Effect of RF-plasma deposition parameters on the composition and properties of organic layers deposited on glass fibers

2009 ◽  
Vol 69 (14) ◽  
pp. 2485-2490 ◽  
Author(s):  
R. Balkova ◽  
J. Jancar ◽  
V. Cech
1991 ◽  
Author(s):  
A. Shah ◽  
E. Narumi ◽  
J. Schutkeker ◽  
S. Patel ◽  
D. T. Shaw

Author(s):  
V. Barbarossa ◽  
O. Martini ◽  
S. Mercuri ◽  
R. Tomaciello ◽  
F. Galluzzi
Keyword(s):  

Author(s):  
S. Patel ◽  
A. Shah ◽  
D. T. Shaw
Keyword(s):  

2001 ◽  
Vol 142-144 ◽  
pp. 163-168 ◽  
Author(s):  
Mariadriana Creatore ◽  
Fabio Palumbo ◽  
Riccardo d'Agostino ◽  
Pierre Fayet

1996 ◽  
Vol 434 ◽  
Author(s):  
U. Müller ◽  
R. Hauert

AbstractAmorphous hydrogenated carbon films are of technological interest as protection coatings due to their special properties such as high hardness, chemical inertness, electrical insulation and infrared transparency. However, some applications still suffer from the poor thermal stability and adhesion problems of these coatings. To ensure good adhesion, especially on hardened steels and non-carbide forming substrates, an extra interlayer has to be deposited first. Often a silicon containing interlayer, Si-a-C:H for example, is used for this purpose. This Si-a-C:H interface layer was deposited by rf plasma deposition from tetramethylsilane. Then a-C:H films containing Si-O with a varying silicon content were produced from a mixture of acetylene and hexamethyldisiloxane. The structural changes upon annealing of these films were investigated using Raman spectroscopy. The analysis of the development of the different peaks upon annealing temperature reveals the transition from the amorphous structure to the more graphitic-like structure. This transition temperature increases by as much as 100°C when silicon is incorporated into the DLC film. However, when Si-O is incorporated instead of only silicon the same increase in temperature stability is observed.


2006 ◽  
Vol 200 (22-23) ◽  
pp. 6405-6408 ◽  
Author(s):  
Peter C.T. Ha ◽  
D.R. McKenzie ◽  
M.M.M. Bilek ◽  
E.D. Doyle ◽  
D.G. McCulloch ◽  
...  

1990 ◽  
Vol 192 ◽  
Author(s):  
Yoshihiro Hishikawa ◽  
Sadaji Tsuge ◽  
Noboru Nakamura ◽  
Shinya Tsuda ◽  
Shoichi Nakano ◽  
...  

ABSTRACTWide-gap a-Si:H films with device quality (Tauc’s optical gap > 1.9eV, σph under AMI.5, 100mW/cm2 illumination ≥ 10−5, Ω−1cm−1, a σph/σ a≥106) have been fabricated. These films are deposited at low substrtate temperatures (TS≤80°C ) either by diluting SiH4 with H2 or optimizing the plasma parameters in a capacitively–coupled RF plasma–CVD reactor. Reduction in the SiH2 bond density and the ESR spin density are also observed. In this study, good film quality is always accompanied by a small deposition rate. Furthermore, σph is nearly the same if the deposition rate and Ts is the same, regardless of other deposition parameters. This suggests that the surface reactions or structural relaxations at the film-growing surface can produce high–quality a–Si:H films even at low TsS, if the deposition rate is low. Results in thermal annealing, light exposure, and solar cell performance confirm that these films have device quality and wide bandgap.


2001 ◽  
Vol 32 (9) ◽  
pp. 783-786 ◽  
Author(s):  
Marco A.R. Alves ◽  
Jônatas F. Rossetto ◽  
Olga Balachova ◽  
Edmundo da Silva Braga ◽  
Lucila Cescato

1996 ◽  
Vol 441 ◽  
Author(s):  
Woon Choi ◽  
Dong-Hoon Shin ◽  
Seoung-Eui Nam ◽  
Hyoung-June Kim

AbstractHydrogenated DLC films were synthesized by RF plasma deposition with and without magnetic enhancement, and their film stresses were investigated as a function of process parameters. Under investigated process conditions, Vb/P1/2 (where Vb is the self-bias voltage and P is the working pressure) is the appropriate scaling factor representing impinging ion energy. Film stress is influenced by not only ion impinging energy but also by ion to adspecies flux ratios. As ion energy increases, film stresses increase to a maximum value corresponding to the highest number of sp3 carbon bonds. As ion/adspecies flux ratio increases, the maximum stress value decreases and the corresponding ion energy increases. Induction of a magnetic field promotes film stresses as high as 15.2 GPa, which is one of the highest value reported in hydrogenated DLC films. The magnetic-induced increase of stress can be explained by increased ion/adspecies flux ratio, thus, enhanced sp3 formation. Rapid reduction of stresses observed at high ion energies may stem from the formation of graphite (sp2 bond) phases. Inclusion of hydrogen in the films is not directly responsible for the stress generation.


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