Effect of microcrystalline cellulose on geopolymer and Portland cement pastes mechanical performance

2021 ◽  
Vol 288 ◽  
pp. 123053
Author(s):  
Saulo Rocha Ferreira ◽  
Neven Ukrainczyk ◽  
Keoma Defáveri do Carmo e Silva ◽  
Luiz Eduardo Silva ◽  
Eduardo Koenders
Keyword(s):  
Portland Cement ◽  
Microcrystalline Cellulose ◽  
Mechanical Performance ◽  
Cement Pastes

scholarly journals Influence of Ultrasonication of Functionalized Carbon Nanotubes on the Rheology, Hydration, and Compressive Strength of Portland Cement Pastes

Materials ◽  
2021 ◽  
Vol 14 (18) ◽  
pp. 5248
Author(s):  
Laura Silvestro ◽  
Artur Ruviaro ◽  
Geannina Lima ◽  
Paulo de Matos ◽  
Afonso R. G. de Azevedo ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Compressive Strength ◽  
Portland Cement ◽  
Mechanical Performance ◽  
Isothermal Calorimetry ◽  
Hydration Kinetics ◽  
Cement Pastes ◽  
Degree Of Hydration ◽  
Vis Spectroscopy ◽  
Localized Defects

The functionalization process usually increases the localized defects of carbon nanotubes (CNT). Thus, the ultrasonication parameters used for dispersing non-functionalized CNT should be carefully evaluated to verify if they are adequate in dispersing functionalized CNT. Although ultrasonication is widely used for non-functionalized CNT, the effect of this dispersing process of functionalized CNT has not been thoroughly investigated. Thus, this work investigated the effect of ultrasonication on functionalized CNT + superplasticizer (SP) aqueous dispersions by ultraviolet-visible (UV-Vis) spectroscopy, dynamic light scattering (DLS), and Fourier transform infrared spectroscopy (FTIR). Furthermore, Portland cement pastes with additions of 0.05% and 0.1% CNT by cement weight and ultrasonication amplitudes of 0%, 50% and 80% were evaluated through rheometry, isothermal calorimetry, compressive strength at 1, 7 and 28 days, X-ray diffraction (XRD), and thermogravimetric analysis (TGA). FTIR results from CNT + SP dispersions indicated that ultrasonication may negatively affect SP molecules and CNT graphene structure. The increase in CNT content and amplitude of ultrasonication gradually increased the static and dynamic yield stress of paste but did not significantly affect its hydration kinetics. Compressive strength results indicated that the optimum CNT content was 0.05% by cement weight, which increased the strength of composite by up to 15.8% compared with the plain paste. CNT ultrasonication neither increases the degree of hydration of cement nor the mechanical performance of composite when compared with mixes containing unsonicated CNT. Overall, ultrasonication of functionalized CNT is not efficient in improving the fresh and hardened performance of cementitious composites.

scholarly journals Effect of nano-silica on Portland cement matrices containing supplementary cementitious materials

2021 ◽  
Vol 14 (4) ◽  
Author(s):  
Thiago Melanda Mendes ◽  
Wellington Longuini Repette
Keyword(s):  
Portland Cement ◽  
Mechanical Performance ◽  
Mercury Porosimetry ◽  
Cementitious Materials ◽  
Nano Particles ◽  
Supplementary Cementitious Materials ◽  
Nano Silica ◽  
Fixed Amount ◽  
Cement Pastes ◽  
Cement Matrices

abstract: For a controlled granulometry, this study evaluates the effect of nano-silica on mechanical and rheological properties, as well in the microstructure of Portland cement matrices containing a fixed amount of supplementary cementitious materials and three different types of cements. The rheological behavior of cement pastes was evaluated by rotational rheometry and mechanical performance was measured througth the compressive strength. The microstructure was analyzed by intrusion mercury porosimetry and scanning electron microscopy. There was an increasing on the viscosity of the cementitious matrices, as a consequence of the reduction in the inter particle separation of these suspensions. The optimum content of nano-silica varied according to Ca/Si ratio of Portland cement matrices containing supplementary cementitious materials. The use of nano-silica allowed to modify the pore size distribution of cementitious matrices. And the structure of nano-silica in cementitious matrices has occurred in layers or agglomerates of nano-particles covered by hydration products.

