Hydrothermal Carbonization of Soybean Hulls for the Generation of Hydrochar: A Promising Valorization Pathway for Low Value Biomass

Author(s):  
RH Fitri Faradilla ◽  
Lucian Lucia ◽  
Marko Hakovirta
2020 ◽  
Vol 149 ◽  
pp. 104844 ◽  
Author(s):  
Bence Babinszki ◽  
Emma Jakab ◽  
Zoltán Sebestyén ◽  
Marianne Blazsó ◽  
Bernadett Berényi ◽  
...  

Energies ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2697
Author(s):  
Gabriel Gerner ◽  
Luca Meyer ◽  
Rahel Wanner ◽  
Thomas Keller ◽  
Rolf Krebs

Phosphorus recovery from waste biomass is becoming increasingly important, given that phosphorus is an exhaustible non-renewable resource. For the recovery of plant nutrients and production of climate-neutral fuel from wet waste streams, hydrothermal carbonization (HTC) has been suggested as a promising technology. In this study, digested sewage sludge (DSS) was used as waste material for phosphorus and nitrogen recovery. HTC was conducted at 200 °C for 4 h, followed by phosphorus stripping (PS) or leaching (PL) at room temperature. The results showed that for PS and PL around 84% and 71% of phosphorus, as well as 53% and 54% of nitrogen, respectively, could be recovered in the liquid phase (process water and/or extract). Heavy metals were mainly transferred to the hydrochar and only <1 ppm of Cd and 21–43 ppm of Zn were found to be in the liquid phase of the acid treatments. According to the economic feasibility calculation, the HTC-treatment per dry ton DSS with an industrial-scale plant would cost around 608 USD. Between 349–406 kg of sulfuric acid are required per dry ton DSS to achieve a high yield in phosphorus recovery, which causes additional costs of 96–118 USD. Compared to current sewage sludge treatment costs in Switzerland, which range between 669 USD and 1173 USD, HTC can be an economically feasible process for DSS treatment and nutrient recovery.


Author(s):  
Selva Bilge ◽  
Emre Ergene ◽  
Ebru Talak ◽  
Seyda Gokyer ◽  
Yusuf Osman Donar ◽  
...  

AbstractSkeletal muscle is an electrically and mechanically active tissue that contains highly oriented, densely packed myofibrils. The tissue has self-regeneration capacity upon injury, which is limited in the cases of volumetric muscle loss. Several regenerative therapies have been developed in order to enhance this capacity, as well as to structurally and mechanically support the defect site during regeneration. Among them, biomimetic approaches that recapitulate the native microenvironment of the tissue in terms of parallel-aligned structure and biophysical signals were shown to be effective. In this study, we have developed 3D printed aligned and electrically active scaffolds in which the electrical conductivity was provided by carbonaceous material (CM) derived from algae-based biomass. The synthesis of this conductive and functional CM consisted of eco-friendly synthesis procedure such as pre-carbonization and multi-walled carbon nanotube (MWCNT) catalysis. CM obtained from biomass via hydrothermal carbonization (CM-03) and its ash form (CM-03K) were doped within poly(ɛ-caprolactone) (PCL) matrix and 3D printed to form scaffolds with aligned fibers for structural biomimicry. Scaffolds were seeded with C2C12 mouse myoblasts and subjected to electrical stimulation during the in vitro culture. Enhanced myotube formation was observed in electroactive groups compared to their non-conductive counterparts and it was observed that myotube formation and myotube maturity were significantly increased for CM-03 group after electrical stimulation. The results have therefore showed that the CM obtained from macroalgae biomass is a promising novel source for the production of the electrically conductive scaffolds for skeletal muscle tissue engineering.


2021 ◽  
pp. 126734
Author(s):  
M. Bardhan ◽  
T.M. Novera ◽  
M. Tabassum ◽  
Md. Azharul ◽  
Md. Atikul ◽  
...  

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 173
Author(s):  
Velma Beri Kimbi Yaah ◽  
Satu Ojala ◽  
Hamza Khallok ◽  
Tiina Laitinen ◽  
Marcin Selent ◽  
...  

This paper presents results related to the development of a carbon composite intended for water purification. The aim was to develop an adsorbent that could be regenerated using light leading to complete degradation of pollutants and avoiding the secondary pollution caused by regeneration. The composites were prepared by hydrothermal carbonization of palm kernel shells, TiO2, and W followed by activation at 400 °C under N2 flow. To evaluate the regeneration using light, photocatalytic experiments were carried out under UV-A, UV-B, and visible lights. The materials were thoroughly characterized, and their performance was evaluated for diclofenac removal. A maximum of 74% removal was observed with the composite containing TiO2, carbon, and W (HCP25W) under UV-B irradiation and non-adjusted pH (~5). Almost similar results were observed for the material that did not contain tungsten. The best results using visible light were achieved with HCP25W providing 24% removal of diclofenac, demonstrating the effect of W in the composite. Both the composites had significant amounts of oxygen-containing functional groups. The specific surface area of HCP25W was about 3 m2g−1, while for HCP25, it was 160 m2g−1. Increasing the specific surface area using a higher activation temperature (600 °C) adversely affected diclofenac removal due to the loss of the surface functional groups. Regeneration of the composite under UV-B light led to a complete recovery of the adsorption capacity. These results show that TiO2- and W-containing carbon composites are interesting materials for water treatment and they could be regenerated using photocatalysis.


2021 ◽  
Vol 13 (14) ◽  
pp. 7706
Author(s):  
Tova Jarnerud ◽  
Andrey V. Karasev ◽  
Chuan Wang ◽  
Frida Bäck ◽  
Pär G. Jönsson

A six day industrial trial using hydrochar as part of the carbon source for hot metal production was performed in a production blast furnace (BF). The hydrochar came from two types of feedstocks, namely an organic mixed biosludge generated from pulp and paper production and an organic green waste residue. These sludges and residues were upgraded to hydrochar in the form of pellets by using a hydrothermal carbonization (HTC) technology. Then, the hydrochar pellets were pressed into briquettes together with commonly used briquetting material (in-plant fines such as fines from pellets and scraps, dust, etc. generated from the steel plant) and the briquettes were top charged into the blast furnace. In total, 418 tons of hydrochar briquettes were produced. The aim of the trials was to investigate the stability and productivity of the blast furnace during charging of these experimental briquettes. The results show that briquettes containing hydrochar from pulp and paper industries waste and green waste can partially be used for charging in blast furnaces together with conventional briquettes. Most of the technological parameters of the BF process, such as the production rate of hot metal (<1.5% difference between reference days and trial days), amount of dust, fuel rate and amount of injected coal, amount of slag, as well as contents of FeO in slag and %C, %S and %P in the hot metal in the experimental trials were very similar compared to those in the reference periods (two days before and two days after the trials) without using these experimental charge materials. Thus, it was proven that hydrochar derived from various types of organic residues could be used for metallurgical applications. While in this trial campaign only small amounts of hydrochar were used, nevertheless, these positive results support our efforts to perform more in-depth investigations in this direction in the future.


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