pyrolysis gases
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2021 ◽  
Vol 11 (22) ◽  
pp. 10570
Author(s):  
Hermes Scandelli ◽  
Azita Ahmadi-Senichault ◽  
Jean Lachaud ◽  
Franck Richard

The numerical simulation of fire propagation requires capturing the coupling between wood pyrolysis, which leads to the production of various gaseous species, and the combustion of these species in the flame, which produces the energy that sustains the pyrolysis process. Experimental and numerical works of the fire community are targeted towards improving the description of the pyrolysis process to better predict the rate of production and the chemical nature of the pyrolysis gases. We know that wood pyrolysis leads to the production of a large variety of chemical species: water, methane, propane, carbon monoxide and dioxide, phenol, cresol, hydrogen, etc. With the idea of being able to capitalize on such developments to study more accurately the physics of fire propagation, we have developed a numerical framework that couples a detailed three-dimensional pyrolysis model and fireFoam. In this article, we illustrate the capability of the simulation tool by treating the combustion of a wood log. Wood is considered to be composed of three phases (cellulose, hemicellulose and lignin), each undergoing parallel degradation processes leading to the production of methane and hydrogen. We chose to simplify the gas mixture for this first proof of concept of the coupling of a multi-species pyrolysis process and a flame. In the flame, we consider two separate finite-rate combustion reactions for methane and hydrogen. The flame evolves during the simulation according to the concentration of the two gaseous species produced from the material. It appears that introducing different pyrolysis species impacts the temperature and behavior of the flame.


Author(s):  
O.B. Sezonenko ◽  
O.O. Vasechko ◽  
V.V. Aleksyeyenko ◽  
A.V. Snihur

Materials of practical research work on thermal destruction of paper waste were presented. The main task was The comprehensive study of the aspects of carbon formation on the basis of analytical studies was considered, as well as using a specially built laboratory installation — a waste graphitizer. Research has been carried out on the effectivity of application of pyrolysis gases of the process as fuel to maintain the temperatures of the thermal destruction reaction. Practical examples have proved the possibility and expediency of using the solid residue of the reaction as a component in various fields of production. Bibl. 10, Fig. 1, Tab. 3.


Author(s):  
Xiaobin Chen ◽  
Yuting Tang ◽  
Chuncheng Ke ◽  
Chaoyue Zhang ◽  
Sichun Ding ◽  
...  
Keyword(s):  

2021 ◽  
pp. 103424
Author(s):  
Sahand Rasoulipour ◽  
Charles Fleischmann ◽  
Luke Merciec ◽  
Nicole Adams

2021 ◽  
pp. 333-342
Author(s):  
Andrey Borisovich Shishmakov ◽  
Yuliya Vladimirovna Mikushina ◽  
Ol'ga Vasil'yevna Koryakova

By pyrolysis of powdered cellulose granules impregnated with palladium nitrate, catalysts of 1–8% Pd / C were obtained. Pyrolysis was carried out in a reactor with a water seal at 600 ° C. Metal reduction was carried out with pyrolysis gases and matrix carbon. It was found that the ash content of powdered cellulose granules is ~ 40 times less than the ash content of sulfate cellulose, from which they were made. It was shown by X-ray phase analysis and electron microscopy that palladium in the catalysts is present in the form of Pd (0) nanoparticles uniformly covering carbon fibers and shapeless massive metal precipitates up to 20 μm in diameter. In catalysts 1–3% Pd / С, nanoparticles 10–40 nm dominate (> 95%), in 8% Pd / С, 20–70 nm. The share of massive metal formations in Pd (1%) / C, Pd (3%) / C and Pd (8%) / C is: ~ 2%, ~ 5% and ~ 60%, respectively. They consist of aggregated spherical particles 0.05–0.15 µm in diameter. XRD palladium oxide was not detected in the catalysts. The presence of palladium nitrate in powdered cellulose during its carbonization has a significant effect on the formation of the carbon matrix. With an increase in the content of palladium nitrate in powdered cellulose, the yield of carbon material decreases and its total porosity increases. Infrared spectroscopy revealed the presence of oxygen-containing ether groups in the carbon matrix of palladium catalysts. The activity of catalysts in the model process of decomposition of hydrogen peroxide increases with increasing dispersion of palladium nanoparticles.


2021 ◽  
Vol 25 (5) ◽  
pp. 46-51
Author(s):  
A.N. Rasstegaev ◽  
A.M. Gonopolsky ◽  
K.V. Tarantsev ◽  
K.R. Tarantseva ◽  
V.V. Golubovsky

An assessment of the efficiency and safety of the formaldehyde decontamination process containing solid waste of wood-chip boards by method of medium-temperature dry pyrolysis at the installation developed by the authors was evaluated. Sawdust of chip boards and coke ash residue after their pyrolysis were subjected to biological examination. The test objects were Daphnia magna Straus, algae Scenedesmus quadricauda and luminescent bacteria. It was revealed that pyrolysis of these wastes at the proposed plant will reduce the load on the hydrosphere and reduce the ratio of dilution of water extracts by more than half. Analysis of the composition of pyrolysis gases showed that the mass concentration of nitrogen oxides and carbon in the air of the working zone does not exceed the MPC of the working zone and MPC of settlements. The conclusion on environmental safety of the process of pyrolysis of formaldehyde-containing solid wastes at the proposed installation is made.


