Effect of aging time on intergranular corrosion behavior of a newly developed LDX 2404 lean duplex stainless steel

2016 ◽  
Vol 672 ◽  
pp. 147-154 ◽  
Author(s):  
Hui Zhao ◽  
Ziying Zhang ◽  
Huizhen Zhang ◽  
Jun Hu ◽  
Jin Li
Metals ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 529 ◽  
Author(s):  
Federica Zanotto ◽  
Vincenzo Grassi ◽  
Andrea Balbo ◽  
Fabrizio Zucchi ◽  
Cecilia Monticelli

This paper reports the effects of thermal aging between 650 and 850 °C on the localized corrosion behavior of lean duplex stainless steel (LDSS 2404). Critical pitting temperature (CPT) and double loop electrochemical potentiokinetic reactivation (DL-EPR) tests were performed. The localization of pitting attack and intergranular corrosion (IGC) attack after DL-EPR was investigated by optical (OM) and scanning electron microscopy (SEM) and by focused ion beam (FIB) coupled to SEM. Thermal aging caused the precipitation of mainly chromium nitrides at grain boundaries. Aging at 650 °C or short aging times (5 min) at 750 °C caused nitride precipitation mainly at α/α grain boundaries as a result of fast diffusion of chromium in this phase. Aging at 850 °C or aging times from 10 to 60 min at 750 °C also allowed the precipitation at the α/γ interface. Nitrides at γ/γ grain boundaries were observed rarely and only after long aging times (60 min) at 850 °C. Electrochemical tests showed that in as-received samples, pitting attack only affected the α phase. Conversely, in aged samples, pitting and IGC attack were detected close to nitrides in correspondence of α/α and α/γ grain boundaries depending on aging temperatures and times.


Materials ◽  
2014 ◽  
Vol 7 (9) ◽  
pp. 6604-6619 ◽  
Author(s):  
Yanjun Guo ◽  
Jincheng Hu ◽  
Jin Li ◽  
Laizhu Jiang ◽  
Tianwei Liu ◽  
...  

2017 ◽  
Vol 53 (1) ◽  
pp. 824-836 ◽  
Author(s):  
Yan Zhao ◽  
Xin Liu ◽  
Xin Li ◽  
Yuan Wang ◽  
Weina Zhang ◽  
...  

Author(s):  
Chengsi Zheng ◽  
Qingnan Fei ◽  
Weihai Kong ◽  
Zhibin Ai

Abstract A 2205 duplex stainless steel (DSS) was pre-stretched to 5% and subsequently aged at 850 °C for 0–120 minutes, to explore the effects of pre-strain and aging treatment on the corrosion behavior of the DSS in 6% FeCl3 solution at 50 °C for 72 hours. The microstructure, hardness and corrosion behavior of the pre-strained and aged DSS were investigated based on statistical data and physical metallurgy in comparison with the counterparts without pre-strain. The results showed that the sigma (σ) phase precipitated firstly in δ-ferrite grain boundaries and then in δ-ferrite/γ-austenite (δ/γ) phases boundaries by consuming the volume fraction of δ-ferrite. The volume fraction of σ phase in the DSS with and without pre-strain increased with increasing aging times following a classical Johnson-Mehl-Avrami (JMA) relationship, and the kinetics of the precipitation of σ phase was accelerated by pre-strain throughout the aging time of 60–120 min. The hardness of the non-pre-strained DSS (NP-DSS) was lower than that of pre-strained DSS (P-DSS) throughout 0–120 min at 850 °C. The hardness of NP-DSS increased continuously with increasing aging time, and the hardness of P-DSS decreased firstly and then increased continuously with increasing aging time. The aged NP-DSS displayed a gradually serious pitting with increasing aging time, and the corresponding corrosion behavior of the aged P-DSS exhibited pitting firstly and then mainly cracking, and the pitting occurred in the vicinity of δ/σ and γ/σ boundaries.


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