Low temperature pressureless sintering of silicon nitride ceramics for circuit substrates in powder electronic devices

2018 ◽  
Vol 44 (4) ◽  
pp. 4375-4380 ◽  
Author(s):  
Yusen Duan ◽  
Jingxian Zhang ◽  
Xiaoguang Li ◽  
Ying Shi ◽  
Jianjun Xie ◽  
...  
2007 ◽  
Vol 554 ◽  
pp. 107-112 ◽  
Author(s):  
V. Demir ◽  
Derek P. Thompson

Silicon nitride samples were pressureless sintered with up to 5 w/o MgO to give densities in the range 98-99% of theoretical. After pressureless sintering, selected samples were placed in a vacuum heat treatment furnace surrounded by a carbon bed in a carbon crucible at a pressure of less than 4x10-4 mbar, and vacuum heat treated at different temperatures and times to remove grainboundary glass. The results showed that this was substantially achieved at 1575oC for 3h and that increasing the time to 5 hours gave still further improvement. SEM images, EDX analysis and oxidation tests provided additional evidence for the removal of Mg from the samples.


2008 ◽  
Vol 22 (09n11) ◽  
pp. 1819-1826 ◽  
Author(s):  
KIL HO GUAHK ◽  
IN SUB HAN ◽  
KEE SUNG LEE

Strength degradations in silicon nitride ceramics subject to damage from contact with hard spheres are investigated. Strengths against indentation load, number of cycles in contact, or stress-rate parameter are reported and compared with theoretical models. Silicon nitride ceramics are prepared by nitride pressureless sintering (NPS) process, which process is the continuous process of nitridation reaction of Si metal combined with subsequent pressureless sintering. Microstructure characterizations reveal silicon nitride fabricated by NPS process exhibits a quasi-plastic mode, with continuous strength loss beyond a load above the onset of yield, and falloff at high number of cycles, > 105 at contact load, P = 950 N , using WC sphere r = 1.98 mm . The strength degradation is substantially faster by dynamic fatigue. Failures originated from contact damages, quasi-plastic microcrack zones, with developing radial cracks during strength test. The implication is that quasi-plastic damage of NPS silicon nitride itself can preserve benefits from the inherent higher damage tolerance at lower number of cycles of contacts, but fatigue susceptibility at multicycle contacts and lower stressing rate.


2017 ◽  
Vol 43 (13) ◽  
pp. 10123-10129 ◽  
Author(s):  
Qingyu Meng ◽  
Zhihao Zhao ◽  
Yongqiang Sun ◽  
Xiaolei Li ◽  
Huiming Ji

2006 ◽  
Vol 45 ◽  
pp. 1717-1722 ◽  
Author(s):  
José Carlos Bressiani ◽  
Luis Antonio Genova

Densification curves of silicon nitride specimens with varying composition were determined with the aid of a dilatometer and these curves are presented in this paper. A novel procedure has been used to determine the densification curves as well as the temperature at which the rate of densification was highest. From these data, sintering profiles have been proposed to produce silicon nitride based ceramics with high apparent density (above 96% of theoretical density) at temperatures as low as 1520º C, with incipient grain growth. This procedure also enabled efficient separation of the densification and grain growth phenomena and it can be used in other two-step sintering studies.


2016 ◽  
Vol 42 (10) ◽  
pp. 11593-11597 ◽  
Author(s):  
Wenmiao Zeng ◽  
Xueping Gan ◽  
Zhiyou Li ◽  
Kechao Zhou

2008 ◽  
Vol 403 ◽  
pp. 23-26 ◽  
Author(s):  
Toyohiko Yano ◽  
Junichi Yamane ◽  
Katsumi Yoshida

For the transmutation of the very long half-lived isotopes which are separated from the spent nuclear fuels, it is necessary to find proper inert matrices these are stable under heavy neutron irradiation at high temperature. Silicon nitride ceramics is a candidate since it is very tolerant for heavy neutron irradiation and keeps relatively high thermal conductivity. For these reasons, we try to sinter Si3N4 ceramics containing large amounts of CeO2 as a simulant for Am2O3, a typical transuranium element. The low-temperature pressureless-sintering behavior of the ceramics and chemical and thermal properties of the obtained sintered bodies are reported.


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