Bioethanol production from detoxified hydrolysate and the characterization of oxalic acid pretreated Eucalyptus (Eucalyptus globulus) biomass

2016 ◽  
Vol 83 ◽  
pp. 322-328 ◽  
Author(s):  
Chandan Kundu ◽  
Jae-Won Lee
2020 ◽  
Author(s):  
Madhur Kumar Dubey ◽  
Naman Jain ◽  
Atul Kumar ◽  
Gaurang Deep ◽  
Md Sharib

DYNA ◽  
2019 ◽  
Vol 86 (210) ◽  
pp. 98-107
Author(s):  
Luz Marina Flórez Pardo ◽  
Andrea González Córdoba ◽  
Jorge Enrique López Galán

In this research, the types of hemicellulose that predominate in the leaves and tops of the three most cultivated varieties (CC 8475, CC 8592, V 7151) of sugarcane (Saccharum officinarum L.) in Valle del Cauca, Colombia were determined. Hemicellulose analyses were performed after delignification with sodium chlorite and extraction with 18% NaOH and 24% KOH containing 0.26 M NaBH4. The main components of hemicellulose were identified via FTIR and NMR spectroscopy, and monomeric sugars were identified via HPLC. Hemicellulose A composed of arabinoxylans, glucomannans and arabinogalactactans and hemicellulose B primarily composed of arabinoxylans were extracted. The hemicelluloses of the Colombian varieties were more stable against heat than those of the Venezuelan variety. The results of this project allowed discovery of the potential use of agricultural sugarcane residues for bioethanol production because they have a holocellulose content of more than 60%.


2013 ◽  
Vol 61 (2) ◽  
pp. 379-386 ◽  
Author(s):  
Hanyu Yangcheng ◽  
Hongxin Jiang ◽  
Michael Blanco ◽  
Jay-lin Jane

BioResources ◽  
2014 ◽  
Vol 9 (2) ◽  
Author(s):  
Raymundo Sánchez Orozco ◽  
Patricia Balderas Hernández ◽  
Gabriela Roa Morales ◽  
Fernando Ureña Núñez ◽  
Juan Orozco Villafuerte ◽  
...  

Holzforschung ◽  
2008 ◽  
Vol 62 (5) ◽  
Author(s):  
Jorge Rencoret ◽  
Gisela Marques ◽  
Ana Gutiérrez ◽  
David Ibarra ◽  
Jiebing Li ◽  
...  

Abstract The chemical structure of milled-wood lignins from Eucalyptus globulus, E. nitens, E. maidenii, E. grandis, and E. dunnii was investigated. The lignins were characterized by analytical pyrolysis, thioacidolysis, and 2D-NMR that confirmed the predominance of syringyl over guaiacyl units and only showed traces of p-hydroxyphenyl units. E. globulus lignin had the highest syringyl content. The heteronuclear single quantum correlation (HSQC) NMR spectra yielded information about relative abundances of inter-unit linkages in the whole polymer. All the lignins showed a predominance of β-O-4′ ether linkages (66–72% of total side-chains), followed by β-β′ resinol-type linkages (16–19%) and lower amounts of β-5′ phenylcoumaran-type (3–7%) and β-1′ spirodienone-type linkages (1–4%). The analysis of desulfurated thioacidolysis dimers provided additional information on the relative abundances of the various carbon-carbon and diaryl ether bonds, and the type of units (syringyl or guaiacyl) involved in each of the above linkage types. Interestingly, 93–94% of the total β-β′ dimers included two syringyl units indicating that most of the β-β′ substructures identified in the HSQC spectra were of the syringaresinol type. Moreover, three isomers of a major trimeric compound were found which were tentatively identified as arising from a β-β′ syringaresinol substructure attached to a guaiacyl unit through a 4-O-5′ linkage.


