A novel kind of copper–active carbon nanocomposites with their high hydrogen storage capacities at room temperature

2007 ◽  
Vol 32 (12) ◽  
pp. 1943-1948 ◽  
Author(s):  
Juan Hu ◽  
Qiuming Gao ◽  
Yihua Wu ◽  
Shuqing Song
2010 ◽  
Vol 150-151 ◽  
pp. 88-91
Author(s):  
Huo Gen Huang ◽  
Rong Li ◽  
Liang Chen

Ti-Zr-Ni icosahedral quasicrystals (IQCs) have been regarding as potential hydrogen storage materials due to their high hydrogen ability. Nevertheless, their hydrogen capacities are largely different as reported by different researchers, which is toughly understood.We investigated in this paper deuterium absorption at room temperature for quasicrystalline alloys Ti45Zr38Ni17, Ti41.5Zr41.5Ni17, Ti40Zr40Ni20 with corresponding phase structures of IQC+β(Ti,Zr), IQC+C14(TiZrNi), IQC. The results indicated the same solid solution state for the deuterium in these alloys, whose deuterium concentration was 12~13mmol/g. Given that all these alloys are in a single IQC phase, we believe very similar deuterium capacities for them, which surely needs more strict experimental evidence.


2010 ◽  
Vol 654-656 ◽  
pp. 2819-2822
Author(s):  
Hayao Imamura ◽  
Naotaka Shimomura ◽  
Keisuke Watanabe ◽  
Kenichi Tanaka ◽  
Fumiya Nakamura ◽  
...  

Hydrogen storage by calcium nitride or magnesium nitride has been undertaken by the use of ammonia, in which the possibility of ammonia as a vector for hydrogen carriers has been studied. When the calcium imide ornitride obtained by thermal decomposition of calcium amide dispersed on active carbon (AC) was brought into contact with ammonia gas (300 Torr) at room temperature, NH3 uptake readily occurred. When the sample after NH3 uptake was heated, the absorbed ammonia was released in the form of hydrogen and nitrogen. The ammonia is possibly absorbed in the form of the decomposed state in the imide ornitride. This type of hydrogen storage has been extensively studied and characterized.For magnesium nitride, ammonia was absorbed and desorbed without the decomposition.


2011 ◽  
Vol 312-315 ◽  
pp. 882-887
Author(s):  
Dalibor Vojtěch ◽  
Vítězslav Knotek ◽  
Pavel Novák

Mg-based alloys are prospective materials for reversible hydrogen storage in the form of metallic hydrides. Usually, hydrogen saturation is carried out at high temperatures and high hydrogen pressures. This is the reason for the high cost of metallic hydrides in comparison with other hydrogen storage methods. Electrochemical hydriding, on the other hand, can be realized at room temperature. Moreover, this process does not need any hydrogen atmosphere. In the presented work, electrochemical hydriding of several Mg-Ni-Mm-based alloys (Mm = mishmetal) is performed. Hydriding efficiency, mechanism and kinetics are described. It is shown that the additions of Ni, Mm and the formation of eutectic structures support hydriding of alloys.


Carbon ◽  
2009 ◽  
Vol 47 (6) ◽  
pp. 1585-1591 ◽  
Author(s):  
Seung Jae Yang ◽  
Jung Hyun Cho ◽  
Gyu Hwan Oh ◽  
Kee Suk Nahm ◽  
Chong Rae Park

2007 ◽  
Vol 16 (8) ◽  
pp. 1517-1523 ◽  
Author(s):  
Nor Hasridah Abu Hassan ◽  
Abdul Rahman Mohamed ◽  
Sharif Hussein Sharif Zein

2001 ◽  
Vol 706 ◽  
Author(s):  
Xiaohong Chen ◽  
Urszula Dettlaff-Weglikowska ◽  
Miroslav Haluska ◽  
Martin Hulman ◽  
Siegmar Roth ◽  
...  

AbstractThe hydrogen adsorption capacity of various carbon nanostructures including single-wall carbon nanotubes, graphitic nanofibers, activated carbon, and graphite has been measured as a function of pressure and temperature. Our results show that at room temperature and a pressure of 80 bar the hydrogen storage capacity is less than 1 wt.% for all samples. Upon cooling, the capacity of hydrogen adsorption increases with decreasing temperature and the highest value was observed to be 2.9 wt. % at 50 bar and 77 K. The correlation between hydrogen storage capacity and specific surface area is discussed.


2021 ◽  
Vol 2039 (1) ◽  
pp. 012005
Author(s):  
D V Blinov ◽  
V I Borzenko ◽  
A V Bezdudny ◽  
A N Kazakov

Abstract The results of the development of metal hydride (MH) reactors for the storage and purification of hydrogen of various types are presented. Two methods of metal hydride purification of hydrogen are presented. The use of the MH method of flow-through purification of hydrogen has high hydrogen recovery rates at high volume contents of hydrogen in the mixture (⩾10% vol.), while the method of periodic evacuation of accumulated impurities is most effective at low hydrogen contents in the mixture (<10% vol.).


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