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<p>Near-term decarbonization of aviation requires energy-dense, renewable liquid fuels. Biomass-
derived 1,4-dimethylcyclooctane (DMCO), a cyclic alkane with a volumetric net heat of
combustion up to 9.2% higher than Jet-A, has the potential to serve as a low-carbon, high-
performance jet fuel blendstock that may enable paraffinic bio-jet fuels to operate without
aromatic compounds. DMCO can be produced from bio-derived isoprenol (3-methyl-3-buten-1-
ol) through a multi-step upgrading process. This study presents detailed process configurations
for DMCO production to estimate the minimum selling price and life-cycle greenhouse gas
(GHG) footprint considering three different hydrogenation catalysts and two bioconversion
pathways. The platinum-based catalyst offers the lowest production cost and GHG footprint of
$9.0/L-Jet-Aeq and 61.4 gCO2e/MJ, given the current state of technology. However, when the
conversion process is optimized, hydrogenation with a Raney nickel catalyst is preferable,
resulting in a $1.5/L-Jet-Aeq cost and 18.3 gCO2e/MJ GHG footprint if biomass sorghum is the
feedstock. This price point requires dramatic improvements, including 28 metric-ton/ha
sorghum yield and 95-98% of the theoretical maximum conversion of biomass-to-sugars,
sugars-to-isoprenol, isoprenol-to-isoprene, and isoprene-to-DMCO. Because increased
gravimetric energy density of jet fuels translates to reduced aircraft weight, DMCO also has the
potential to improve aircraft efficiency, particularly on long-haul flights.
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