Analysis and predictive correlation of mass transfer coefficient KGav of blended MDEA-MEA for use in post-combustion CO2 capture

2013 ◽  
Vol 19 ◽  
pp. 3-12 ◽  
Author(s):  
Abdulaziz Naami ◽  
Teerawat Sema ◽  
Mohamed Edali ◽  
Zhiwu Liang ◽  
Raphael Idem ◽  
...  
2021 ◽  
Vol 7 (1) ◽  
pp. 25
Author(s):  
Pao-Chi Chen ◽  
Hsun-Huang Cho ◽  
Jyun-Hong Jhuang ◽  
Cheng-Hao Ku

In order to select the best mixed amines in the CO2 capture process, the absorption of CO2 in mixed amines was explored at the required concentrations by using monoethanolamine (MEA) as a basic solvent, mixed with diisopropanolamine (DIPA), triethanolamine (TEA), 2-amino-2-methyl-1-propanol (AMP), and piperazine (PZ). Here, a bubble column was used as the scrubber, and a continuous operation was adopted. The Taguchi method was used for the experimental design. The conditional factors included the type of mixed amine (A), the ratio of the mixed amines (B), the liquid feed flow (C), the gas-flow rate (D), and the concentration of mixed amines (E). There were four levels, respectively, and a total of 16 experiments. The absorption efficiency (EF), absorption rate (RA), overall mass transfer coefficient (KGa), and scrubbing factor (ϕ) were used as indicators and were determined in a steady-state by the mass balance and two-film models. According to the Taguchi analysis, the importance of the parameters and the optimum conditions were obtained. In terms of the absorption efficiency (EF), the absorption rate (absorption factor) (RA/ϕ), and the overall mass transfer coefficient (KGa), the order of importance is D > E > A > B > C, D > E > C > B > A, and D > E > C > A > B, respectively, and the optimum conditions are A1B4C4D3E3, A1B3C4D4E2, A4B2C3D4E4, and A1B1C1D4E1. The optimum condition validation results showed that the optimal values of EF, RA, and KGa are 100%, 30.69 × 10−4 mol/s·L, 1.540 l/s, and 0.269, respectively. With regard to the selection of mixed amine, it was found that the mixed amine (MEA + AMP) performed the best in the CO2 capture process.


Energies ◽  
2020 ◽  
Vol 13 (20) ◽  
pp. 5465
Author(s):  
Nattee Akkarawatkhoosith ◽  
Wannarak Nopcharoenkul ◽  
Amaraporn Kaewchada ◽  
Attasak Jaree

This work focused on the application of a microchannel contactor for CO2 capture using water as absorbent, especially for the application of CO2-rich gas. The influence of operating conditions (temperature, volumetric flow rate of gas and liquid, and CO2 concentration) on the absorption efficiency and the overall liquid-side volumetric mass transfer coefficient was presented in terms of the main effects and interactions based on the factorial design of experiments. It was found that 70.9% of CO2 capture was achieved under the operating conditions as follows; temperature of 50 °C, CO2 inlet fraction of 53.7%, total gas volumetric flow rate of 150 mL min−1, and adsorbent volumetric flow rate of 1 mL min−1. Outstanding performance of CO2 capture was demonstrated with the overall liquid-side volumetric mass transfer coefficient of 0.26 s−1. Further enhancing the system by using 2.2 M of monoethanolamine in water (1:1 molar ratio of MEA-to-CO2) boosted the absorption efficiency up to 88%.


1986 ◽  
Vol 51 (10) ◽  
pp. 2127-2134 ◽  
Author(s):  
František Potůček ◽  
Jiří Stejskal

Absorption of oxygen into water and aqueous solutions of poly(acrylamides) was studied in an absorber with a wetted sphere. The effects of changes in the liquid flow rate and the polymer concentration on the liquid side mass transfer coefficient were examined. The results are expressed by correlations between dimensionless criteria modified for non-Newtonian liquids whose flow curve can be described by the Ostwald-de Waele model.


2021 ◽  
Vol 33 (1) ◽  
Author(s):  
Sher Ahmad ◽  
Gabriela Vollet Marson ◽  
Waheed Ur Rehman ◽  
Mohammad Younas ◽  
Sarah Farrukh ◽  
...  

Abstract Background In this research work, a coupled heat and mass transfer model was developed for salt recovery from concentrated brine water through an osmotic membrane distillation (OMD) process in a hollow fiber membrane contactor (HFMC).The model was built based on the resistance-in-series concept for water transport across the hydrophobic membrane. The model was adopted to incorporate the effects of polarization layers such as temperature and concentration polarization, as well as viscosity changes during concentration. Results The modeling equations were numerically simulated in MATLAB® and were successfully validated with experimental data from literature with a deviation within the range of 1–5%. The model was then applied to study the effects of key process parameters like feed concentrations, osmotic solution concentration, feed, and osmotic solution flow rates and feed temperature on the overall heat and mass transfer coefficient as well as on water transport flux to improve the process efficiency. The mass balance modeling was applied to calculate the membrane area based on the simulated mass transfer coefficient. Finally, a scale-up for the MD process for salt recovery on an industrial scale was proposed. Conclusions This study highlights the effect of key parameters for salt recovery from wastewater using the membrane distillation process. Further, the applicability of the OMD process for salt recovery on large scale was investigated. Sensitivity analysis was performed to identify the key parameters. From the results of this study, it is concluded that the OMD process can be promising in salt recovery from wastewater.


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