Geographical identification of Chianti red wine based on ICP-MS element composition

2020 ◽  
Vol 315 ◽  
pp. 126248 ◽  
Author(s):  
Benedetta Bronzi ◽  
Claudio Brilli ◽  
Gian Maria. Beone ◽  
Maria Chiara Fontanella ◽  
Davide Ballabio ◽  
...  
Keyword(s):  
Red Wine ◽  
2020 ◽  
Vol 105 (6) ◽  
pp. 820-832 ◽  
Author(s):  
Aleksandr S. Stepanov ◽  
Leonid V. Danyushevsky ◽  
Ross R. Large ◽  
Indrani Mukherjee ◽  
Irina A. Zhukova

Abstract Pyrite is a common mineral in sedimentary rocks and is the major host for many chalcophile trace elements utilized as important tracers of the evolution of the ancient hydrosphere. Measurement of trace element composition of pyrite in sedimentary rocks is challenging due to fine-grain size and intergrowth with silicate matrix and other sulfide minerals. In this contribution, we describe a method for calculation of trace element composition of sedimentary pyrite from time-resolved LA-ICP-MS data. The method involves an analysis of both pyrite and pyrite-free sediment matrix, segmentation of LA-ICP-MS spectra, normalization to total, regression analysis of dependencies between the elements, and calculation of normalized composition of the mineral. Sulfur is chosen as an explanatory variable, relative to which all regressions are calculated. The S content value used for calculation of element concentrations from the regressions is calculated from the total, eliminating the need for independent constraints. The algorithm allows efficient measurement of concentrations of multiple chalcophile trace elements in pyrite in a wide range of samples, including quantification of detection limits and uncertainties while excluding operator bias. The data suggest that the main sources of uncertainties in pyrite composition are sample heterogeneity and counting statistics for elements of low abundance. The analysis of regression data of time-resolved LA-ICP-MS measurements could provide new insights into the geochemistry of the sedimentary rocks and minerals. It allows quantification of ratios of elements that do not have reference material available (such as Hg) and provides estimates on the content of non-sulfidic Fe in the silicate matrix. Regression analysis of the mixed LA-ICP-MS signal could be a powerful technique for deconvolution of phase compositions in complex multicomponent samples.


2020 ◽  
pp. 3-23
Author(s):  
Igor Migachev ◽  
Olga Minina ◽  
Vadim Zvezdov

A comprehensive study of native gold from Mnogovershinnoye gold cluster ores and placers (granulometry, crystal morphology, internal structure, nature of exogenetic transformations, fineness and trace element composition) was performed to define placer association with primary sources. Using ICP-MS method and X-ray spectrographic analysis, new data on geochemical gold features was obtained, which expands and clarifies the evidence of gold typomorphism from a gold-silver deposit primary source and its association with placers.


LITOSFERA ◽  
2018 ◽  
pp. 928-941
Author(s):  
Lubov’ M. Kondratyeva ◽  
Oksana S. Polevskaya ◽  
Evgeniya M. Golubeva ◽  
Anna V. Shtareva ◽  
Natal’ya S. Konovalova

Object of research.The aim of this work was the comparative analysis of element composition of groundwater (drip, fracture), water from the interior of the watercourse in a karst cave Proshchal’naya (Khabarovsk Territory) and the surface water of the nearest river Sagdy-Selanka. The great interest was the study of speleothem (dropstones) “moon milk” in the cave Proshchal’naya.Materials and methods.Speleothem “moon milk” was investigated with a scanning electron microscope (EVO-40HV, CarlZeiss, Germany) and silicon-drift x-ray detector X-MAX 80 мм2 . By ICP-MS method a comparative analysis of element composition of groundwater (drip, fracture), water from an internal stream in the cave Proshchal’naya and surface water of the river Sagdy-Selenka were carried out.Results.Maximum concentrations of calcium, iron and manganese was installed in the spring, between drip and fracture water and magnesium – in flowing waters (inland watercourse caves and Sagdy-Selanka R.). It was determined that visually plastic and homogeneous mass of speleothem “moon milk” is heterogeneous and contains various microstructures. Tubular microstructures were represented by richer elemental compo sition (C, O, Ca, Fe, Mn, Si, Al, and S) compared with club-shaped formations (C, O, Ca, and Na). The binding matrix in the composition of the “moon milk” were reticular structures similar to actinomycente mycelium and bacterial films. Findings. The results of studies conducted in a monsoon climate may be interesting for researchers which study karst processes in other climatic zones.


