstructure (tBN), will form in the absence of ion-irradiation. The mechanistic role of the irradiation is not well understood, but recent work suggests that ion-induced compressive film stress may induce the transformation to cBN.Typically, BN films are deposited at temperatures less than 1000°C, a regime for which the structure of the sp2-bonded precursor material dictates the phase and microstructure of the material that forms from conventional (bulk) high pressure treatment.

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Molecular insights on the dynamic stability of peptide nucleic acid functionalized carbon and boron nitride nanotubes

Physical Chemistry Chemical Physics ◽

10.1039/d0cp05759b ◽

2021 ◽

Vol 23 (1) ◽

pp. 219-228

Author(s):

Nabanita Saikia ◽

Mohamed Taha ◽

Ravindra Pandey

Keyword(s):

Nucleic Acid ◽

Boron Nitride ◽

Nucleic Acids ◽

Dynamic Stability ◽

Peptide Nucleic Acid ◽

Rational Design ◽

Peptide Nucleic Acids ◽

Boron Nitride Nanotubes ◽

Molecular Hybrids ◽

Single Wall Nanotubes

The rational design of self-assembled nanobio-molecular hybrids of peptide nucleic acids with single-wall nanotubes rely on understanding how biomolecules recognize and mediate intermolecular interactions with the nanomaterial's surface.

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