2019 ◽  
Vol 944 ◽  
pp. 650-656
Author(s):  
Ming Rui Zhang ◽  
Yuan Qin ◽  
Dao Zhang ◽  
Guang Yuan Wang ◽  
Sen Yang

The liquid phase reduction-heat treatment has been used to prepare V2O3nanoparticles in this paper. It is a novel method that the precursor was developed by Oxalic acid dehydrate (H2C2O4·2H2O) reduction of V2O5powder in anhydrous ethanol. V2O3nanoparticles were successfully obtained by thermal treatment of the precursor. The phase, composition, structure, and morphology of the as-obtained samples were verified by XRD, XPS, SEM and TEM measurements. Meanwhile, the possible formation mechanism of V2O3in the heat-treatment is briefly discussed by analyzing the DSC.


Minerals ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 859
Author(s):  
Lovasoa C. Razanamahandry ◽  
Assumpta C. Nwanya ◽  
Michael O. Akharame ◽  
Badeggi U. Muhammad ◽  
Seteno K.O. Ntwampe ◽  
...  

Mine wastewater (MW) is often rich in heavy metals that can have measurable effects on humans. The storage and treatment of MW remains a challenge for most mining companies. Iron (Fe) in MW was removed by using extracts from Eucalyptus globulus (EG); Callistemon viminalis (CV); and Persea americana (AS). Fe was removed from MW samples with an initial concentration of 5.53 mg Fe mL−1; 4.63 mg Fe mL−1 and 4.40 mg Fe mL−1 using EG leaves, CV flowers and AS seed extracts, respectively. Conditions of the MW decontamination were studied by varying the dosage of the plant extracts, the temperature of the medium and the contact time between the MW and the plant extracts. Undiluted plant extracts—which were mixed with the MW and heated at 45 °C for 3 h—gave the highest Fe-removal efficiency for CV (70%) and AS (53%) extracts, respectively. Similarly, EG extracts, albeit heated at 25 °C, showed a higher Fe-removal efficiency (85%) than the CV and AS extracts at low to high temperatures. The residual Fe concentration in the MW was 0.83 mg Fe mL−1, 1.39 mg Fe mL−1 and 2.07 mg Fe mL−1 for EG, CV and AS extracts, respectively. Residue solid-phase deposits from the precipitation reaction of the MW with the plant extracts were collected and analyzed. Fe was among the byproducts detected in the deposited material. The characterization of the annealed solid-phase deposits revealed Fe precipitates as maghemite-C (Fe2O3) and magnetite (FeFe2O4) nanoparticles. Therefore, the MW quality and form were improved, making it reusable for other purposes.


2015 ◽  
Vol 4 (1) ◽  
pp. 112-120 ◽  
Author(s):  
Madhuka Roy ◽  
Krishnendu Kundu ◽  
V. R. Dahake

Enhanced rate of fossil fuel extraction is likely to deplete limited natural resources over short period of time. So search for alternative fuel is only the way to overcome this problem of upcoming energy crisis. In this aspect biofuel is a sustainable option. Agricultural lands cannot be compromised for biofuel production due to the requirement of food for the increasing population. Certain species of algae can produce ethanol during anaerobic fermentation and thus serve as a direct source for bioethanol production. The high content of complex carbohydrates entrapped in the cell wall of the microalgae makes it essential to incorporate a pre-treatment stage to release and convert these complex carbohydrates into simple sugars prior to the fermentation process. There have been researches on production of bioethanol from a particular species of algae, but this work was an attempt to produce bioethanol from easily available indigenous algae. Acid hydrolysis was carried out as pre-treatment. Gas Chromatographic analysis showed that 5 days’ fermentation by baker’s yeast had yielded 93% pure bioethanol. The fuel characterization of the bioethanol with respect to gasoline showed comparable and quite satisfactory results for its use as an alternative fuel.DOI: http://dx.doi.org/10.3126/ije.v4i1.12182International Journal of Environment Volume-4, Issue-1, Dec-Feb 2014/15, page: 112-120  


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