2012 ◽  
Vol 710 ◽  
pp. 33-39 ◽  
Author(s):  
Fabrina R.S. Bentlin ◽  
Clarissa M.M. dos Santos ◽  
Érico M.M. Flores ◽  
Dirce Pozebon

2019 ◽  
pp. 80-86
Author(s):  
N. A. Golubkina ◽  
Ju. P. Shevchenko ◽  
V. A. Kharchenko ◽  
O. V. Kosheleva ◽  
A. V. Soldatenko

Chicory is widely cultivated in many countries of the world due to high nutritional and pharmacological value. The possibility of chicory forcing in winter provides quick production of salad heads, which biochemical characteristics are not fully described. Concentration of sugars, water soluble compounds and antioxidants in roots, leaves and stumps of salad C.intybus Konus cv are studied. Element composition of roots and leaves is obtained using ICP-MS method. The highest amount of water soluble compounds and ascorbic acid was indicated in stumps, while the highest polyphenol concentration was demonstrated in leaves. Antioxidant activity of alcoholic extracts reached maximum in leaves and did not differ between roots and stumps. The ability of Konus variety to hyperaccumulate selenium was revealed for the first time: selenium concentration reached 2800 mcg/kg d.w. in roots and 3800 mcg/kg d.w. in leaves. Konus cv was characterized also by high accumulation of chromium, manganese, molybdenum and iron. Uneven distribution of elements between roots and leaves are demonstrated for all elements except Al, As and Si. Intensive root-leaves transport was revealed for Ca, Cr, Cu, Fe, K, Mg, Mn, Mo, Ni, P, Pb, Se and Zn and decreased rootleaves flow for B, Cd, Co, Li, Sn, Sr, V and especially Na. One hundred g of fresh leaves provides 22% of the daily adequate consumption levels for Se, 91%- for Cr, 15%- for Mo, 14%- for Fe and 12 % for Mn. The results suppose high prospects of C.intybus Konus cv as a functional food, capable to optimize the human Se and Cr status.


2012 ◽  
Vol 9 (8) ◽  
pp. 10615-10644 ◽  
Author(s):  
L. Jonkers ◽  
L. J. de Nooijer ◽  
G.-J. Reichart ◽  
R. Zahn ◽  
G.-J. A. Brummer

Abstract. Crust formation is a common phenomenon in planktonic foraminifera. Because of their different formation mechanism and hence composition, crusts affect the overall test composition and therefore complicate the use of crust-bearing foraminifera in paleoceanography. Such species are often used to estimate subsurface paleotemperatures and although the influence of the crust on the trace element/Ca ratio is recognised, it has not been systematically explored between and within tests. Here we use laser ablation ICP-MS to assess the variability in trace element composition of the crust of Neogloboquadrina dutertrei within individual chambers, as well as the effect of compositional heterogeneity of the crust on whole test chemistry. Compositionally, the outer crust differs from inner layer by lower Mg/Ca and Mn/Ca, but is indistinguishable in Sr/Ca. Crust thickness decreases towards the younger chambers and it may be entirely absent from the last chamber. In contrast to Mn/Ca and Sr/Ca, crustal Mg/Ca ratios show a tendency towards higher values on the younger chambers. These patterns in crust thickness and in crust Mg/Ca indicates that temperature is not the dominant factor controlling crust composition. Temperature estimates based on N. dutertrei, and presumably other crust-forming species too, are therefore biased towards too low values. Through comparison of modern and glacial tests we show that this bias is not constant and that changes in the crust thickness and/or in the Mg/Ca values can spuriously suggest temperature changes.


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