scholarly journals Influence of number of azo bonds and mass transport limitations towards the elimination capacity of continuous electrochemical process for the removal of textile industrial dyes

Chemosphere ◽  
2021 ◽  
Vol 262 ◽  
pp. 128381
Author(s):  
Jaanavee Alagesan ◽  
MecghaSri Jaisankar ◽  
Sindhu Muthuramalingam ◽  
Emmanuel Mousset ◽  
Padmanaban Velayudhaperumal Chellam
1979 ◽  
Vol 44 ◽  
pp. 349-355
Author(s):  
R.W. Milkey

The focus of discussion in Working Group 3 was on the Thermodynamic Properties as determined spectroscopically, including the observational techniques and the theoretical modeling of physical processes responsible for the emission spectrum. Recent advances in observational techniques and theoretical concepts make this discussion particularly timely. It is wise to remember that the determination of thermodynamic parameters is not an end in itself and that these are interesting chiefly for what they can tell us about the energetics and mass transport in prominences.


Author(s):  
Rebecca W. Keller ◽  
Carlos Bustamante ◽  
David Bear

Under ideal conditions, the Scanning Tunneling Microscope (STM) can create atomic resolution images of different kinds of samples. The STM can also be operated in a variety of non-vacuum environments. Because of its potentially high resolution and flexibility of operation, it is now being applied to image biological systems. Several groups have communicated the imaging of double and single stranded DNA.However, reproducibility is still the main problem with most STM results on biological samples. One source of irreproducibility is unreliable sample preparation techniques. Traditional deposition methods used in electron microscopy, such as glow discharge and spreading techniques, do not appear to work with STM. It seems that these techniques do not fix the biological sample strongly enough to the substrate surface. There is now evidence that there are strong forces between the STM tip and the sample and, unless the sample is strongly bound to the surface, it can be swept aside by the tip.


1984 ◽  
Vol 45 (C2) ◽  
pp. C2-285-C2-288
Author(s):  
I. B. Borovskii ◽  
D. D. Gorodskii ◽  
I. M. Sharafeev
Keyword(s):  

2003 ◽  
Vol 8 (1) ◽  
pp. 3-18 ◽  
Author(s):  
R. Baronas ◽  
F. Ivanauskas ◽  
J. Kulys

A mathematical model of amperometric biosensors has been developed to simulate the biosensor response in stirred as well as non stirred solution. The model involves three regions: the enzyme layer where enzyme reaction as well as mass transport by diffusion takes place, a diffusion limiting region where only the diffusion takes place, and a convective region, where the analyte concentration is maintained constant. Using computer simulation the influence of the thickness of the enzyme layer as well the diffusion one on the biosensor response was investigated. The computer simulation was carried out using the finite difference technique.


1996 ◽  
Vol 451 ◽  
Author(s):  
T. P. Moffat

ABSTRACTA variety of Cu/(Ni, Co) multilayers have been grown on Cu single crystals by pulse plating from an alloy electroplating bath. Copper is deposited under mass transport control while the iron group metal is deposited under interfacial charge transfer control. The structural evolution of these films is influenced by the morphological instability of the mass transport limited copper deposition reaction and the development of growth twins during iron-group metal deposition. Specular films have been obtained for growth on Cu(100) while rough, defective films were typically obtained for growth on Cu(111) and Cu(110).


2016 ◽  
pp. 3287-3297
Author(s):  
Tarek El Ashram ◽  
Ana P. Carapeto ◽  
Ana M. Botelho do Rego

Tin-bismuth alloy ribbons were produced using melt-spinning technique. The two main surfaces (in contact with the rotating wheel and exposed to the air) were characterized with Optical Microscopy and AFM, revealing that the surface exposed to the air is duller (due to a long-range heterogeneity) than the opposite surface. Also the XPS chemical composition revealed many differences between them both on the corrosion extension and on the total relative amounts of tin and bismuth. For instance, for the specific case of an alloy with a composition Bi-4 wt % Sn, the XPS atomic ratios Sn/Bi are 1.1 and 3.7 for the surface in contact with the rotating wheel and for the one exposed to air, respectively, showing, additionally, that a large segregation of tin at the surface exists (nominal ratio should be 0.073). This segregation was interpreted as the result of the electrochemical process yielding the corrosion products.


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