Controllable atom implantation for achieving Coulomb-force unbalance toward lattice distortion and vacancy construction for accelerated water splitting
The reactivity of CeO2–Sc2O3 solid solution for solar hydrogen production via two-step water-splitting reaction has been studied in this work. The CeO2–Sc2O3 solid solution was synthesized by polymerized complex method (PCM) with various Sc content between 0 and 20 mol. %. Analysis results from online direct gas mass spectrometry (DGMS) suggest that Ce3 + formed by CeO2–Sc2O3 solid solution in the O2-releasing step could be completely oxidized by H2O to generate hydrogen and return to Ce4 + in the H2-generation step. A Ce0.97Sc0.03O1.985 generates the largest amount of O2 and H2 among present samples, and the reduction and oxidation ratios are about 9.9% (Ce) and 10% (Ce), respectively. An estimated H2-generation reaction rate is about 4 ml g−1min−1 for Ce0.97Sc0.03O1.985. This value is about seven times greater than that of Ce0.89Zr0.11O2. The high reaction rate of Ce0.97Sc0.03O1.985 makes all formed Ce3 + completely oxidized by H2O in 5 min in the H2-generation step. The reasons for high performance are discussed from the views of lattice distortion and the amount of oxygen vacancies formed in the lattice.
Lattice distortion is an important way to improve the electrocatalytic performance and stability of two-dimensional transition metal materials (2d-TMSs). Herein, a lattice distortion nickel-molybdenum sulfide electrocatalyst on foam nickel (NiMoS4-12/NF)...
A self-supported dual-cation (Mo,Cu) co-doped Ni2P@ nickel foam catalyst (Mo,Cu-Ni2P@NF) has been prepared, the co-doped samples can distort the lattice and expose a larger specific surface area, which provides more...
Electron crystallography is an emerging field for structure determination as evidenced by a number of membrane proteins that have been solved to near-atomic resolution. Advances in specimen preparation and in data acquisition with a 400kV microscope by computer controlled spot scanning mean that our ability to record electron image data will outstrip our capacity to analyze it. The computed fourier transform of these images must be processed in order to provide a direct measurement of amplitudes and phases needed for 3-D reconstruction.In anticipation of this processing bottleneck, we have written a program that incorporates a menu-and mouse-driven procedure for auto-indexing and refining the reciprocal lattice parameters in the computed transform from an image of a crystal. It is linked to subsequent steps of image processing by a system of data bases and spawned child processes; data transfer between different program modules no longer requires manual data entry. The progress of the reciprocal lattice refinement is monitored visually and quantitatively. If desired, the processing is carried through the lattice distortion correction (unbending) steps automatically.
A cobalt oxide catalyst prepared by a flame-assisted deposition method on the surface of FTO and hematite for electrochemical and photoelectrochemical water oxidation, respectively.
Strong Electronic Interaction in Dual‐Cation‐Incorporated NiSe
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Nanosheets with Lattice Distortion for Highly Efficient Overall Water Splitting