Rapid Microwave Method for Synthesis of Iron Oxide Particles under Specific Conditions

The advantages of microwave technology over conventionally conducted experiments are numerous. Some of them are reduction in reaction time, a higher degree of process control, repeatability, and work safety. Microwave synthesis routes require a complete description of the experimental details, instrumentation, and design program of a microwave oven used in the experiments. In this work, microwave-assisted hydrothermal synthesis of hematite (α-Fe2O3) particles from 0.1 M FeCl3 solution in highly alkaline media with heating in a microwave oven at continuous microwave emission of 800 W at 150 °C, 200 °C, and 250 °C for 20 min are presented. Also, the influence of the percentage of the addition of a cationic surfactant, cetyltrimethylammonium bromide (CTAB) on the composition, size, and shape of the final product was investigated. The samples precipitated at 150 °C formed a final product consisting of goethite (α-FeOOH) and hematite particles in contrast to the those precipitated at 200 °C and 250 °C where pure hematite phase was obtained. In these synthesis routes, the CTAB caused to slow down the rate of the goethite-to-hematite transformation process at temperatures at 200 °C but did not affect the transformation at 250 °C.

Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone

Research into the solvent extraction of iron(III) from a chloride solution after bauxite HCl leaching by neutral oxygen-containing extractants and their mixtures were studied and the iron(III) extraction degree from chloride solutions using alcohols is presented. The effect of dilution of alcohol with a ketone by an extraction mixture in relation to its effectiveness was investigated. The iron(III) was efficiently extracted by the mixture of 1-octanol and 1-decanol (70%) with 2-undecanone (30%) from hydrochloric bauxite leach liquor at an O:A ratio = 2-4:1 at an iron(III) concentration of 7.4 g/L and 6 M HCl. For the removal of iron-containing organic phase from impurities (Al, Ca, Cr) that are co-extracted with iron(III), we used two step scrubbing at O:A = 5:1 by 7 M HCl as a scrub solution. The iron(III) stripping at the O:A ratio is shown. Using counter-current cascade of extractors, it was possible to obtain an FeCl3 solution with the iron(III) content of 90.5 g/L and total impurities less than 50 mg/L.

An Environmentally Friendly and Economical Strategy to Cyclically Produce Cellulose Nanocrystals with High Thermal Stability and High Yield

Cellulose nanocrystals (CNCs) have been widely used in various industries; however, green, efficient, low-cost and recyclable CNC preparation still faces great challenges. Herein, ferric chloride (FeCl3) solution was used as...

The Electrical Conductivty Of Fe-Chitosan Schiff Base Complex

High electrical conductivity material Fe-Chitosan Schiff base produced via two stages mechanism, reaction of salicylaldehyde and chitosan in three necked flask following the formation of complex by soak Chitosan Schiff base in FeCl3 solution in various times. The formed Schiff base was confirmed by presence of imine at 1604.77 cm-1. Next, Fe absorption was analyzed by using ICP-MS gives highest results at 492,51 ppm at 5 hours immersion time. The electrical conductivity exhibit tendency to increase and the highest point at 3.5 x 10-6 S cm­-1

On the Electrical and Optical Properties Stability of P3HT Thin Films Sensitized with Nitromethane Ferric Chloride Solutions

The electrical and optical properties stability of poly(3-hexylthiophene) (P3HT) thin films sensitized with nitromethane ferric chloride (FeCl3) solution was investigated. The optical properties modifications were studied by spectrophotometry and ellipsometry. For electrical characterizations, electrical resistivity measurements were performed. In agreement with the observations of other authors, an important decrease in the electrical resistivity by six orders of magnitude was noticed. In addition, the repeatability and stability of this phenomenon were investigated over a few weeks after sensitization and during different cycles of heating and cooling, both in the dark and under illumination.

