Novel detection method for gallic acid: a water soluble boronic acid-based fluorescent sensor with double recognition sites

Author(s):  
Dongxue Zhan ◽  
Zhancun Bian ◽  
Haizhen Li ◽  
Ran Wang ◽  
Guiqian Fang ◽  
...  
RSC Advances ◽  
2020 ◽  
Vol 10 (47) ◽  
pp. 28148-28156
Author(s):  
Zhancun Bian ◽  
Guiqian Fang ◽  
Ran Wang ◽  
Dongxue Zhan ◽  
Qingqiang Yao ◽  
...  

Herein, the specific recognition of caffeic acid by the double sites boronic acid sensor 5c is reported. The synergistic effect of the two recognition sites greatly improves the binding affinity and selectivity of the sensor.


2015 ◽  
Vol 13 (25) ◽  
pp. 6927-6930 ◽  
Author(s):  
Yoshihide Hattori ◽  
Miki Ishimura ◽  
Youichirou Ohta ◽  
Hiroshi Takenaka ◽  
Tsubasa Watanabe ◽  
...  

To develop a detection method for boronic acid derivatives, boron-chelating ligands were synthesized as fluorescent sensors for boronic acid derivatives.


2019 ◽  
Vol 43 (11) ◽  
pp. 4385-4390 ◽  
Author(s):  
Hao Wang ◽  
Guiqian Fang ◽  
Hongxiao Wang ◽  
Jindi Dou ◽  
Zhancun Bian ◽  
...  

Herein we reported a novel boronic acid-based water-soluble sensor. It decreased the fluorescence by 50% when combined with 0.0146 M of d-ribose, while increased or not changed obviously after binding to other carbohydrates.


2021 ◽  
Vol 8 (1) ◽  
pp. 9
Author(s):  
Laura Brelle ◽  
Estelle Renard ◽  
Valerie Langlois

A novel generation of gels based on medium chain length poly(3-hydroxyalkanoate)s, mcl-PHAs, were developed by using ionic interactions. First, water soluble mcl-PHAs containing sulfonate groups were obtained by thiol-ene reaction in the presence of sodium-3-mercapto-1-ethanesulfonate. Anionic PHAs were physically crosslinked by divalent inorganic cations Ca2+, Ba2+, Mg2+ or by ammonium derivatives of gallic acid GA-N(CH3)3+ or tannic acid TA-N(CH3)3+. The ammonium derivatives were designed through the chemical modification of gallic acid GA or tannic acid TA with glycidyl trimethyl ammonium chloride (GTMA). The results clearly demonstrated that the formation of the networks depends on the nature of the cations. A low viscoelastic network having an elastic around 40 Pa is formed in the presence of Ca2+. Although the gel formation is not possible in the presence of GA-N(CH3)3+, the mechanical properties increased in the presence of TA-N(CH3)3+ with an elastic modulus G’ around 4200 Pa. The PHOSO3−/TA-N(CH3)3+ gels having antioxidant activity, due to the presence of tannic acid, remained stable for at least 5 months. Thus, the stability of these novel networks based on PHA encourage their use in the development of active biomaterials.


2021 ◽  
Author(s):  
Lamiaa Reda Ahmed ◽  
Ahmed F. M. EL-Mahdy ◽  
Cheng-Tang Pan ◽  
Shiao-Wei Kuo

In this paper, we describe the construction of a new fluorescent hydroxyl- and hydrazone-based covalent organic framework (TFPB-DHTH COF) through the one-pot polycondensation of 1,3,5-tris(4-formylphenyl)benzene (TFPB) and 2,5-dihydroxyterephthalohydrazide (DHTH) under...


2014 ◽  
Vol 56 ◽  
pp. 58-63 ◽  
Author(s):  
Jian Xu ◽  
Qian Li ◽  
Ying Yue ◽  
Yong Guo ◽  
Shijun Shao

2017 ◽  
Vol 41 (9) ◽  
pp. 3303-3307 ◽  
Author(s):  
You-Ming Zhang ◽  
Kai-Peng Zhong ◽  
Jun-Xia Su ◽  
Xiao-Peng Chen ◽  
Hong Yao ◽  
...  

A novel water soluble fluorescent sensor was synthesized by employing the carboxyl and imidazolyl moiety as the hydrophilic group site and Hg2+ binding site, whereas a naphthalimide moiety was used as the signal group.


2018 ◽  
Vol 96 (4) ◽  
pp. 363-370 ◽  
Author(s):  
You-Ming Zhang ◽  
Xiao-Peng Chen ◽  
Guo-Yan Liang ◽  
Kai-Peng Zhong ◽  
Hong Yao ◽  
...  

The selective recognition of target ions in water is very important and the development of novel water-soluble chemosensor is still an intriguing challenge. Herein, a novel water-soluble fluorescent sensor based on aspartic acid (Asp) functionalized 1,8-naphthalimide derivative (Asp-NI) has been designed and synthesized. The sensor Asp-NI could dissolve in water and successively detect Fe3+ and H2PO4− in water solution with high selectivity and sensitivity. The detection limits are 4.97 × 10−7 mol/L for Fe3+ and 5.27 × 10−6 mol/L for H2PO4−. Other coexistent competitive metal ions (Hg2+, Ag+, Ca2+, Cu2+, Co2+, Ni2+, Cd2+, Pb2+, Zn2+, Cr3+, and Mg2+) showed no interference in the Fe3+ detection process. The sensor Asp-NI could act as a Fe3+ and H2PO4− controlled “On–Off–On” fluorescent switch. More interestingly, the Fe3+ induced fluorescence quenching process could be totally reversed by the addition of H2PO4−, this “On–Off–On” switching process could be repeated several times with little fluorescence loss. Notably, the actual usage of sensor Asp-NI was further demonstrated by test kits.


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