Thermal aging at 475°C of newly developed lean duplex stainless steel 2404: Mechanical properties and corrosion behavior

2017 ◽  
Vol 116 ◽  
pp. 66-73 ◽  
Author(s):  
R. Silva ◽  
L.F.S. Baroni ◽  
C.L. Kugelmeier ◽  
M.B.R. Silva ◽  
S.E. Kuri ◽  
...  
Metals ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 529 ◽  
Author(s):  
Federica Zanotto ◽  
Vincenzo Grassi ◽  
Andrea Balbo ◽  
Fabrizio Zucchi ◽  
Cecilia Monticelli

This paper reports the effects of thermal aging between 650 and 850 °C on the localized corrosion behavior of lean duplex stainless steel (LDSS 2404). Critical pitting temperature (CPT) and double loop electrochemical potentiokinetic reactivation (DL-EPR) tests were performed. The localization of pitting attack and intergranular corrosion (IGC) attack after DL-EPR was investigated by optical (OM) and scanning electron microscopy (SEM) and by focused ion beam (FIB) coupled to SEM. Thermal aging caused the precipitation of mainly chromium nitrides at grain boundaries. Aging at 650 °C or short aging times (5 min) at 750 °C caused nitride precipitation mainly at α/α grain boundaries as a result of fast diffusion of chromium in this phase. Aging at 850 °C or aging times from 10 to 60 min at 750 °C also allowed the precipitation at the α/γ interface. Nitrides at γ/γ grain boundaries were observed rarely and only after long aging times (60 min) at 850 °C. Electrochemical tests showed that in as-received samples, pitting attack only affected the α phase. Conversely, in aged samples, pitting and IGC attack were detected close to nitrides in correspondence of α/α and α/γ grain boundaries depending on aging temperatures and times.


Materials ◽  
2014 ◽  
Vol 7 (9) ◽  
pp. 6604-6619 ◽  
Author(s):  
Yanjun Guo ◽  
Jincheng Hu ◽  
Jin Li ◽  
Laizhu Jiang ◽  
Tianwei Liu ◽  
...  

2021 ◽  
Vol 802 ◽  
pp. 140577
Author(s):  
Ariane Neves de Moura ◽  
Cláudio Moreira de Alcântara ◽  
Tarcísio Reis de Oliveira ◽  
Marco Antônio da Cunha ◽  
Marcelo Lucas Pereira Machado

Metals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 317 ◽  
Author(s):  
Qingdong Zhang ◽  
Sida Ma ◽  
Tao Jing

Z3CN20.09M cast duplex stainless steel (CDSS) has been used for primary coolant water pipes in pressurized water reactors due to its excellent mechanical properties. Such pipes operate at an elevated service temperature (~320 °C) and experience issues of thermal aging embrittlement. In situ tensile tests were conducted to investigate the deformation mechanisms of Z3CN20.09M CDSS after long-term thermal aging at 475 °C for up to 2000 h in both optical microscope and scanning electron microscope at 320 °C. For the 320 °C tests, the tensile stress and other mechanical properties, e.g. the yield stress and the ultimate tensile strength, increase during the thermal aging process and recover to almost the same level as the unaged condition after annealing heat-treatment, which is caused by the formation and dissolution of precipitation during aging and anneal heat-treatment, respectively. For the slip mechanism, straight slip lines form first in the austenite phase. When these slip lines reach the austenite/ferrite interface, three kinds of slip systems are found in the ferrite phase. During the fracture process, the austenite phase is torn apart and the ferrite phase shows a significant elongation. The role of the ferrite phase is to hold the austenite matrix, thus increasing the tensile strength of this steel.


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