scholarly journals Surface Roughness and Porosity of Hydrated Cement Pastes

10.14311/1374 ◽  
2011 ◽  
Vol 51 (3) ◽  
Author(s):  
T. Ficker ◽  
D. Martišek ◽  
H. M. Jennings
Keyword(s):  
The Other ◽  
Porous Solids ◽  
Surface Irregularity ◽  
Hydrated Cement ◽  
Cement Pastes ◽  
Cement Ratio ◽  
Fracture Surfaces ◽  
Water To Cement Ratio ◽  
The One ◽  
Highly Porous

. Seventy-eight graphs were plotted to describe and analyze the dependences of the height and roughness irregularities on the water-to-cement ratio and on the porosity of the cement hydrates. The results showed unambiguously that the water-to-cement ratio or equivalently the porosity of the specimens has a decisive influence on the irregularities of the fracture surfaces of this material. The experimental results indicated the possibility that the porosity or the value of the water-to-cement ratio might be inferred from the height irregularities of the fracture surfaces. It was hypothesized that there may be a similarly strong correlation between porosity and surface irregularity, on the one hand, and some other highly porous solids, on the other, and thus the same possibility to infer porosity from the surfaces of their fracture remnants.

Roughness and fractality of fracture surfaces as indicators of mechanical quantities of porous solids

Open Physics ◽  
2011 ◽  
Vol 9 (6) ◽  
Author(s):  
Tomáš Ficker ◽  
Dalibor Martišek
Keyword(s):  
Mechanical Properties ◽  
Fractal Dimension ◽  
Fractal Dimensions ◽  
Point Of View ◽  
Porous Solids ◽  
Surface Parameter ◽  
Cement Pastes ◽  
Fracture Surfaces ◽  
Profile Parameter ◽  
3D Profile

AbstractThe 3D profile surface parameter H q and fractal dimension D were tested as indicators of mechanical properties inferred from fracture surfaces of porous solids. High porous hydrated cement pastes were used as prototypes of porous materials. Both the profile parameter H q and the fractal dimension D showed capability to assess compressive strength from the fracture surfaces of hydrated pastes. From a practical point of view the 3D profile parameter H q seems to be more convenient as an indicator of mechanical properties, as its values suffer much less from statistical scatter than those of fractal dimensions.

scholarly journals CO2 Curing Efficiency for Cement Paste and Mortars Produced by a Low Water-to-Cement Ratio

Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3883
Author(s):  
Seong Ho Han ◽  
Yubin Jun ◽  
Tae Yong Shin ◽  
Jae Hong Kim
Keyword(s):  
Cement Paste ◽  
Pressure Vessel ◽  
Gas Pressure ◽  
Strength Development ◽  
Co2 Uptake ◽  
Cement Pastes ◽  
Co2 Gas ◽  
Cement Ratio ◽  
Mix Proportion ◽  
Water To Cement Ratio

Curing by CO2 is a way to utilize CO2 to reduce greenhouse gas emissions. Placing early-age cement paste in a CO2 chamber or pressure vessel accelerates its strength development. Cement carbonation is attributed to the quickened strength development, and CO2 uptake can be quantitatively evaluated by measuring CO2 gas pressure loss in the pressure vessel. A decrease in CO2 gas pressure is observed with all cement pastes and mortar samples regardless of the mix proportion and the casting method; one method involves compacting a low water-to-cement ratio mix, and the other method comprises a normal mix consolidated in a mold. The efficiency of the CO2 curing is superior when a 20% concentration of CO2 gas is supplied at a relative humidity of 75%. CO2 uptake in specimens with the same CO2 curing condition is different for each specimen size. As the specimen scale is larger, the depth of carbonation is smaller. Incorporating colloidal silica enhances the carbonation as well as the hydration of cement, which results in contributing to the increase in the 28-day strength.

scholarly journals Hydration processes of cement paste-an EPR study

2010 ◽  
Vol 7 (1) ◽  
pp. 215-219
Author(s):  
R. Gopalakrishnan ◽  
D. Govindarajan
Keyword(s):  
Setting Time ◽  
Electron Paramagnetic Resonance Study ◽  
Hydration Time ◽  
Time Intervals ◽  
Paramagnetic Resonance ◽  
Cement Pastes ◽  
Cement Ratio ◽  
Final Setting Time ◽  
Water To Cement Ratio ◽  
Electron Paramagnetic

The present works reports the hydration processes of Portland cement through Electron paramagnetic resonance study. Cement pastes in a Water to cement ratio (W/C) of 0.4 at different hydration time intervals have been prepared. The g-factor of Fe(III) and Mn(II) impurities at different hydration ages has been related to changes in setting time of cement. Both gFe and gMn values are reach a maximum values at final setting time of OPC paste.

