The effect of sintering temperature on the microstructure and phase transformation in tetragonal YSZ and LZ/YSZ composites

2016 ◽  
Vol 42 (2) ◽  
pp. 2456-2465 ◽  
Author(s):  
X.Y. Liu ◽  
X.Z. Wang ◽  
A. Javed ◽  
C. Zhu ◽  
G.Y. Liang
2014 ◽  
Vol 616 ◽  
pp. 194-198 ◽  
Author(s):  
Jian Feng Zhang ◽  
Rong Tu ◽  
Takashi Goto

WC-Co-cBN composites were consolidated by SPS at 1373 to 1673 K under a moderate pressure of 100 MPa. The addition of cBN increased the starting and finishing temperature of shrinkage and decreased the relative density of WC-Co. The relative density of WC-(10-20 vol%) cBN composites was about 97-100% at 1573 K and decreased with increasing the sintering temperature to 1673 K due to the phase transformation of cBN to hBN. The highest hardness and fracture toughness of WC-Co-20 vol% cBN composite sintered at 1573 K were 23.2 GPa and 8.0 MP m1/2, respectively.


2010 ◽  
Vol 24 (15n16) ◽  
pp. 2875-2879
Author(s):  
FANFEI ZHANG ◽  
YUE ZHANG ◽  
ANG LI ◽  
DAHAI ZHANG ◽  
ZONGPING LI

In the present work, a series of samples were prepared by pressureless sintering from the starting materials of Si 3 N 4 (α and/or β phases), SiO 2 and Li 2 CO 3. The phase transformation was studied with emphasis on the influence of sintering temperature and Li 2 CO 3 content. Related phase transformation was observed and analyzed by SEM and XRD and probable mechanisms were given, which will be helpful for the further explanation to the oxidation mechanism of Si 3 N 4 based ceramics at elevated temperature.


2022 ◽  
pp. 103-117
Author(s):  
Sukanto ◽  
Wahyono Suprapto ◽  
Rudy Soenoko ◽  
Yudy Surya Irawan

This study aims to determine the effect of milling time and sintering temperature parameters on the alumina transformation phase in the manufacture of Aluminium Matrix Composites (AMCs) reinforced by 20 % silica sand tailings using powder metallurgy technology. The matrix and fillers use waste to make the composites more efficient, clean the environment, and increase waste utilization. The milling time applied to the Mechanical Alloying (MA) process was 0.5, 6, 24, 48, and 96 hours, with a ball parameter ratio of 15:1 and a rotation of 93 rpm. Furthermore, hot compaction was carried out using a 100 MPa two-way hydraulic compression machine at a temperature of 300 °C for 20 minutes. The temperature variables of the sintering parameter process were 550, 600 to 650 °C, with a holding time of 10 minutes. Characterization of materials carried out included testing particle size, porosity, X-Ray Diffraction (XRD), SEM-Image, and SEM-EDX. The particle measurement of mechanical alloying processed, using Particle Size Analyzer (PSA) instrument and based on XRD data using the Scherrer equation, showed a relatively similar trend, decreasing particle size occurs when milling time was increased 0.5 to 24 hours. However, when the milling time increases to 48 and 96 hours, the particle size tends to increase slightly, due to cold-weld and agglomeration when the Mechanical Alloying is processed. The impact is the occurrence of the matrix and filler particle pairs in the cold-weld state. So, the results of XRD and SEM-EDX characterization showed a second phase transformation to form alumina compounds at a relatively low sintering temperature of 600 °C after the mechanical alloying process was carried out with a milling time on least 24 hours


2007 ◽  
Vol 280-283 ◽  
pp. 1013-1016 ◽  
Author(s):  
Ben Jun Cheng ◽  
Xing Zhong Guo ◽  
Li Li ◽  
Jian Ming Zheng

The mechanism of the effect that zircon additive had on the properties of 95-alumina ceramic was studied and compared with that of zirconia additive. The results show that zircon additive can decrease the sintering temperature of 95-alumina ceramic, the suitable content of zircon additive is 3% and the suitable sintering temperature is1630°C; under these conditions, the 95-alumina composite ceramic can obtain satisfactory sintering and mechanical properties. Compared with zirconia additive, besides the stress-induced-phase-transformation of ZrO2 and micro-cracks, the toughened mechanism of 95-alumina ceramic with zircon additive also includes zirconia secondary crystallization in the liquid phase.


2009 ◽  
Vol 417-418 ◽  
pp. 549-552
Author(s):  
Burak Özkal ◽  
Tugba Uçar

Different amounts of fiber added samples were prepared by standard ceramic processing routes and sintered at different temperatures. Although powder packing characteristics of the matrix material were negatively affected with increasing fiber content; certain improvements were observed for the density, MOR and water absorption values both for green and sintered states. Fracture surfaces of the samples after three-point bending test were investigated via detailed SEM observations and phase analyses were performed by XRD measurements. It is found that phase transformation controlled fiber-matrix integration starts with increasing sintering temperature and degree of bonding between fiber/matrix interfaces can be arranged by selecting optimum sintering temperature. Aluminosilicate fiber addition was found efficient for improving mechanical properties of clay-kaolin matrix and the mechanism of the improvement can be grouped into two categories i.e. (1) brittle fiber – brittle matrix interactions via well known pulled-out, crack deflection and bridging mechanisms prior to fiber-matrix integration (2) further densification via phase transformation controlled fiber-matrix integration after high sintering temperatures.


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