Hardened portland cement pastes of low porosity

1973 ◽  
Vol 3 (3) ◽  
pp. 279-293 ◽  
Author(s):  
Stephen Brunauer ◽  
Jan Skalny ◽  
Ivan Odler ◽  
Marvin Yudenfreund
Keyword(s):  
Portland Cement ◽  
Cement Pastes ◽  
Low Porosity

scholarly journals Mechanical Properties of an Igneous Aggregate-Modified Hydraulic Concrete

2001 ◽  
Vol 10 (2) ◽  
pp. 096369350101000
Author(s):  
E. Alonso ◽  
L. Martvnez-Gomez ◽  
W. Martvnez ◽  
L. Villaseρor ◽  
V.M. Castapo
Keyword(s):  
Mechanical Properties ◽  
Portland Cement ◽  
Mechanical Testing ◽  
Mechanical Performance ◽  
Central Mexico ◽  
Natural Sources ◽  
Hydraulic Concrete ◽  
West Central ◽  
Careful Control

Portland cement concretes were prepared by adding different igneous materials from west central Mexico. The results of the mechanical testing of these materials show the feasibility of employing igneous minerals to produce concretes and mortars, provided a careful control of granulometry and the geochemistry involved is attained. The mechanical performance, as well as the workability of the slurries can be managed by the convenient use of commercial additives (i.e. water reducers and aging accelerators). These results open the attractive possibility of expanding the natural sources of concrete-forming elements.

Electrochemical behavior of Portland cement pastes containing phosphonates

1995 ◽  
Vol 2 (5) ◽  
pp. 182-188 ◽  
Author(s):  
P. Gu ◽  
V.S. Ramachandran ◽  
J.J. Beaudoin ◽  
E. Quinn
Keyword(s):  
Portland Cement ◽  
Electrochemical Behavior ◽  
Cement Pastes

Early carbonation curing effects on the microstructure of high initial strength Portland cement pastes

2019 ◽  
Vol 31 (8) ◽  
pp. 382-388 ◽  
Author(s):  
Alex Neves Junior ◽  
Romildo Dias Toledo Filho ◽  
Jo Dweck ◽  
Frank K. Cartledged ◽  
Eduardo de Moraes Rego Fairbairn
Keyword(s):  
Portland Cement ◽  
Cement Pastes ◽  
Initial Strength ◽  
Carbonation Curing

scholarly journals Volcanic Ash as a Sustainable Binder Material: An Extensive Review

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1302
Author(s):  
Andrés Játiva ◽  
Evelyn Ruales ◽  
Miren Etxeberria
Keyword(s):  
Chemical Composition ◽  
Portland Cement ◽  
Urban Areas ◽  
Volcanic Ash ◽  
Mechanical Performance ◽  
Cement Clinker ◽  
Alkali Activation ◽  
Cement Production ◽  
Sustainable Solutions ◽  
Alkali Activated

The construction industry is affected by the constant growth in the populations of urban areas. The demand for cement production has an increasing environmental impact, and there are urgent demands for alternative sustainable solutions. Volcanic ash (VA) is an abundant low-cost material that, because of its chemical composition and amorphous atomic structure, has been considered as a suitable material to replace Portland cement clinker for use as a binder in cement production. In the last decade, there has been interest in using alkali-activated VA material as an alternative material to replace ordinary Portland cement. In this way, a valuable product may be derived from a currently under-utilized material. Additionally, alkali-activated VA-based materials may be suitable for building applications because of their good densification behaviour, mechanical properties and low porosity. This article describes the most relevant findings from researchers around the world on the role of the chemical composition and mineral contents of VA on reactivity during the alkali-activation reaction; the effect of synthesis factors, which include the concentration of the alkaline activator, the solution-to-binder ratio and the curing conditions, on the properties of alkali-activated VA-based materials; and the mechanical performance and durability properties of these materials.

Portland Cement Pastes with 3-Aminopropyltriethoxysilane Functionalized Nanosilica: Scientific, Hydration and Microstructural Aspects

2021 ◽  
Author(s):  
Julliana Simas Vasconcellos ◽  
Yuri Sotero Bomfim Fraga ◽  
João Henrique da Silva Rêgo ◽  
Patrícia Pommé Confessori Sartoratto ◽  
Moisés Frías Rojas
Keyword(s):  
Portland Cement ◽  
Cement Pastes
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