A parametric experimental study has been conducted to investigate the effect of fly ash on the fracture properties of high-performance concrete (HPC), with four fly ash contents used. By means of three-point bending method, the fracture toughness, fracture energy, effective crack length, critical crack opening displacement, and maximum crack opening displacement of the specimen were measured, respectively. The results indicate that fly ash has great improvement on the fracture parameters, and these fracture parameters gradually increase when the content of fly ash increases from 10 per cent to 20 per cent. However, these fracture parameters begin to decrease after the fly ash content exceeds 20 per cent. Besides, as the fly ash content increases from 10 per cent to 20 per cent, the relational curves between the vertical load and the mid-span deflection ( PV– δ), crack mouth opening displacement ( PV– CMOD), and crack tip opening displacement ( PV– CTOD) become plumper and plumper, which indicates that the capability of HPC containing fly ash to resist crack propagation is becoming stronger and stronger, while the curves become shriveled after the fly ash content exceeds 20 per cent. The contribution of fly ash on the fracture properties of HPC containing fly ash seems to be performed only when the fly ash content does not exceed 20 per cent.