Template-etched sodium alginate hydrogel as the sublayer to improve the FO performance with double barriers for high metal ion rejection

2020 ◽  
pp. 127425
Author(s):  
Wei Huang ◽  
Lihua Zhao ◽  
Jiayan Zhang ◽  
Hao Wen ◽  
Ziyi Zhu ◽  
...  
2020 ◽  
Vol 22 (40) ◽  
pp. 23226-23236
Author(s):  
Eris Sinoimeri ◽  
Victor Maia Fernandes ◽  
Jérôme Cognard ◽  
Jorge Fernando Brandão Pereira ◽  
Lenka Svecova ◽  
...  

Large amounts of Fe(iii) or Fe(ii) strongly modify the biphasic behavior of the system P44414Cl/HCl/H2O while large amounts of Fe(iii) induce a biphasic regime for the mixture PEG-600/HCl/H2O.


2021 ◽  
pp. 118269
Author(s):  
Yueshan Li ◽  
Zhisen Wang ◽  
Xiaoyu Wang ◽  
Bin Yan ◽  
Yinjie Peng ◽  
...  

2007 ◽  
Vol 3 (1) ◽  
pp. 133-142 ◽  
Author(s):  
Ishaq Abdullah Zaafarany

Abstract          The kinetics of sol-gel transformation between A13+, La 3+ and Th4+ metal ion electrolytes and sodium alginate sol have been studied complexometrically at various  temperatures. In the presence of a large excess of sodium alginate sol concentration over that of metal ion electrolyte, the pseudo first–order plots of exchange showed sigmoidal curves with two distinct stages. The initial part was relatively fast and curved significantly at early times, followed by a slow decrease in the rates of exchange over longer time periods. The rate constants of gelation showed second-order overall kinetics which was first order in the concentration of both reactants. The thermodynamic parameters have been evaluated and tentative gelation mechanisms consistent with the kinetic results of gelation are suggested. The stability of these ionotropic metal-alginate complexes has been discussed in terms of the coordination geometry and strength of chelated bonds.


2014 ◽  
Vol 24 (1) ◽  
pp. 633-641 ◽  
Author(s):  
Peng Zhao ◽  
Cuijun Deng ◽  
Hongzhen Xu ◽  
Xing Tang ◽  
Hailong He ◽  
...  

2021 ◽  
Author(s):  
Xiao Zhang ◽  
Zhiyue Li ◽  
Taoyi Zhang ◽  
Jing Chen ◽  
Wenxi Ji ◽  
...  

A novel zeolitic imidazolate framework-8 (ZIF-8) alginate composite hydrogel material (PVA/SA@ZIF-8) is alginate composite bead which was fabricated by grafting ZIF-8 on the surface of the sodium alginate hydrogel beads...


2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Peter Kasak ◽  
Martin Danko ◽  
Sifani Zavahir ◽  
Miroslav Mrlik ◽  
Yuan Xiong ◽  
...  

Abstract We introduce a simple approach to fabricate fluorescent multivalent metal ion-free alginate hydrogels, which can be produced using carbon dots accessible from natural sources (citric acid and L-cysteine). Molecular fluorophore 5-oxo-2,3-dihydro-5H-[1,3]-thiazolo[3,2-a] pyridine-3,7-dicarboxylic acid (TPDCA), which is formed during the synthesis of carbon dots, is identified as a key segment for the crosslinking of hydrogels. The crosslinking happens through dynamic complexation of carboxylic acid groups of TPDCA and alginate cages along with sodium ions. The TPDCA derived hydrogels are investigated regarding to their thermal, rheological and optical properties, and found to exhibit characteristic fluorescence of this aggregated molecular fluorophore. Moreover, gradient hydrogels with tunable mechanical and optical properties and controlled release are obtained upon immersion of the hydrogel reactors in solutions of divalent metal ions (Ca2+, Cu2+, and Ni2+) with a higher affinity to alginate.


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