Effect of Fly Ash Incorporation on Rheology of Cement Pastes

1986 ◽  
Vol 86 ◽  
Author(s):  
M. Rattanussorn ◽  
D. M. Roy ◽  
R. I. A. Malek
Keyword(s):  
Fly Ash ◽  
Chemical Composition ◽  
Zeta Potential ◽  
Spherical Shape ◽  
Ash Content ◽  
Type I ◽  
Special Effect ◽  
Cement Pastes ◽  
Cement Ratio ◽  
Water To Cement Ratio

ABSTRACTThe predominant spherical shape of fly ash particles combined with mainly glassy composition and texture of its surfaces have a special effect on rheology of cement pastes containing fly ash. The early ages rheological behavior of cement pastes (ASTM Type I) incorporating 30% low-calcium fly ash was monitored by measuring viscosity of the fresh pastes prior to initial hardening and stiffening (up to −2 hours) as a function of time. The viscosities were determined using a co-axial rotoviscometer (HAAKE). The effects of fly ash content, water to cement ratio, and presence and concentration of superplasticizer, were evaluated. In addition, the dispersivity of fly ash spheres was evaluated by determining the zeta-potential of fly ash suspensions in water using a microelectrophoresis technique and the results were correlated to the chemical composition of fly ash as well as the viscosities of fresh pastes.

Roughness of fracture surfaces and compressive strength of hydrated cement pastes

2010 ◽  
Vol 40 (6) ◽  
pp. 947-955 ◽  
Author(s):  
Tomáš Ficker ◽  
Dalibor Martišek ◽  
Hamlin M. Jennings
Keyword(s):  
Compressive Strength ◽  
Hydrated Cement ◽  
Cement Pastes ◽  
Fracture Surfaces

Nuclear Magnetic Resonance Studies on Microstructure of Cement Pastes

2010 ◽  
Vol 177 ◽  
pp. 518-521 ◽  
Author(s):  
Dan Jin ◽  
Wu Yao ◽  
An Ming She ◽  
Xiao Yan Liu
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Relaxation Time ◽  
Magnetic Resonance ◽  
Fast Diffusion ◽  
Cement Pastes ◽  
Bulk Fluid ◽  
Cement Ratio ◽  
Water To Cement Ratio ◽  
The Difference ◽  
Nuclear Magnetic

For water filled porous materials, the difference between the relaxation time of molecules at the pore surface and the relaxation time of molecules in the bulk fluid can be interpreted by a fast diffusion model. With this model, the nuclear magnetic resonance (NMR) can be applied to investigate the microstructure of cement pastes. The cement pastes we tested are two series, one is of same water to cement ratio (w/c=0.4) at different curing time (7d, 28d and 90d), the other is of different water to cement ratio (w/c=0.3, 0.4 and0.5, respectively) at the same curing day. Comparing results by NMR method with those by mercury intrusion porosimetry (MIP) shows that NMR is a convenient and nondestructive way to probe pore distribution of cement pastes.

scholarly journals Effect of Lightweight Aggregate Impregnation on Selected Concrete Properties

Materials ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 198
Author(s):  
Lucyna Domagała ◽  
Agnieszka Podolska
Keyword(s):  
Compressive Strength ◽  
Water Absorption ◽  
Cement Paste ◽  
Initial Moisture Content ◽  
Lightweight Aggregate ◽  
The Other ◽  
Lightweight Aggregates ◽  
Cement Pastes ◽  
Water Absorption Test ◽  
The One

The impregnation of lightweight aggregate (LWA) is an alternative method to its pre-moistening, which is used to limit the loss of fresh concrete workability due to the aggregate’s ability to absorb a great amount of mixing water. The aim of this study was to access the effectiveness, by pre-coating LWAs with cement paste, in modifying the properties of concrete composites. Two types of lightweight aggregates (Lytag and Leca) characterized with a relatively open-structure shell were selected. The other changeable parameters taken into consideration in this research were: LWA size, initial moisture of aggregate before the impregnation process and type of cement paste applied as an impregnant. Sixteen concretes prepared with pre-moistened and pre-coated lightweight aggregates were subject to a density test in different moisture conditions, a water absorption test and a compressive strength test. On the one hand, the pre-coating of LWAs with cement paste resulted in a relatively slight increase in concrete density (by up to 19%) compared to the pre-moistening of LWAs. On the other hand, it caused a very significant reduction (by up to 52%) in the composite’s water absorption and an incomparably greater growth (by up to 107%) in compressive strength. The most crucial factors determining the effectiveness of impregnation of LWAs with cement pastes in improvement of composite properties were the aggregate type and its size. The composition of impregnating slurry and the initial moisture content of LWA before pre-coating also mattered.

Sign in / Sign up

Export Citation Format

Share Document