Physical mechanism for photon emissions from group-IV-semiconductor quantum-dots in quartz-glass and thermal-oxide layers

We experimentally studied the influence of both impurity density and dangling-bond density on PL emissions from group-IV-semiconductor quantum-dots (IV-QDs) of Si and SiC fabricated by hot-ion implantation technique, to improve the PL intensity (IPL) from IV-QDs embedded in two types of insulators of quartz glass (QZ) with low impurity density and thermal-oxide (OX) layers. First, we verified the IPL reduction in the IV-QDs in QZ. However, we demonstrated the IPL enhancement of IV-QDs in doped QZ, which is attributable to multiple-level emission owing to acceptor and donor ion implantations into QZ. Secondly, we confirmed the large IPL enhancement of IV-QDs in QZ and OX, owing to forming gas annealing with H2/N2 mixed gas, which are attributable to the reduction of the dangling-bond density in IV-QDs. Consequently, it is possible to improve the IPL of IV-QDs by increasing impurity density and reducing dangling-bond density.

Perspective/Discussion on “Quantum Mechanical Metric for Internal Cohesion in Cement Crystals” by C. C. Dharmawardhana, A. Misra and Wai-Yim Ching

The single most important structural material, and the major Portland cement binding phase in application globally, is calcium silicate hydrate (C-S-H). The concentration has increasingly changed due to its atomic level comprehension because of the chemistry and complex structures of internal C-S-H cohesion in cement crystals at different lengths. This perspective aimed at describing on calcium-silicate-hydrates (C-S-H) structures with differing contents of Ca/Si ratio based on the report entitled “Quantum mechanical metric for internal cohesion in cement crystals” published by C. C. Dharmawardhana, A. Misra and Wai-Yim Ching. Crystal structural and bond behaviors in synthesized C-S-H were also discussed. The investigator studied large subset electronic structures and bonding of the common C-S-H minerals. From each bonding type, the results and findings show a wide variety of contributions, particularly hydrogen bonding, that allow critical analyses of spectroscopic measurement and constructions of practical C-S-H models. The investigator found that the perfect overall measurement for examining crystal cohesions of the complex substances is the total bond density (TBOD), which needs to be substituted for traditional metrics such as calcium to silicon ratios. In comparison to Tobermorite and Jennite, hardly known orthorhombic phased Suolunites were revealed to have greater cohesion and total order distribution density than those of the hydrated Portland cement backbone. The findings of the perspective showed that utilizing quantum mechanical metrics, the total bond orders and total bond order distributions are the most vital criteria for assessing the crystalline cohesions in C-S-H crystals. These metrics encompass effects of both interatomic interactions and geometric elements. Thus, the total bond order distribution and bond order offer comprehensive and in-depth measures for the overall behaviors of these diverse groups of substances. The total bond order distributions must clearly be substituted for the conventional and longstanding Ca/Si ratios applied in categorizing the cement substances. The inconspicuous Suolunite crystals were found to have the greatest total bond order distributions and the perfect bonding characteristics, compositions, and structures for cement hydrates.

Indentation Response of Calcium Aluminoborosilicate Glasses Subjected to Humid Aging and Hot Compression

Aluminoborosilicate glasses find a wide range of applications, which require good mechanical reliability such as surface damage resistance. Calcium aluminoborosilicate (CABS) glasses have recently been found to exhibit so-called intermediate behavior in terms of their response to sharp contact loading. That is, these glasses deform with less shear than normal glass and less densification than anomalous glasses. This deformation mechanism is believed to give rise to high crack initiation resistance of certain CABS glasses. In order to further improve and understand the micromechanical properties of this glass family, we studied the indentation response of different CABS glasses subjected to two types of post-treatment, namely hot compression and humid aging. Upon hot compression, density, elastic moduli, and hardness increased. Specifically, elastic modulus increased by as much as 20% relative to the as-made sample, while the largest change in hardness was 1.8 GPa compared to the as-made sample after hot compression. The pressure-induced increase in these properties can be ascribed to the increase in network connectivity and bond density. On the other hand, the crack initiation resistance decreased, as the hot compression increased the residual stress driving the indentation cracking. Humid aging had only a minor impact on density, modulus, and hardness, but an observed decrease in crack initiation resistance. We discuss the correlations between hardness, density, crack resistance, and deformation mechanism and our study thus provides guidelines for tailoring the mechanical properties of oxide glasses.

Effect of precise linker length, bond density, and broad temperature window on the rheological properties of ethylene vitrimers

Dynamic networks with precise spacers between boronic ester bonds were investigated over a broad temperature window. Arrhenius behavior breaks down and an increase in relaxation time is observed when approach the glass transition temperature.

EMPIRICAL ASSESSMENT OF THE IMPACT OF THE ARMED CONFLICT ON THE STATE OF ECONOMIC SECURITY IN THE TEMPORARILY OCCUPIED DONETSK AND LUHANSK REGIONS

The article calculated the indicators of economic security of the Donetsk and Luhansk regions and assessed the impact of the armed conflict on the state of economic security in the temporarily occupied Donetsk and Luhansk regions. It is investigated that the deterioration of economic parameters of the development of the Donetsk and Luhansk regions after the outbreak of hostilities in the Donbas, largely caused a decrease in the level of economic security of Ukraine. The presence of such an impact is confirmed by the results of a pair correlation analysis of the communication force between the components of economic security (growth rate of component indices) of Luhansk, Donetsk regions and Ukraine (values of component indices). The results of multiple regression show a high bond density and, accordingly, the impact on Ukraine's economic security of such components of economic security in the Luhansk region, as macroeconomic, food, investment and innovation, demographic and such components of economic security of the Donetsk region as financial, industrial, foreign economic. A comparative calculation of the integral values of economic security of Donetsk, Luhansk regions and Ukraine as a whole was made. The direct positive impact of the level of economic security of the Donetsk and Luhansk regions on the level of economic security of Ukraine was identified, which is further evidence of the significant impact of destabilizing the situation in Donbas on the national economy of the country. Empirically assessed the dependence of ukraine's economic security components on the economic security components of Luhansk and Donetsk regions, conducted the results of multiple regression of dependence of Ukraine's economic security on the components of economic security of Donetsk and Luhansk regions. The indicators and characteristics of economic security of Donetsk and Luhansk regions, the impact of their economies on the state economic security of the state as a whole were studied. The author's methodology calculated the integral values of economic security of Donetsk and Luhansk regions and it was identified that external hybrid aggression had a greater impact on the deterioration of economic security components.

Connecting the stimuli-responsive rheology of biopolymer hydrogels to underlying hydrogen-bonding interactions

Many biopolymer hydrogels are environmentally responsive because they are held together by physical associations that depend on pH and temperature. Here we investigate how the pH and temperature response of the rheology of hyaluronan hydrogels is connected to the underlying molecular interactions. Hyaluronan is an essential structural biopolymer in the human body with many applications in biomedicine. Using two-dimensional infrared (2DIR) spectroscopy, we show that hyaluronan chains become connected by hydrogen bonds when the pH is changed from 7.0 to 2.5, and that the bond density at pH 2.5 is independent of temperature. Temperature-dependent rheology measurements show that due to this hydrogen bonding the stress relaxation at pH 2.5 is strongly slowed down in comparison to pH 7.0, consistent with the sticky reptation model of associative polymers. From the flow activation energy we conclude that each polymer is crosslinked by multiple (5-15) hydrogen bonds to others, causing slow macroscopic stress relaxation, despite the short time scale of breaking and reformation of each individual hydrogen bond. Our findings can aid the design of stimuli-responsive hydrogels with tailored viscoelastic properties for biomedical applications.