Modified Biochar—A Tool for Wastewater Treatment

Global deposits of concentrated phosphates, which are a necessary source for the production of phosphate fertilizers, are limited. These reserves keep getting thinner, and every day, large amounts of phosphorus end up in watercourses. In this study, we verified that modified biochar (saturated with FeCl3 solution and then neutralized with NaOH solution) can adsorb significant amounts of phosphorus from wastewater. Moreover, the agrochemical qualities of sludge water from a municipal wastewater treatment plant, struvite, phosphorus-saturated biochar, and iron(III) phosphate from a reused biochar filter were tested in this study. We determined the amount of mobile phosphorus as well as the amount of extractable phosphorus and its five fractions. It was found that modified biochar can hold one-third of the phosphorus amount contained in the commonly used agricultural fertilizer simple superphosphate (1 × 105 g of modified biochar captures up to 2.79 × 103 g of P). Moreover, plants can more easily access phosphorus biochar fractions than struvite, which is formed spontaneously during sludge management. The results of this research prove that the proposed method of recycling phosphorus from wastewater can be applied in technological practice.

Easy and Fast Fabrication of Self-Cleaning and Anti-Icing Perfluoroalkyl Silane Film on Aluminium

A combination of the chemical etching process in FeCl3 solution and chemical surface grafting by immersion in ethanol solution containing 1H,1H,2H,2H-perfluorodecyltriethoxysilane is a viable route to achieve a hierarchical surface topography and chemical bonding of silane molecules on an aluminium surface leading to (super)hydrophobic characteristics. Characterisation of untreated and treated aluminium surfaces was carried out using contact profilometry, optical tensiometry, scanning electron microscopy coupled with energy-dispersive spectroscopy and X-ray photoelectron spectroscopy to define the surface topography, wettability, morphology and surface composition. Additionally, the dynamic characteristics were evaluated to define bouncing and the self-cleaning effect. A thermal infrared camera was employed to evaluate anti-icing properties. The micro/nano-structured etched aluminium surface grafted with perfluoroalkyl silane film showed excellent superhydrophobicity and bounce dynamics in water droplet tests. The superhydrophobic aluminium surface exhibited the efficient self-cleaning ability of solid pollutants as well as improved anti-icing performance with melting delay.

Effect of Pre-Strain and Aging Heat Treatment on the Corrosion Behavior for 2205 Duplex Stainless Steel in 6% FeCl3 Solution

A 2205 duplex stainless steel (DSS) was pre-stretched to 5% and subsequently aged at 850 °C for 0–120 minutes, to explore the effects of pre-strain and aging treatment on the corrosion behavior of the DSS in 6% FeCl3 solution at 50 °C for 72 hours. The microstructure, hardness and corrosion behavior of the pre-strained and aged DSS were investigated based on statistical data and physical metallurgy in comparison with the counterparts without pre-strain. The results showed that the sigma (σ) phase precipitated firstly in δ-ferrite grain boundaries and then in δ-ferrite/γ-austenite (δ/γ) phases boundaries by consuming the volume fraction of δ-ferrite. The volume fraction of σ phase in the DSS with and without pre-strain increased with increasing aging times following a classical Johnson-Mehl-Avrami (JMA) relationship, and the kinetics of the precipitation of σ phase was accelerated by pre-strain throughout the aging time of 60–120 min. The hardness of the non-pre-strained DSS (NP-DSS) was lower than that of pre-strained DSS (P-DSS) throughout 0–120 min at 850 °C. The hardness of NP-DSS increased continuously with increasing aging time, and the hardness of P-DSS decreased firstly and then increased continuously with increasing aging time. The aged NP-DSS displayed a gradually serious pitting with increasing aging time, and the corresponding corrosion behavior of the aged P-DSS exhibited pitting firstly and then mainly cracking, and the pitting occurred in the vicinity of δ/σ and γ/σ boundaries.

Sorption and Desorption of Remazol Yellow by a Fe-Zeolitic Tuff

The adsorption of remazol yellow from aqueous solution was evaluated using a Fe-zeolitic tuff. The adsorbent was characterized by scanning electron microscopy, IR spectroscopy and X-Ray diffraction. Sorption kinetic and isotherms were determined and the adsorption behavior was analyzed. Kinetic pseudo-second order and Langmuir-Freundlich models were successfully applied to the experimental results, indicating chemisorption on a heterogeneous material. The regeneration of the material was best accomplished by using a H2O2 solution. The sorption capacity of the Fe-zeolitic tuff increased when the saturated samples were treated with a H2O2 or FeCl3 solution.