A modeling approach for soot formation in non-premixed flames with elevated stoichiometric mixture fraction

2021 ◽  
Vol 229 ◽  
pp. 111383
Author(s):  
Phillip R. Johnson ◽  
Rajan K. Chakrabarty ◽  
Benjamin M. Kumfer
Processes ◽  
2021 ◽  
Vol 9 (10) ◽  
pp. 1756
Author(s):  
Chaoyang Wang ◽  
Guangtong Tang ◽  
Huibo Yan ◽  
Lujiang Li ◽  
Xiaopei Yan ◽  
...  

Oxy-combustion with high flame temperature, low heat loss, high combustion efficiency, and low NOx emissions is being extensively studied. The thermal radiation from soot particles and gases in oxy-combustion accounts for the vast majority of the total heat transfer. Based on a detailed chemical reaction mechanism coupled with the soot particle dynamics model and optically thin radiation model, the influence of the flame structure and temperature distribution on the thermal radiation in oxygen-enriched counterflow diffusion flames was studied in this paper. The results revealed that reasonable assignment of total recycled flue gas and the degree of dilution of fuel and oxidant were critical, which can be used to adjust the overall radiation situation of the flame. At the same adiabatic flame temperature, as the fuel concentration decreased and the oxidant concentration increased (the stoichiometric mixture ratio is from 0.3 to 0.6), the soot formation decreased, which led to the particle radiation disappearing while the main radiation zone of gases moved 0.04 cm toward the fuel side. At the same stoichiometric mixture fraction (0.4), the radiation area was broadened and the radiation of soot particles was gradually enhanced with the adiabatic flame increasing from 2300 K to 2700 K.


1991 ◽  
Vol 84 (3-4) ◽  
pp. 265-276 ◽  
Author(s):  
J.M. Janssen ◽  
D.W. Senser

2021 ◽  
Author(s):  
Amit Makhija ◽  
Krishna Sesha Giri

Abstract Soot volume fraction predictions through simulations carried out on OpenFOAM® are reported in diffusion flames with ethylene fuel. A single-step global reaction mechanism for gas-phase species with an infinitely fast chemistry assumption is employed. Traditionally soot formation includes inception, nucleation, agglomeration, growth, and oxidation processes, and the individual rates are solved to determine soot levels. However, in the present work, the detailed model is replaced with the soot formation and oxidation rates, defined as analytical functions of mixture fraction and temperature, where the net soot formation rate can be defined as the sum of individual soot formation and oxidation rates. The soot formation/oxidation rates are modelled as surface area-independent processes. The flame is modelled by solving conservation equations for continuity, momentum, total energy, and species mass fractions. Additionally, separate conservation equations are solved to compute the mixture fraction and soot mass fraction consisting of source terms that are identical and account for the mixture fraction consumption/production due to soot. As a consequence, computational time can be reduced drastically. This is a quantitative approach that gives the principal soot formation regions depending on the combination of local mixture fraction and temperature. The implemented model is based on the smoke point height, an empirical method to predict the sooting propensity based on fuel stoichiometry. The model predicts better soot volume fraction in buoyant diffusion flames. It was also observed that the optimal fuel constants to evaluate soot formation rates for different fuels change with fuel stoichiometry. However, soot oxidation strictly occurs in a particular region in the flame; hence, they are independent of fuel. The numerical results are compared with the experimental measurements, showing an excellent agreement for the velocity and temperature. Qualitative agreements are observed for the soot volume fraction predictions. A close agreement was obtained in smoke point prediction for the overventilated flame. An established theory through simulations was also observed, which states that the amount of soot production is proportional to the fuel flow rate. Further validations underscore the predictive capabilities. Model improvements are also reported with better predictions of soot volume fractions through modifications to the model constants based on mixture fraction range.


