scholarly journals A novel electrodeposition route for fabrication of the superhydrophobic surface with unique self-cleaning, mechanical abrasion and corrosion resistance properties

2016 ◽  
Vol 303 ◽  
pp. 37-47 ◽  
Author(s):  
Huaiyuan Wang ◽  
Yixing Zhu ◽  
Ziyi Hu ◽  
Xiguang Zhang ◽  
Shiqi Wu ◽  
...  
2020 ◽  
Vol 20 (10) ◽  
pp. 6317-6325 ◽  
Author(s):  
Xueting Shi ◽  
Libin Zhao ◽  
Jing Wang ◽  
Libang Feng

This work reports a facile method for fabricating superhydrophobic surface on copper plate by AgNO3 treatment and dodecyl mercaptan modification. The as-prepared superhydrophobic copper plate presents hierarchical and rough morphology composed of nanosheets and nanoparticleformed matrix. Meanwhile, long alkyl chains are assembled onto the rough surface successfully. Consequently, the copper plate is endowed with excellent superhydrophobic performance with a water contact angle of 156.8° and a rolling angle of ca. 3°. Moreover, the superhydrophobicity has long-term durability and excellent stability. Grounded on the strong water repellence, the resultant superhydrophobic copper plate surface exhibits multi-functions. The excellent performance can be well explained by “Cushion effect” and Capillary phenomena. As a result, water and corrosive species can be prevented from contacting with the copper plate surface, and contaminants can be taken away easily by the rolling water droplets. Meanwhile, the icing process of water is delayed on the superhydrophobic surface. Therefore, the superhydrophobic copper is endued with enhanced corrosion resistance, excellent self-cleaning and anti-icing performance. We believe that this facile method provides a simple and cost-effective process to improve the properties of copper plate, and which may see practical application of the superhydrophobic materials.


Author(s):  
Shuwei Lv ◽  
Xinming Zhang ◽  
Xiaodong Yang ◽  
Xianli Liu ◽  
Zhuojuan Yang ◽  
...  

Abstract Aluminum (Al) is a metal material commonly used in industry, but its surface is easily corroded. The superhydrophobic surface has great self-cleaning and anti-corrosion properties, and it is an ideal method to construct a functional aluminum surface. Here, a simple method based on cyclic chemical etching was proposed to achieve the superhydrophobic Al surface with honeycomb structures. The surface of the sample etched eight times comprised micro/nano-scale honeycomb cavities, while exhibiting a water contact angle (WCA) of 135°. After being treated with an octadecanethiol (C18H38S) methanol solution, this sample demonstrated a WCA of 153.1°. A self-cleaning test was performed on the superhydrophobic Al surface, showing the excellent self-cleaning property. Finally, the electrochemical anti-corrosion test demonstrated that the above-mentioned superhydrophobic Al surface had great corrosion resistance property. Overall, this work has enriched the theory and technology for fabricating aluminum to achieve superhydrophobic.


Micromachines ◽  
2020 ◽  
Vol 11 (2) ◽  
pp. 159 ◽  
Author(s):  
Xiaojuan Dong ◽  
Jianbing Meng ◽  
Yizhong Hu ◽  
Xiuting Wei ◽  
Xiaosheng Luan ◽  
...  

Aluminum alloys are widely used, but they are prone to contamination or damage under harsh working environments. In this paper, a self-cleaning superhydrophobic aluminum alloy surface with good corrosion resistance was successfully fabricated via the combination of sand peening and electrochemical oxidation, and it was subsequently covered with a fluoroalkylsilane (FAS) film. The surface morphology, surface wettability, and corrosion resistance were investigated using a scanning electron microscope (SEM), an optical contact angle measurement, and an electrochemical workstation. The results show that binary rough structures and an FAS film with a low surface energy on the Al alloy surfaces confer good superhydrophobicity with a water contact angle of 167.5 ± 1.1° and a sliding angle of 2.5 ± 0.7°. Meanwhile, the potentiodynamic polarization curve shows that the corrosion potential has a positively shifted trend, and the corrosion current density decreases by three orders of magnitude compared with that of the original aluminum alloy sample. In addition, the chemical stability of the as-prepared superhydrophobic surface was evaluated by dripping test using solutions with different pH values for different immersion time. It indicates that the superhydrophobic surface could provide long-term corrosion protection for aluminum alloys. Consequently, the as-prepared superhydrophobic surface has excellent contamination resistance and self-cleaning efficacy, which are important for practical applications.


2017 ◽  
Vol 728 ◽  
pp. 815-826 ◽  
Author(s):  
C.L. Zhang ◽  
F. Zhang ◽  
L. Song ◽  
R.C. Zeng ◽  
S.Q. Li ◽  
...  

Coatings ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 390 ◽  
Author(s):  
Qian Zhao ◽  
Tiantian Tang ◽  
Fang Wang

The development of a self-cleaning and corrosion resistant superhydrophobic coating for aluminum alloy surfaces that is durable in aggressive conditions has attracted great interest in materials science. In the present study, a superphydrophobic film was fabricated on an AA5052 aluminum alloy surface by the electrodeposition of Ni–Co alloy coating, followed by modification with 6-(N-allyl-1,1,2,2-tetrahydro-perfluorodecyl) amino-1,3,5-triazine-2,4-dithiol monosodium (AF17N). The surface morphology and characteristics of the composite coatings were investigated by means of scanning electron microscopy (SEM), energy dispersive X-ray spectrum (EDS), atomic force microscope (AFM) and contact angle (CA). The corrosion resistance of the coatings was assessed by electrochemical tests. The results showed that the surface exhibited excellent superhydrophobicity and self-cleaning performance with a contact angle maintained at 160° after exposed to the atmosphere for 240 days. Moreover, the superhydrophobic coatings significantly improved the corrosion resistant performance of AA5052 aluminum alloy substrate in 3.5 wt.% NaCl solution.


Nanoscale ◽  
2018 ◽  
Vol 10 (32) ◽  
pp. 15393-15401 ◽  
Author(s):  
Hanpeng Gao ◽  
Yan Liu ◽  
Shuyi Li ◽  
Guoyong Wang ◽  
Zhiwu Han ◽  
...  

The as-prepared superhydrophobic surface has a switchable contact angle and adhesion with good stability and corrosion resistance.


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