Enhancing the catalytic performance of calcium-based catalyst derived from gypsum waste for renewable light fuel production through a pyrolysis process: A study on the effect of magnesium content

Chemosphere ◽  
2022 ◽  
pp. 133516
Author(s):  
Wasipim Chansiriwat ◽  
Kitirote Wantala ◽  
Rattabal Khunphonoi ◽  
Pongtanawat Khemthong ◽  
Totsaporn Suwannaruang ◽  
...  
Keyword(s):  
Magnesium Content ◽  
Catalytic Performance ◽  
Pyrolysis Process ◽  
Fuel Production

scholarly journals Ag3PO4Semiconductor Photocatalyst: Possibilities and Challenges

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Gui-Fang Huang ◽  
Zhi-Li Ma ◽  
Wei-Qing Huang ◽  
Yong Tian ◽  
Chao Jiao ◽  
...  
Keyword(s):  
Recent Progress ◽  
Photocatalytic Performance ◽  
Catalytic Performance ◽  
Future Research ◽  
Fuel Production ◽  
Theoretical Understanding ◽  
Research Activities ◽  
Composite Photocatalysts ◽  
The Stability ◽  
Exposed Facets

Ag3PO4as a photocatalyst has attracted enormous attention in recent years due to its great potential in harvesting solar energy for environmental purification and fuel production. The photocatalytic performance of Ag3PO4strongly depends on its morphology, exposed facets, and particle size. The effects of morphology and orientation of Ag3PO4on the catalytic performance and the efforts on the stability improvement of Ag3PO4are reviewed here. This paper also discusses the current theoretical understanding of photocatalytic mechanism of Ag3PO4, together with the recent progress towards developing Ag3PO4composite photocatalysts. The crucial issues that should be addressed in future research activities are finally highlighted.

Production of Phenolic Compounds from Low Temperature Catalytic Fast Pyrolysis of Biomass with Activated Carbon

2014 ◽  
Vol 541-542 ◽  
pp. 190-194 ◽  
Author(s):  
Zhi Bo Zhang ◽  
Xiao Ning Ye ◽  
Qiang Lu ◽  
Chang Qing Dong ◽  
Yong Qian Liu
Keyword(s):  
Activated Carbon ◽  
Phenolic Compounds ◽  
Fast Pyrolysis ◽  
Product Distribution ◽  
Catalytic Performance ◽  
Gas Chromatography Mass Spectrometry ◽  
Pyrolysis Process ◽  
Pyrolysis Gas ◽  
Catalytic Fast Pyrolysis ◽  
Pyrolysis Of Biomass

Activated carbon (AC) was reported as a promising catalyst to selectively produce phenolic compounds from biomass using the micro-wave assisted catalytic pyrolysis technique. In order to evaluate the catalytic performance of the AC under the traditional fast pyrolysis process, analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) technique was applied for the catalytic fast pyrolysis of biomass mixed with the AC. Polar wood was selected as the feedstock, and experiments were conducted to reveal the AC-catalyzed poplar wood pyrolysis behavior and product distribution. The results indicated that the AC was also effective for the phenolics production in the traditional fast pyrolysis process at 350 °C. It could promote the formation of phenolic compounds, and inhibit most of the other pyrolytic products. The maximal phenolics yield was obtained at the biomass to catalyst ratio of 1:4, with the peak area% over 50%.

Enhanced Liquid Fuel Production from CO2 Hydrogenation: Catalytic Performance of Bimetallic Catalysts over a Two-Stage Reactor System

2018 ◽  
Vol 3 (48) ◽  
pp. 13705-13711 ◽  
Author(s):  
Lisheng Guo ◽  
Yu Cui ◽  
Peipei Zhang ◽  
Xiaobo Peng ◽  
Yoshiharu Yoneyama ◽  
...  
Keyword(s):  
Bimetallic Catalysts ◽  
Liquid Fuel ◽  
Catalytic Performance ◽  
Co2 Hydrogenation ◽  
Reactor System ◽  
Fuel Production ◽  
Two Stage

scholarly journals Synthetic fuel production from shredded scrap waste

2017 ◽  
Vol 26 (44) ◽  
pp. 133
Author(s):  
Iván Ernesto Barragán-Gutiérrez ◽  
Alfonso López-Díaz ◽  
Wolfgang Krumm
Keyword(s):  
Internal Combustion Engines ◽  
Physicochemical Characterization ◽  
Combustion Engines ◽  
Pyrolysis Process ◽  
Synthetic Fuels ◽  
Fuel Production ◽  
Processing Technologies ◽  
Innovation Project ◽  
Definition Of

This technological innovation project involved material identification, and design, installation, implementation, and evaluation of a pilot plant with capacity of 10 t per batch to recover materials and produce synthetic fuels (oil, syngas and solid) from shredded scrap waste. The results showed the proper way to separate materials (metals, and organic and inert compounds), and to perform the pyrolysis process to produce gas, oil, and coke as synthetic fuels from organic waste. The process started with the physicochemical characterization of the waste, followed by the selection of separation, sorting and processing technologies, and the definition of pyrolysis process parameters. Finally, the synthetic fuels were characterized, and uses for the furnace billet, ladle preheating, internal combustion engines, and auto generation were suggested. The results showed 82 % recovery of magnetic and non-magnetic metals, and production of synthetic fuels with PCI between 20 650 and 36 900 kJ/kg.

