Synthesis, characterization, optical and electrical properties of nanostructured poly(aniline-co-o-bromoaniline) prepared by in-situ polymerization method

Optik ◽  
2016 ◽  
Vol 127 (8) ◽  
pp. 3984-3988 ◽  
Author(s):  
A. Mahudeswaran ◽  
J. Vivekanandan ◽  
A. Jeeva ◽  
J. Chandrasekaran ◽  
P.S. Vijayanand
Keyword(s):  
Electrical Properties ◽  
In Situ Polymerization ◽  
Optical And Electrical Properties ◽  
Polymerization Method ◽  
Poly Aniline

Enhanced cycling stability of silicon anode by in situ polymerization of poly(aniline-co-pyrrole)

RSC Advances ◽  
2014 ◽  
Vol 4 (96) ◽  
pp. 54134-54139 ◽  
Author(s):  
Qingtao Wang ◽  
Ruirong Li ◽  
Dong Yu ◽  
Xiaozhong Zhou ◽  
Jian Li ◽  
...  
Keyword(s):  
Anode Material ◽  
In Situ Polymerization ◽  
Chemical Oxidation ◽  
Silicon Anode ◽  
Composite Anode ◽  
Chemical Oxidation Polymerization ◽  
Si Nanoparticles ◽  
Polymerization Method ◽  
Poly Aniline

Poly(aniline-co-pyrrole)-encapsulated Si nanoparticles composite anode material were prepared by an in situ chemical oxidation polymerization method.

Optical and Electrical Properties of Organic Conducting Polymers

2014 ◽  
Vol 8 (1) ◽  
pp. 1457-1463
Author(s):  
Salah Abdulla Hasoon
Keyword(s):  
Electrical Properties ◽  
Conjugated Polymer ◽  
Polymeric Materials ◽  
Quantum Mechanical ◽  
Optical And Electrical Properties ◽  
Electrically Conducting ◽  
Temperature Ranges ◽  
Lithium Tetrafluoroborate ◽  
Absorbance Peak ◽  
Polymerization Method

Novel electrically conducting polymeric materials are prepared in this work. Polythiophene (PT) and poly (3-Methelthiophene) (P3MT) films were prepared by electro-polymerization method using cyclic voltammetry in acetonitrile as a solvent and lithium tetrafluoroborate as the electrolyte on a gold electrode. Electrical properties of P3MT have been examined in different environments using UV-Vis absorption spectroscopy and quantum mechanical ab initio calculations, The observed absorption peaks at 314 and 415 nm, were attributed to the n-π* and π-π* transitions, respectively in the conjugated polymer chain, in contrast, the observed absorbance peak at 649 nm, is responsible for electric conduction. The temperature dependence of the conductivity can be fitted to the Arrhenius and the VTF equations in different temperature ranges.

Synthesis and Characterizations of Poly(Butylene Succinate) Copolyester

2014 ◽  
Vol 1015 ◽  
pp. 381-384
Author(s):  
Li Liu ◽  
Li Hai Cai ◽  
Dan Liu ◽  
Jun Xu ◽  
Bao Hua Guo
Keyword(s):  
Mechanical Properties ◽  
Polymer Matrix ◽  
Crystallization Temperature ◽  
In Situ Polymerization ◽  
Nucleating Agent ◽  
Single Fiber ◽  
Butylene Succinate ◽  
Crystallization Behaviors ◽  
Polymerization Method

The poly (butylene succinate) (PBS) and 3 wt% attapulgite (ATP) reinforced PBS/ATP nanocomposites with 1,6-hexanediol were fabricated using an in situ polymerization method. The crystallization behaviors indicated that ATP had effectively acted as nucleating agent, resulting in the enhancement on the crystallization temperature. The SEM results showed a superior interfacial linkage between ATP and PBS. Also, ATP could disperse as a single fiber and embed in the polymer matrix, which resulted in the improved mechanical properties.

