Energy storage and photosensitivity of in-situ formed silver-copper (Ag-Cu) heterogeneous nanoparticles generated using multi-tool micro electro discharge machining process

2021 ◽  
pp. 162950
Author(s):  
Ishwar Bhiradi ◽  
Somashekhar S. Hiremath
Author(s):  
Juan Li ◽  
Bo Wang ◽  
Tianzhao Hu ◽  
Yuzuo Wang ◽  
Zhenhua Sun ◽  
...  

Sodium-ion hybrid capacitors are emerging as the promising energy storage and power output devices. However, they suffer from sluggish faradaic reaction of anode and low capacity of cathode. Zeolite-templated carbons...


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Xing Shen ◽  
Quan Zhou ◽  
Miao Han ◽  
Xingguo Qi ◽  
Bo Li ◽  
...  

AbstractNa-ion batteries have been considered promising candidates for stationary energy storage. However, their wide application is hindered by issues such as high cost and insufficient electrochemical performance, particularly for cathode materials. Here, we report a solvent-free mechanochemical protocol for the in-situ fabrication of sodium vanadium fluorophosphates. Benefiting from the nano-crystallization features and extra Na-storage sites achieved in the synthesis process, the as-prepared carbon-coated Na3(VOPO4)2F nanocomposite exhibits capacity of 142 mAh g−1 at 0.1C, higher than its theoretical capacity (130 mAh g−1). Moreover, a scaled synthesis with 2 kg of product was conducted and 26650-prototype cells were demonstrated to proof the electrochemical performance. We expect our findings to mark an important step in the industrial application of sodium vanadium fluorophosphates for Na-ion batteries.


Nanoscale ◽  
2021 ◽  
Author(s):  
Qiufan Wang ◽  
Jiaheng Liu ◽  
Guofu Tian ◽  
Daohong Zhang

The rapid development of human-machine interface and artificial intelligence is dependent on flexible and wearable soft devices such as sensors and energy storage systems. One of the key factors for...


Physchem ◽  
2021 ◽  
Vol 1 (1) ◽  
pp. 26-44
Author(s):  
Chiara Ferrara ◽  
Riccardo Ruffo ◽  
Piercarlo Mustarelli

Extended interphases are playing an increasingly important role in electrochemical energy storage devices and, in particular, in lithium-ion and lithium metal batteries. With this in mind we initially address the differences between the concepts of interface and interphase. After that, we discuss in detail the mechanisms of solid electrolyte interphase (SEI) formation in Li-ion batteries. Then, we analyze the methods for interphase characterization, with emphasis put on in-situ and operando approaches. Finally, we look at the near future by addressing the issues underlying the lithium metal/electrolyte interface, and the emerging role played by the cathode electrolyte interphase when high voltage materials are employed.


Author(s):  
J-B Li ◽  
K Jiang ◽  
G J Davies

A novel die-sinking micro-electro discharge machining (EDM) process is presented for volume fabrication of metallic microcomponents. In the process, a high-precision silicon electrode is fabricated using deep reactive ion etching (DRIE) process of microelectromechanical systems (MEMS) technology and then coated with a thin layer of copper to increase the conductivity. The metalized Si electrode is used in the EDM process to manufacture metallic microcomponents by imprinting the electrode onto a flat metallic surface. The two main advantages of this process are that it enables the fabrication of metallic microdevices and reduces manufacturing cost and time. The development of the new EDM process is described. A silicon component was produced using the Surface Technology Systems plasma etcher and the DRIE process. Such components can be manufactured with a precision in nanometres. The minimum feature of the component is 50 μm. In the experiments, the Si component was coated with copper and then used as the electrode on an EDM machine of 1 μm resolution. In the manufacturing process, 130 V and 0.2 A currents were used for a period of 5 min. The SEM images of the resulting device show clear etched areas, and the electric discharge wave chart indicates a good fabrication condition. The experimental results have been analysed and the new micro-EDM process is found to be able to fabricate 25 μm features.


Batteries ◽  
2021 ◽  
Vol 7 (3) ◽  
pp. 53
Author(s):  
Purna C. Ghimire ◽  
Arjun Bhattarai ◽  
Tuti M. Lim ◽  
Nyunt Wai ◽  
Maria Skyllas-Kazacos ◽  
...  

Progress in renewable energy production has directed interest in advanced developments of energy storage systems. The all-vanadium redox flow battery (VRFB) is one of the attractive technologies for large scale energy storage due to its design versatility and scalability, longevity, good round-trip efficiencies, stable capacity and safety. Despite these advantages, the deployment of the vanadium battery has been limited due to vanadium and cell material costs, as well as supply issues. Improving stack power density can lower the cost per kW power output and therefore, intensive research and development is currently ongoing to improve cell performance by increasing electrode activity, reducing cell resistance, improving membrane selectivity and ionic conductivity, etc. In order to evaluate the cell performance arising from this intensive R&D, numerous physical, electrochemical and chemical techniques are employed, which are mostly carried out ex situ, particularly on cell characterizations. However, this approach is unable to provide in-depth insights into the changes within the cell during operation. Therefore, in situ diagnostic tools have been developed to acquire information relating to the design, operating parameters and cell materials during VRFB operation. This paper reviews in situ diagnostic tools used to realize an in-depth insight into the VRFBs. A systematic review of the previous research in the field is presented with the advantages and limitations of each technique being discussed, along with the recommendations to guide researchers to identify the most appropriate technique for specific investigations.


Sign in / Sign up

Export Citation Format

Share Document