Catalytic ethylene production from ethanol dehydration over non-modified and phosphoric acid modified Zeolite H-Y (80) catalysts

2017 ◽  
Vol 158 ◽  
pp. 85-95 ◽  
Author(s):  
Jiah Chee Soh ◽  
Soo Ling Chong ◽  
Sk Safdar Hossain ◽  
Chin Kui Cheng
2021 ◽  
Vol 10 (4) ◽  
pp. 75-79
Author(s):  
Loc Bui Tan ◽  
Tu Le Nguyen Quang ◽  
Long Nguyen Quang

The catalytic dehydration of ethanol is a potential alternative route to synthesize ethylene apart from the traditional method which depends on fossil fuels. This report successfully prepared modified ZSM-5 with mesopores using desilication methods to enhance ethanol catalytic dehydration performance and ethylene production at lower temperature. The modified zeolite have the external surface area increased by 3.5 times and a higher dehydration efficiency compared with the original sample especially at temperatures below 220°C. Increasing reaction temperatures and gas houly space velocity (GHSV) increased the dehydration efficiency while increasing the inlet ethanol concentration had opposite effect. Significantly, the ethanol conversion over modified zeolite remained above 90 % when the GHSV increased to 36000 h‑1 after the time-on-stream of 24 h.


Fuel ◽  
2019 ◽  
Vol 239 ◽  
pp. 491-501 ◽  
Author(s):  
Maria Clara H. Clemente ◽  
Gesley Alex V. Martins ◽  
Elon F. de Freitas ◽  
José A. Dias ◽  
Sílvia C.L. Dias

Author(s):  
K. V. Thiruvengadaravi ◽  
J. Nandagopal ◽  
P. Baskaralingam ◽  
V. Sathya Selva Bala ◽  
P. Vijayalakshmi ◽  
...  

2009 ◽  
Vol 6 (3) ◽  
pp. 729-736 ◽  
Author(s):  
P. Panneerselvam ◽  
V. Sathya Selva Bala ◽  
N. Thinakaran ◽  
P. Baskaralingam ◽  
M. Palanichamy ◽  
...  

The sorptive removal of nickel ion from aqueous solutions using modified ZSM-5 zeolites was investigated. Experiments were carried out as a function of solute concentration and different temperatures. Mesoporous material of ZSM-5 zeolite was modified with phosphoric acid by wet method. The modified zeolite was converted to Na+form using aqueous NaHCO3solution. The Na+form of modified zeolite, represented as PNa2--ZSM-5 was characterized by XRD, BET, SEM and AAS techniques. It was then tested for ion exchange with aqueous Ni(SO4) solution. The Ni2+content of the solution was analyzed by AAS. Phosphoric acid modified PNa2--ZSM-5 zeolite shows higher adsorption capacity than the parent Na-Y zeolite. Equilibrium modeling data were fit to linear Langmuir model then the Freundlich model. These parameter confirmed that sorption of Ni2+is feasible spontaneous and endothermic.


1990 ◽  
Vol 115 (2) ◽  
pp. 294-298 ◽  
Author(s):  
Janusz Prusinski ◽  
Anwar A. Khan

Seeds (intact or slit) of lettuce (Luctuca sativa L.) cultivars with greater ability to produce ethylene germinated better under stressful conditions. Highly significant correlations were found between ethylene production and germination in 0.1 m NaCI (- 0.49 MPa) solution at 25C (r = 0.95, intact seeds), in - 0.3 MPa PEG solution (r = 0.86, intact seeds; r = 0.81, slit seeds), and in water at 32C (r = 0.80, slit seeds) or 35C (r = 0.80, slit seeds). Slitting the seed coat increased the ethylene production and improved germination during osmotic restraint in most cultivars, particularly in `Mesa 659' and `Super 59'. The differing ability of cultivars to produce ethylene during stress generally corresponded with their ability to generate germination potential. Ethylene production and germination potential in untreated and ACC-treated `Mesa 659' seeds increased upon slitting under stressful conditions. Thus, the ability of seeds to produce ethylene and to generate high germination potential under stressful conditions may be used as criteria to select stress-tolerant lettuce cultivars. Chemical names used: polyethylene glycol 8000 (PEG), 1-aminocyclopropane-1-carboxylic acid (ACC), (2-chlorethyl) phosphoric acid (ethephon).


2020 ◽  
Vol 249 ◽  
pp. 119323 ◽  
Author(s):  
Yoke Wang Cheng ◽  
Chi Cheng Chong ◽  
Chin Kui Cheng ◽  
Kim Hoong Ng ◽  
Thongthai Witoon ◽  
...  

2020 ◽  
Vol 264 ◽  
pp. 118517 ◽  
Author(s):  
Juan Li ◽  
Guanying Chen ◽  
Jiahao Yan ◽  
Baibiao Huang ◽  
Hefeng Cheng ◽  
...  

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