2021 ◽  
Vol 124 ◽  
pp. 46-53
Author(s):  
Sihua Xu ◽  
Fu Yang ◽  
Hongyun Hu ◽  
Linxia Gao ◽  
Tongzhou Chen ◽  
...  

2021 ◽  
Vol 37 (1) ◽  
pp. 40-45
Author(s):  
Khamael M. Abualnaja ◽  
Hala M. Abo-Dief ◽  
Ola A. Abu Ali ◽  
Abdullah Al-Anazi ◽  
Ashraf T. Mohamed

The oily sludge treatments catch widespread attention. But, management of sludge is difficult and costly undertaking. The oil recovery pyrolysis temperature, heating rate and carbon wt.% is discussed. The recovered aliphatic, aromatic, elemental components and gases were obtained with respect to the nitrogen flow rate. The present work showed that as the heating rate increases, both the %pyrolysis oil and gases increases up to 600 OC, while the %pyrolysis char decreases. Beyond 600 OC, the pyrolysis gases% increases, the pyrolysis oil% decreases while the %pyrolysis char continuous decreases. Gas chromatography, and calorific value used to examine the hydrocarbon compositions of the virgin, sludge, and pyrolysis oils.


2021 ◽  
Vol 247 ◽  
pp. 01056
Author(s):  
Alexey Demin ◽  
Grigorii Pavlov ◽  
Mansur Khasiyatullov

The results of the study of joint pyrolysis of various types of waste (municipal solid waste, plastic waste, etc.) are presented. Preliminarily crushed and dried wastes were fed into the pyrolysis chamber of the model experimental setup. Thermal energy required for heating raw materials and carrying out their thermal destruction was obtained by burning a part of the pyrolysis gases. The rest of these gases were removed from the pyrolysis chamber and cooled. The temperature in the pyrolysis zone was about 650 °C. Plant productivity was up to 500 kg/h. The target product was the liquid phase, which is a mixture of hydrocarbon compounds. When organizing the processes, the yield of solid carbon residue was minimized. The obtained mass ratio of the final gas/liquid products was approximately equal to 1/6. Experimental results of the analysis of the chemical composition of the gas and liquid fractions are presented. The results of modeling the combustion of pyrolysis products at different amounts of supplied air are also shown. The operating parameters at which the optimum temperature level in the pyrolysis zone is maintained are numerically determined and recommended.


Author(s):  
Nyamsuren B ◽  
Barsbold Kh ◽  
Buyan-Ulzii B ◽  
Baasanjargal T ◽  
Enkhsaruul B

Bench-scale methanation experiments were performed using the mixture gases evolved in pyrolysis of Tavantolgoi weathered coal and of Baganuur thermal coal. The methanation reactor was composed of the parts of feed gas desulfurization, fixed bed main reactor, condenser and dryer of product gases. The preliminary desulfurized feed gas passed through the fixed bed methanation reactor with the three layers of Ni/Al2O3 catalyst mixed with different amounts of quartz in order to avoid from overheating in upper level of the catalyst. Methanation experiments of pyrolysis gases were performed at temperatures of 250°С and 350˚°С, in a pressure of 3 bar with a GHSV of 9000 h-1. In methanation of pyrolysis gas from the Tavantolgoi weathered coal, CH4 content was increased 10 times from 3.20% to 34.4% at 250°С, however CH4 content was increased 3 times from 9.60% to 29.4% during the methanation of Baganuur coal pyrolysis gas at 350°С. Тавантолгойн болон Багануурын нүүрсний пиролизын хийн метанжуулалтын томруулсан туршилт Хураангуй: Энэхүү судалгааны ажлаар Тавантолгойн ордын исэлдсэн давхаргын нүүрс болон Багануурын ордын үндсэн давхаргын нүүрсний пиролизоос үүссэн хийг метанжуулах томруулсан (бэнч) хэмжээний туршилтыг хийж гүйцэтгэв. Метанжуулалтын томруулсан төхөөрөмж нь хүхэргүйжүүлэгч, конденсатор, чийг шингээгч болон хөдөлгөөнгүй үет реактор бүхий урвалын систем байхаар зохион бүтээсэн. Нүүрсний пиролизын хийг кварцтай хольж Ni/Al2O3 катализаторын гурван үеэр нэвтрүүлж, дулаан дамжуулалтын усгүй шийдлийг хэрэглэсэн. Метанжуулалтын томруулсан туршилтыг 250°С болон 350˚°С температуруудад, 3 бар даралтанд, 9000 h-1 түүхий эдийн урсгал хурдтай нөхцөлд хийж гүйцэтгэв. Тавантолгойн ордын исэлдсэн давхаргын нүүрсний пиролизын хийг метанжуулахад бүтээгдэхүүн хий дэх метаны агуулга 3.20%-иас 34.4% хүрч 10 дахин ихсэж, харин Багануурын нүүрсний хийнээс үүссэн метаны агуулга 9.60%-иас 29.4% болж 3 дахин ихэслээ. Хэдийгээр метанжуулах процессын температур харьцангуй нам байсан боловч Тавантолгойн ордын исэлдсэн давхаргын нүүрсний пиролизын хийн метанжуулалтын дүнд үүссэн метан хийн агуулга нь Багануурын ордын үндсэн давхаргын нүүрсний пиролизын хийтэй харьцуулахад 5.01%-иар их байлаа.


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