The influence of water-to-cement ratio and superabsorbent polymers (SAPs) on solid-like behaviors of fresh cement pastes

2021 ◽  
Vol 275 ◽  
pp. 122160
Author(s):  
Siwei Ma ◽  
Cihang Huang ◽  
Prince Baah ◽  
Tommy Nantung ◽  
Na Lu
10.14311/1374 ◽  
2011 ◽  
Vol 51 (3) ◽  
Author(s):  
T. Ficker ◽  
D. Martišek ◽  
H. M. Jennings

. Seventy-eight graphs were plotted to describe and analyze the dependences of the height and roughness irregularities on the water-to-cement ratio and on the porosity of the cement hydrates. The results showed unambiguously that the water-to-cement ratio or equivalently the porosity of the specimens has a decisive influence on the irregularities of the fracture surfaces of this material. The experimental results indicated the possibility that the porosity or the value of the water-to-cement ratio might be inferred from the height irregularities of the fracture surfaces. It was hypothesized that there may be a similarly strong correlation between porosity and surface irregularity, on the one hand, and some other highly porous solids, on the other, and thus the same possibility to infer porosity from the surfaces of their fracture remnants.


Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3883
Author(s):  
Seong Ho Han ◽  
Yubin Jun ◽  
Tae Yong Shin ◽  
Jae Hong Kim

Curing by CO2 is a way to utilize CO2 to reduce greenhouse gas emissions. Placing early-age cement paste in a CO2 chamber or pressure vessel accelerates its strength development. Cement carbonation is attributed to the quickened strength development, and CO2 uptake can be quantitatively evaluated by measuring CO2 gas pressure loss in the pressure vessel. A decrease in CO2 gas pressure is observed with all cement pastes and mortar samples regardless of the mix proportion and the casting method; one method involves compacting a low water-to-cement ratio mix, and the other method comprises a normal mix consolidated in a mold. The efficiency of the CO2 curing is superior when a 20% concentration of CO2 gas is supplied at a relative humidity of 75%. CO2 uptake in specimens with the same CO2 curing condition is different for each specimen size. As the specimen scale is larger, the depth of carbonation is smaller. Incorporating colloidal silica enhances the carbonation as well as the hydration of cement, which results in contributing to the increase in the 28-day strength.


2010 ◽  
Vol 7 (1) ◽  
pp. 215-219
Author(s):  
R. Gopalakrishnan ◽  
D. Govindarajan

The present works reports the hydration processes of Portland cement through Electron paramagnetic resonance study. Cement pastes in a Water to cement ratio (W/C) of 0.4 at different hydration time intervals have been prepared. The g-factor of Fe(III) and Mn(II) impurities at different hydration ages has been related to changes in setting time of cement. Both gFe and gMn values are reach a maximum values at final setting time of OPC paste.


1986 ◽  
Vol 86 ◽  
Author(s):  
M. Rattanussorn ◽  
D. M. Roy ◽  
R. I. A. Malek

ABSTRACTThe predominant spherical shape of fly ash particles combined with mainly glassy composition and texture of its surfaces have a special effect on rheology of cement pastes containing fly ash. The early ages rheological behavior of cement pastes (ASTM Type I) incorporating 30% low-calcium fly ash was monitored by measuring viscosity of the fresh pastes prior to initial hardening and stiffening (up to −2 hours) as a function of time. The viscosities were determined using a co-axial rotoviscometer (HAAKE). The effects of fly ash content, water to cement ratio, and presence and concentration of superplasticizer, were evaluated. In addition, the dispersivity of fly ash spheres was evaluated by determining the zeta-potential of fly ash suspensions in water using a microelectrophoresis technique and the results were correlated to the chemical composition of fly ash as well as the viscosities of fresh pastes.


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