High-density nickel phosphide nanoparticles loaded reduced graphene oxide on nickel foam for enhanced alkaline and neutral water splitting

2020 ◽  
Vol 362 ◽  
pp. 137172
Author(s):  
Zehao Zhang ◽  
Chenbo Li ◽  
Haoran Huang ◽  
Jiefei Li ◽  
Xueqiong Zhang ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Water Splitting ◽  
Nickel Foam ◽  
High Density ◽  
Nickel Phosphide ◽  
Reduced Graphene ◽  
Neutral Water

Tuning the cationic ratio of Fe1CoxNiyP integrated on Vertically aligned reduced graphene oxide array via electroless plating as efficient self-supported bifunctional electrocatalyst for water splitting

2021 ◽  
pp. 1-33
Author(s):  
Kaiming Guo ◽  
Firdoz Shaik ◽  
Jine Yang ◽  
Bin Jiang
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Water Splitting ◽  
Electroless Plating ◽  
Cost Effective ◽  
Bifunctional Electrocatalyst ◽  
Reduced Graphene ◽  
Wide Ph Range ◽  
Vertically Aligned ◽  
Ph Range

Abstract Water splitting is considered as a potential sustainable and green technology for producing mass hydrogen and oxygen. A cost-effective self-supported stable electrocatalyst with excellent electrocatalytic performance in a wide pH range is greatly required for water splitting. This work reports on the synthesis and anchoring of Fe1CoxNiyP nanoparticles on vertically aligned reduced graphene oxide array (VrGO) via electroless plating. The catalytic activity of Fe1CoxNiyP nanoparticles is tuned finely by tailoring the cationic ratio of Co and Ni. Fe1Co2Ni1P/VrGO exhibits the lowest overpotential (58 and 110 mV) at 10 mA cm−2 and lowest tafel slope (31 and 33 mV dec−1) for hydrogen evolution reaction in 1.0 M KOH and 0.5 M H2SO4 respectively. Fe1Co1Ni2P/VrGO exhibits the lowest overpotential (173 mV) at 10 mA cm−2 with lowest tafel slope (47 mV dec-1) for oxygen evolution reaction. The enhanced performance of the electrocatalyst is attributed to improved electrical conductivity, synergistic effects and beneficial electronic states caused by the appropriate atomic ratio of Co and Ni in the bifunctional electrocatalyst. This study helps to explore the effect of variable cationic ratio in the cost-effective ternary iron group metal phosphides electrocatalysts to achieve enhanced electrocatalytic performance for water splitting in a wide pH range.

Porous reduced graphene oxide/nickel foam for highly efficient solar steam generation

2019 ◽  
Vol 30 (42) ◽  
pp. 425403 ◽  
Author(s):  
Xiaoli Shan ◽  
Yawen Lin ◽  
Aiqing Zhao ◽  
Yunsong Di ◽  
Yujing Hu ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Nickel Foam ◽  
Steam Generation ◽  
Highly Efficient ◽  
Reduced Graphene ◽  
Solar Steam Generation

Reduced graphene oxide decorated SnO2/BiVO4 photoanode for photoelectrochemical water splitting

2021 ◽  
Vol 855 ◽  
pp. 156780 ◽  
Author(s):  
Shouli Bai ◽  
Ke Tian ◽  
Jonathan Chenhui Meng ◽  
Yingying Zhao ◽  
Jianhua Sun ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Water Splitting ◽  
Photoelectrochemical Water Splitting ◽  
Reduced Graphene
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