High-performance textile electrodes for wearable electronics obtained by an improved in situ polymerization method

2019 ◽  
Vol 361 ◽  
pp. 897-907 ◽  
Author(s):  
Jingchun Lv ◽  
Peiwen Zhou ◽  
Linping Zhang ◽  
Yi Zhong ◽  
Xiaofeng Sui ◽  
...  
Keyword(s):  
High Performance ◽  
In Situ Polymerization ◽  
Wearable Electronics ◽  
Textile Electrodes ◽  
Polymerization Method

SYNTHESIS, STRUCTURAL, OPTICAL AND ELECTRICAL PROPERTIES OF IN-SITU SYNTHESIZED POLYANILINE/SILVER NANOCOMPOSITES

2012 ◽  
Vol 05 (03) ◽  
pp. 1250026 ◽  
Author(s):  
FAHAD ALAM ◽  
SAJID ALI ANSARI ◽  
WASI KHAN ◽  
M. EHTISHAM KHAN ◽  
A. H. NAQVI
Keyword(s):  
Single Phase ◽  
In Situ Polymerization ◽  
Optical And Electrical Properties ◽  
Silver Colloid ◽  
Dielectric Measurements ◽  
Temperature Dependent ◽  
Colloidal Form ◽  
Uv Visible ◽  
Temperature Dependent Resistivity

Polyaniline (PANI) is recognized as one of the most important conducting polymers due to its high conductivity and good stability. In this paper, polyaniline/silver (PANI/Ag) nanocomposites were synthesized by in-situ polymerization of aniline using ammonium peroxydisulphate (APS) as oxidizing agent with varying concentration of Ag nanoparticles colloids (0 ml, 25 ml and 50 ml). Silver nanoparticles were synthesized separately in colloidal form from silver nitrate (Ag2NO3) with the help of reducing agent sodium borohydride (NaBH4). The PANI/ Ag nanocomposites were characterized by XRD, SEM, AFM, UV-visible, temperature dependent resistivity and dielectric measurements. All samples show a single phase nature of the nanoparticles. The electrical resistivity as function of temperature was measured in the temperature range 298–383 K, which indicates a semiconducting to metallic transition at 373 K and 368 K for 25 ml and 50 ml silver colloid samples, respectively.

High-density polyethylene/graphene oxide nanocomposites prepared via in situ polymerization: Morphology, thermal, and electrical properties

2018 ◽  
Vol 16 ◽  
pp. 232-241 ◽  
Author(s):  
Antonio Cruz-Aguilar ◽  
Dámaso Navarro-Rodríguez ◽  
Odilia Pérez-Camacho ◽  
Salvador Fernández-Tavizón ◽  
Carlos Alberto Gallardo-Vega ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Electrical Properties ◽  
High Density Polyethylene ◽  
In Situ Polymerization ◽  
High Density ◽  
Thermal And Electrical Properties

scholarly journals High Performance Attapulgite/Polypyrrole Nanocomposite Reinforced Polystyrene (PS) Foam Based on Supercritical CO2 Foaming

Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 985 ◽  
Author(s):  
Yidong Liu ◽  
Lingfeng Jian ◽  
Tianhua Xiao ◽  
Rongtao Liu ◽  
Shun Yi ◽  
...  
Keyword(s):  
Supercritical Co2 ◽  
High Performance ◽  
In Situ Polymerization ◽  
Compression Modulus ◽  
Blowing Agents ◽  
Foaming Process ◽  
Potential Applications ◽  
Polymerization Method ◽  
Low Solubility

CO2 has been regarded as one of the most promising blowing agents for polystyrene (PS) foam due to its non-flammability, low price, nontoxicity, and eco-friendliness. However, the low solubility and fast diffusivity of CO2 in PS hinder its potential applications. In this study, an attapulgite (ATP)/polypyrrole (PPy) nanocomposite was developed using the in situ polymerization method to generate the hierarchical cell texture for the PS foam based on the supercritical CO2 foaming. The results demonstrated that the nanocomposite could act as an efficient CO2 capturer enabling the random release of it during the foaming process. In contrast to the pure PS foam, the ATP/PPy nanocomposite reinforced PS foam is endowed with high cell density (up to 1.9 × 106) and similar thermal conductivity as the neat PS foam, as well as high compression modulus. Therefore, the in situ polymerized ATP/PPy nanocomposite makes supercritical CO2 foaming desired candidate to replace the widely used fluorocarbons and chlorofluorocarbons as PS blowing agents.

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