Flammability of Engineered Wood Pyrolysis Gases at Anaerobic Condition

2021 ◽  
pp. 103424
Author(s):  
Sahand Rasoulipour ◽  
Charles Fleischmann ◽  
Luke Merciec ◽  
Nicole Adams
2021 ◽  
Vol 11 (22) ◽  
pp. 10570
Author(s):  
Hermes Scandelli ◽  
Azita Ahmadi-Senichault ◽  
Jean Lachaud ◽  
Franck Richard

The numerical simulation of fire propagation requires capturing the coupling between wood pyrolysis, which leads to the production of various gaseous species, and the combustion of these species in the flame, which produces the energy that sustains the pyrolysis process. Experimental and numerical works of the fire community are targeted towards improving the description of the pyrolysis process to better predict the rate of production and the chemical nature of the pyrolysis gases. We know that wood pyrolysis leads to the production of a large variety of chemical species: water, methane, propane, carbon monoxide and dioxide, phenol, cresol, hydrogen, etc. With the idea of being able to capitalize on such developments to study more accurately the physics of fire propagation, we have developed a numerical framework that couples a detailed three-dimensional pyrolysis model and fireFoam. In this article, we illustrate the capability of the simulation tool by treating the combustion of a wood log. Wood is considered to be composed of three phases (cellulose, hemicellulose and lignin), each undergoing parallel degradation processes leading to the production of methane and hydrogen. We chose to simplify the gas mixture for this first proof of concept of the coupling of a multi-species pyrolysis process and a flame. In the flame, we consider two separate finite-rate combustion reactions for methane and hydrogen. The flame evolves during the simulation according to the concentration of the two gaseous species produced from the material. It appears that introducing different pyrolysis species impacts the temperature and behavior of the flame.


Author(s):  
N. I. Chernova ◽  
S. V. Kiseleva ◽  
O. M. Larina ◽  
G. A. Sytchev

Algae biomass is considered as an alternative raw material for the production of biofuels. The search for new types of raw materials, including high-energy types of microalgae, remains relevant, since the share of motor fuels in the structure of the global fuel and energy balance remains consistently high (about 35%), and the price of oil is characterized by high volatility. The authors have considered the advantages of microalgae as sources of raw materials for fuel production. Biochemical and thermochemical conversion are proposed as technologies for their processing. This paper presents the results of the study of the pyrolysis of the biomass of clonal culture of blue-green microalgae / cyanobacteriumArthrospira platensis rsemsu 1/02-Pfrom the collection of the Research Laboratory of Renewable Energy Sources of the Lomonosov Moscow State University. An experiment to study the process of pyrolysis of microalgae biomass was carried out at the experimental facility of the Institute of High Temperatures RAS in pure nitrogen grade 6.0 to create an oxygen-free environment with a linear heating rate of 10 ºС / min from room temperature to 1000 ºС. The whole process of pyrolysis proceeded in the field of endothermy. The specific amounts of solid residue, pyrolysis liquid and gaseous products were experimentally determined. As a result of the pyrolysis of microalgae biomass weighing 15 g, the following products were obtained: 1) coal has the mass of the solid residue is 2.68 g, or 17.7% of the initial mass of the microalgae (while 9.3% of the initial mass of the microalgae remained in the reactor); 2) pyrolysis liquid – weight 3.3 g, or 21.9% of the initial weight; 3) non-condensable pyrolysis gases – weight 1.15 l. The specific volumetric gas yield (the amount of gas released from 1 kg of the starting material) was 0.076 Nm3/ kg. The analysis of the composition and specific volume yield of non-condensable pyrolysis gases formed in the process of pyrolysis, depending on temperature. It is shown that with increasing temperature, the proportion of highcalorie components of the gas mixture (hydrogen, methane and carbon monoxide) increases. The calorific value of the mixture of these gases has been estimated.


2021 ◽  
Vol 286 ◽  
pp. 116431
Author(s):  
Przemyslaw Maziarka ◽  
Peter Sommersacher ◽  
Xia Wang ◽  
Norbert Kienzl ◽  
Stefan Retschitzegger ◽  
...  

2005 ◽  
Vol 48 (5) ◽  
pp. 1731-1738 ◽  
Author(s):  
J. W. Gaskin ◽  
L. M. Risse ◽  
J. R. Kastner ◽  
W. J. McLaurin

2020 ◽  
Vol 162 ◽  
pp. 1243-1254
Author(s):  
Bang Xu ◽  
Morris D. Argyle ◽  
Xiufeng Shi ◽  
Alexander K. Goroncy ◽  
Asif Hasan Rony ◽  
...  

2017 ◽  
Vol 53 (5) ◽  
pp. 638-645 ◽  
Author(s):  
A. N. Grachev ◽  
M. A. Varfolomeev ◽  
D. A. Emel’yanov ◽  
S. A. Zabelkin ◽  
M. F. Gilfanov ◽  
...  

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