Comparative investigation on removal of thallium(Ⅰ) from wastewater using low-grade pyrolusite and pyrolysis residue derived from oily sludge: Performance, mechanism and application

Author(s):  
Ge Zhang ◽  
Huifen Yang ◽  
Zhen Li ◽  
Meiling Jiang ◽  
Qingping Zhang
2021 ◽  
Vol 651 (4) ◽  
pp. 042058
Author(s):  
Xuan Sun ◽  
Zhiqiang Guo ◽  
Faguo Zhong ◽  
Zhibin Wu ◽  
Penghui Yang ◽  
...  

2018 ◽  
Vol 36 (12) ◽  
pp. 904-909 ◽  
Author(s):  
Ayhan Demirbas ◽  
Sukru Acar ◽  
Bilgehan Yabgu Horasan ◽  
Walid M. Alalayah
Keyword(s):  

2011 ◽  
Vol 393-395 ◽  
pp. 1398-1404
Author(s):  
Yu Shuang Wang ◽  
Chun Xu Wu ◽  
Hong Tao Zhang ◽  
Zhao Lin Chen ◽  
Guo Qing Yuan ◽  
...  

Economical and effective oily sludge pyrolysis residue was prepared, characterized with various techniques, and applied in the removal of COD in biologically treated oil-field wastewater. It was found that surface area of oily sludge pyrolysis residue was 223.62 m2 /g. The content of C and Al2O3 was 27.91% and 27.6%, respectively. Oily sludge pyrolysis residue contains carboxyl, hydroxyl, carbonyl and other oxygen-containing acid functional groups. When the adsorption equilibrium time of oily sludge pyrolysis residue was 90min, pH of solution was 4, the best COD adsorption capacity was 59.5 mg/g. Adsorption of oily sludge pyrolysis residue is determined by its structure and composition. The Al2O3 may play a flocculation and sedimentation role in COD removal, which has a synergistic effect on adsorption. The adsorption of COD from biologically treated oil-field wastewater by oily sludge pyrolysis residue follows Langmuir adsorption isotherm.


Author(s):  
Thomas R. McKee ◽  
Peter R. Buseck

Sediments commonly contain organic material which appears as refractory carbonaceous material in metamorphosed sedimentary rocks. Grew and others have shown that relative carbon content, crystallite size, X-ray crystallinity and development of well-ordered graphite crystal structure of the carbonaceous material increases with increasing metamorphic grade. The graphitization process is irreversible and appears to be continous from the amorphous to the completely graphitized stage. The most dramatic chemical and crystallographic changes take place within the chlorite metamorphic zone.The detailed X-ray investigation of crystallite size and crystalline ordering is complex and can best be investigated by other means such as high resolution transmission electron microscopy (HRTEM). The natural graphitization series is similar to that for heat-treated commercial carbon blacks, which have been successfully studied by HRTEM (Ban and others).


Author(s):  
V.K. Berry

There are two strains of bacteria viz. Thiobacillus thiooxidansand Thiobacillus ferrooxidanswidely mentioned to play an important role in the leaching process of low-grade ores. Another strain used in this study is a thermophile and is designated Caldariella .These microorganisms are acidophilic chemosynthetic aerobic autotrophs and are capable of oxidizing many metal sulfides and elemental sulfur to sulfates and Fe2+ to Fe3+. The necessity of physical contact or attachment by bacteria to mineral surfaces during oxidation reaction has not been fairly established so far. Temple and Koehler reported that during oxidation of marcasite T. thiooxidanswere found concentrated on mineral surface. Schaeffer, et al. demonstrated that physical contact or attachment is essential for oxidation of sulfur.


Author(s):  
Gejing Li ◽  
D. R. Peacor ◽  
D. S. Coombs ◽  
Y. Kawachi

Recent advances in transmission electron microscopy (TEM) and analytical electron microscopy (AEM) have led to many new insights into the structural and chemical characteristics of very finegrained, optically homogeneous mineral aggregates in sedimentary and very low-grade metamorphic rocks. Chemical compositions obtained by electron microprobe analysis (EMPA) on such materials have been shown by TEM/AEM to result from beam overlap on contaminant phases on a scale below resolution of EMPA, which in turn can lead to errors in interpretation and determination of formation conditions. Here we present an in-depth analysis of the relation between AEM and EMPA data, which leads also to the definition of new mineral phases, and demonstrate the resolution power of AEM relative to EMPA in investigations of very fine-grained mineral aggregates in sedimentary and very low-grade metamorphic rocks.Celadonite, having end-member composition KMgFe3+Si4O10(OH)2, and with minor substitution of Fe2+ for Mg and Al for Fe3+ on octahedral sites, is a fine-grained mica widespread in volcanic rocks and volcaniclastic sediments which have undergone low-temperature alteration in the oceanic crust and in burial metamorphic sequences.


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