Thermal and catalytic decomposition of waste plastics and its co-processing with petroleum residue through pyrolysis process

2020 ◽  
Vol 265 ◽  
pp. 121639 ◽  
Author(s):  
Pamreishang Kasar ◽  
D.K. Sharma ◽  
M. Ahmaruzzaman
2021 ◽  
Vol 291 ◽  
pp. 125857
Author(s):  
Xiaodong Jing ◽  
Junqian Dong ◽  
Hanlin Huang ◽  
Yanxi Deng ◽  
Hao Wen ◽  
...  

2021 ◽  
Vol 11 (10) ◽  
pp. 4374
Author(s):  
Waldemar Ścierski

The most advantageous way of managing plastics, according to circular economy assumptions, is recycling, i.e., reusing them. There are three types of plastics recycling: mechanical, chemical and energy recycling. The products of the pyrolysis process can be used for both chemical and energy recycling. Possibilities of further use of pyrolysis products depend on their physicochemical parameters. Getting to know these parameters was the aim of the research, some of which are presented in this article. The paper presents the research position for conducting the pyrolysis process and discusses the results of research on pyrolysis products of waste plastics. The process was conducted to obtain the temperature of 425 °C in the pyrolytic chamber. Such a value was chosen on the basis of my own previous research and literature analysis. The focus was on the migration of sulfur and nitrogen, as in some processes these substances may pose a certain problem. Studies have shown high possibilities of migration of these elements in products of pyrolysis process. It has been shown that the migration of sulfur is similar in the case of homogeneous and mixed waste plastics—it immobilizes mainly in pyrolytic oil. Different results were obtained for nitrogen. For homogeneous plastics, nitrogen immobilizes mainly in char and oil, whereas for mixed plastics, nitrogen immobilizes in pyrolytic gas.


2013 ◽  
Vol 67 (12) ◽  
Author(s):  
Lukáš Gašparovič ◽  
Lukáš Šugár ◽  
Ľudovít Jelemenský ◽  
Jozef Markoš

AbstractThe present work deals with thermo-catalytic decomposition of pyrolytic oil from the scrap tire pyrolysis process. Such oil can be used as a model tar in an experimental study of tar removal from pyrolysis or gasification process gas. Several experiments under different conditions were carried out in order to determine conditions of the gasification and pyrolysis processes. Influence of the oil to steam ratio, temperature, and of the presence of dolomite catalyst was studied. Addition of water steam has positive effect on the hydrogen content in the outgoing process gas as well as on the conversion of the injected oil. The catalytic gasification experiment in a quasi steady state produced process gas with the composition: 61 mole % of H2, 6.4 mole % of CO, and 11.7 mole % of CH4. At temperatures lower than 800°C, the amount of process gas decreased resulting also in a decrease of the oil conversion. A comparison of gasification experiments using fresh calcined dolomite with experiments proceeding with regenerated dolomite was done under the same conditions. There was a decrease in the process gas volumetric flow when regenerated catalyst was used.


2021 ◽  
Author(s):  
Jin Hu

Pyrolysis technology has appeared a long time ago, but it has not been widely recognized and used in the area of waste plastic/rubber management. The key reason is that the high energy consumption of pyrolysis is the most important problem that plagues the further development of pyrolysis. Prior to the pyrolysis of waste plastics/rubbers, in addition to dehydration and drying can save part of the energy consumption of pyrolysis, in this study, we have first reviewed and discussed high irradiance exposure to artificially accelerate the aging process of waste plastics/rubbers as pretreatment. The results from our preliminary experiments show that the pyrolysis process of the plastic that has undergone UV accelerated aging was speed up, accordingly to achieve saving energy in thermal cracking.


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