Author(s):  
Masoud Darbandi ◽  
Majid Ghafourizadeh

In this work, we numerically study the effects of turbulence intensity at the fuel and oxidizer stream inlets on the soot aerosol nano-particles formation in a kerosene fuel-based combustor. In this regard, we study the turbulence intensity effects specifically on the thermal performance and nano-particulate soot aerosol emissions. To construct our computer model, we simulate the soot formation and oxidation using the Polycyclic Aromatic Hydrocarbons PAHs-inception and the hydroxyl concept, respectively. Additionally, the soot nucleation process is described using the phenyl route, in which the soot inception is described based on the formations of two-ringed and three-ringed aromatics from acetylene, benzene, and phenyl radical. We use the two-equation soot model in which the soot mass fraction and the soot number density transport equations are solved considering the evolutionary process of soot nanoparticles, where all the nucleation, coagulation, surface growth, and oxidation phenomena are suitable considered in calculations. For the combustion modeling part, we benefit from the flamelets library, i.e., a lookup table, considering a detailed chemical kinetic mechanism consisting of 121 species and 2613 elementary reactions and solve the transport equations for the mean mixture fraction and its variance. We take into account the turbulence-chemistry interaction using the presumed-shape probability density functions PDFs. We apply the two-equation high-Reynolds-number k-ε turbulence model with round-jet corrections and suitable wall functions in performing our turbulence modeling. Solving the transport equations of turbulence kinetic energy and its dissipation rate, the turbulence closure problem can be resolved suitably. Furthermore, we take into account the radiation heat transfer of soot and gases assuming optically-thin flame, in which the radiation heat transfer of the most important radiating species is determined locally through the emissions. To evaluate our numerical solutions, we first solve an available well-documented experimental test, which provides the details of a kerosene-fueled turbulent nonpremixed flame. Then, we compare the achieved flame structure, i.e., the distributions of mean mixture fraction, temperature, and soot volume fraction, with those measured in the experiment. Next, we change the turbulence intensities of the incoming fuel and oxidizer streams gradually. So, we become able to evaluate the effects of different turbulence intensities on the achieved temperature and soot aerosol concentrations. Our results show that using moderate turbulence intensities at both fuel and oxidizer stream inlets would effectively increase the maximum temperature inside the combustor and this would reduce the exhaust gases temperature. It also reduces the concentrations of soot in the combustor and its emission to the exhaust gases effectively.


Author(s):  
Pravin Nakod ◽  
Saurabh Patwardhan ◽  
Ishan Verma ◽  
Stefano Orsino

Emission standard agencies are coming up with more stringent regulations on soot, given its adverse effect on human health. It is expected that Environmental Protection Agency (EPA) will soon place stricter regulations on allowed levels of the size of soot particles from aircraft jet engines. Since, aircraft engines operate at varying operating pressure, temperature and air-fuel ratios, soot fraction changes from condition to condition. Computation Fluid Dynamics (CFD) simulations are playing a key role in understanding the complex mechanism of soot formation and the factors affecting it. In the present work, soot formation prediction from numerical analyses for turbulent kerosene-air diffusion jet flames at five different operating pressures in the range of 1 atm. to 7 atm. is presented. The geometrical and test conditions are obtained from Young’s thesis [1]. Coupled combustion-soot simulations are performed for all the flames using steady diffusion flamelet model for combustion and Mass-Brookes-Hall 2-equation model for soot with a 2D axisymmetric mesh. Combustion-Soot coupling is required to consider the effect of soot-radiation interaction. Simulation results in the form of axial and radial profiles of temperature, mixture fraction and soot volume fraction are compared with the corresponding experimental measured profiles. The results for temperature and mixture fraction compare well with the experimental profiles. Predicted order of magnitude and the profiles of the soot volume fraction also compare well with the experimental results. The correct trend of increasing the peak soot volume fraction with increasing the operating pressure is also captured.


2018 ◽  
Vol 22 (5) ◽  
pp. 862-882 ◽  
Author(s):  
Zhi X. Chen ◽  
N. Anh Khoa Doan ◽  
Shaohong Ruan ◽  
Ivan Langella ◽  
N. Swaminathan

2019 ◽  
Vol 37 (4) ◽  
pp. 4571-4578 ◽  
Author(s):  
Chun Lou ◽  
Xiaobing Chen ◽  
Weijie Yan ◽  
Yanfei Tian ◽  
Benjamin M. Kumfer

2021 ◽  
Author(s):  
Edison E. Chukwuemeka ◽  
Ingmar M. Schoegl

Abstract Characteristics of non-premixed flames such as flame height and lift-off height are affected by the presence of magnetic fields due to the paramagnetic properties of some combustion species. However, it is unknown whether magnetic fields can be used to reduce the emission of pollutants in non-premixed flames. In general, pollutant emissions are reduced in combustion systems if the mixing of combustion species is enhanced during the process. Since paramagnetic combustion species such as O2, O, OH, HO2, etc have a preferential motion direction in the presence of magnetic fields, there is a potential to harness this effect of mixing by imposing a magnetic field on the flame. This study seeks to provide some insights on the effect of magnetic field on pollutants generated in a laminar non-premixed flame numerically. The non-premixed flame is simulated using a detailed chemical mechanism for propane-air combustion and a modified Moss-Brookes soot model. To simulate the effect of magnetism on the paramagnetic chemical species, the species paramagnetic susceptibility is computed using the Curie relation. The non-premixed flame is placed at three different locations within the magnetic field. The computation predicted that the amount of average pollutants reduction is dependent on the location of the flames within the magnetic fields with respect to magnetic gradients. The mass weighted average of the soot volume fraction over the computational domain decreased when the non-premixed flame is located at certain locations within the magnetic field of the solenoid with respect to the absence of the magnetic fields, but increases in other locations.


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