Synthesis of zinc oxide nanorods from chemical bath deposition at different pH solutions and impact on their surface properties

2017 ◽  
Vol 704 ◽  
pp. 788-794 ◽  
Author(s):  
Sanjay A. Gawali ◽  
Satish. A. Mahadik ◽  
F. Pedraza ◽  
C.H. Bhosale ◽  
Habib M. Pathan ◽  
...  
Author(s):  
Ahmad Nuruddin ◽  
Brian Yuliarto ◽  
Santi Kurniasih ◽  
Henry Setiyanto ◽  
Aditianto Ramelan

2014 ◽  
Vol 92 (7/8) ◽  
pp. 838-841 ◽  
Author(s):  
Kevin Farmer ◽  
Parameswar Hari ◽  
Kenneth Roberts

Controlled growth of ZnO nanorods on various substrates is of great interest in photonic and electronic device applications. Also of interest is increasing the optical activity of zinc oxide nanorods in the visible spectrum. In this study, we report pH dependence for the morphology and photoluminescence of aligned ZnO nanorods grown on an indium tin oxide (ITO) coated glass substrate deposited by a wet chemical bath deposition method. The ZnO nanorods were grown by a chemical bath deposition technique using equimolar ratios of zinc (II) nitrate and hexamethylenetetramine in solution at 95 °C. The pH of the reaction solution prior to oven heating was varied from pH 5 to 10.6. Surface properties of the ZnO nanorods on ITO substrates were studied using scanning electron microscopy and photoluminescence spectroscopy. We also compared the use of NaOH to adjust the pH with the use of NH4OH, the latter necessary at higher pH due to the relative insolubility of zinc. It was found that the size of the nanorods can vary twofold with pH and the choice of base. Uniformity of coverage is also significantly dependent upon these variables and will be discussed as it relates to solubility and crystal growth. It was also found that the intensity of the photoluminescence in the visible range is pH dependent. For example, the intensity of luminescence at 550 nm for ZnO nanorods grown at pH 7 using NH4OH is 532% of the corresponding emission for a sample prepared at pH 5.


2011 ◽  
Vol 15 (6) ◽  
pp. 401-405 ◽  
Author(s):  
S K Lim ◽  
H Q Le ◽  
G K L Goh ◽  
K K Lin ◽  
S B Dolmanan

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 877 ◽  
Author(s):  
Swarup Roy ◽  
Hyun Chan Kim ◽  
Pooja S. Panicker ◽  
Jong-Whan Rhim ◽  
Jaehwan Kim

Here, we report the fabrication and characterization of cellulose nanofiber (CNF)-based nanocomposite films reinforced with zinc oxide nanorods (ZnOs) and grapefruit seed extract (GSE). The CNF is isolated via a combination of chemical and physical methods, and the ZnO is prepared using a simple precipitation method. The ZnO and GSE are used as functional nanofillers to produce a CNF/ZnO/GSE film. Physical (morphology, chemical interactions, optical, mechanical, thermal stability, etc.) and functional (antimicrobial and antioxidant activities) film properties are tested. The incorporation of ZnO and GSE does not impact the crystalline structure, mechanical properties, or thermal stability of the CNF film. Nanocomposite films are highly transparent with improved ultraviolet blocking and vapor barrier properties. Moreover, the films exhibit effective antimicrobial and antioxidant actions. CNF/ZnO/GSE nanocomposite films with better quality and superior functional properties have many possibilities for active food packaging use.


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