Cs promoted Fe5C2/charcoal nanocatalysts for sustainable liquid fuel production

RSC Advances ◽  
2015 ◽  
Vol 5 (55) ◽  
pp. 44211-44217 ◽  
Author(s):  
Ji Chan Park ◽  
Dong Hyun Chun ◽  
Jung-Il Yang ◽  
Ho-Tae Lee ◽  
Sungjun Hong ◽  
...  
Keyword(s):  
High Temperature ◽  
Liquid Fuel ◽  
Catalytic Performance ◽  
Fuel Production ◽  
Fischer Tropsch ◽  
Impregnation Process ◽  
Melt Infiltration ◽  
Excellent Catalytic Performance

Cs promoted Fe5C2/charcoal nanocatalysts especially at Cs/Fe = 0.025, prepared by a melt-infiltration and a wetness impregnation process, demonstrated an excellent catalytic performance for the high-temperature Fischer–Tropsch reaction.

The design and catalytic performance of molybdenum active sites on an MCM-41 framework for the aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran

2019 ◽  
Vol 9 (3) ◽  
pp. 811-821 ◽  
Author(s):  
Zhao-Meng Wang ◽  
Li-Juan Liu ◽  
Bo Xiang ◽  
Yue Wang ◽  
Ya-Jing Lyu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Active Sites ◽  
Aerobic Oxidation ◽  
Catalytic Performance ◽  
Mcm 41

The catalytic activity decreases as –(SiO)3Mo(OH)(O) > –(SiO)2Mo(O)2 > –(O)4–MoO.

Optimizing electron density of nickel sulfide electrocatalysts through sulfur vacancy engineering for alkaline hydrogen evolution

2020 ◽  
Vol 8 (35) ◽  
pp. 18207-18214
Author(s):  
Dongbo Jia ◽  
Lili Han ◽  
Ying Li ◽  
Wenjun He ◽  
Caichi Liu ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Electron Density ◽  
Rational Design ◽  
Nickel Sulfide ◽  
Catalytic Performance ◽  
Sulfide Catalysts ◽  
Sulfur Vacancy

A novel, rational design for porous S-vacancy nickel sulfide catalysts with remarkable catalytic performance for alkaline HER.

Estimation of Recoverable Household Waste Cooking Oil and Life Cycle Analysis of Biodiesel Fuel Production

2008 ◽  
Vol 4 (4) ◽  
pp. 318-323 ◽  
Author(s):  
Hirotsugu KAMAHARA ◽  
Shun YAMAGUCHI ◽  
Ryuichi TACHIBANA ◽  
Naohiro GOTO ◽  
Koichi FUJIE
Keyword(s):  
Life Cycle ◽  
Life Cycle Analysis ◽  
Waste Cooking Oil ◽  
Household Waste ◽  
Biodiesel Fuel ◽  
Fuel Production ◽  
Cooking Oil

Valorisation of by-Products/Waste of Agro-Food Industry by the Pyrolysis Process

2016 ◽  
Vol 3 (1) ◽  
pp. 1-11 ◽  
Author(s):  
D. Fino ◽  
◽  
Y.S. Camacho ◽  
S Bensaid ◽  
B. Ruggeri ◽  
...  
Keyword(s):  
Food Industry ◽  
Pyrolysis Process ◽  
By Products

Catalytic Resonance Theory: Parallel Reaction Pathway Control

2019 ◽  
Author(s):  
M. Alexander Ardagh ◽  
Manish Shetty ◽  
Anatoliy Kuznetsov ◽  
Qi Zhang ◽  
Phillip Christopher ◽  
...  
Keyword(s):  
Chemical Reactions ◽  
Active Site ◽  
Active Sites ◽  
Reaction Pathway ◽  
Control Strategies ◽  
Oscillation Amplitude ◽  
Catalytic Performance ◽  
Parallel Reaction ◽  
Resonance Theory ◽  
Static Conditions

Catalytic enhancement of chemical reactions via heterogeneous materials occurs through stabilization of transition states at designed active sites, but dramatically greater rate acceleration on that same active site is achieved when the surface intermediates oscillate in binding energy. The applied oscillation amplitude and frequency can accelerate reactions orders of magnitude above the catalytic rates of static systems, provided the active site dynamics are tuned to the natural frequencies of the surface chemistry. In this work, differences in the characteristics of parallel reactions are exploited via selective application of active site dynamics (0 < ΔU < 1.0 eV amplitude, 10<sup>-6</sup> < f < 10<sup>4</sup> Hz frequency) to control the extent of competing reactions occurring on the shared catalytic surface. Simulation of multiple parallel reaction systems with broad range of variation in chemical parameters revealed that parallel chemistries are highly tunable in selectivity between either pure product, even when specific products are not selectively produced under static conditions. Two mechanisms leading to dynamic selectivity control were identified: (i) surface thermodynamic control of one product species under strong binding conditions, or (ii) catalytic resonance of the kinetics of one reaction over the other. These dynamic parallel pathway control strategies applied to a host of chemical conditions indicate significant potential for improving the catalytic performance of many important industrial chemical reactions beyond their existing static performance.

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