scholarly journals Migration of Sulfur and Nitrogen in the Pyrolysis Products of Waste and Contaminated Plastics

2021 ◽  
Vol 11 (10) ◽  
pp. 4374
Author(s):  
Waldemar Ścierski

The most advantageous way of managing plastics, according to circular economy assumptions, is recycling, i.e., reusing them. There are three types of plastics recycling: mechanical, chemical and energy recycling. The products of the pyrolysis process can be used for both chemical and energy recycling. Possibilities of further use of pyrolysis products depend on their physicochemical parameters. Getting to know these parameters was the aim of the research, some of which are presented in this article. The paper presents the research position for conducting the pyrolysis process and discusses the results of research on pyrolysis products of waste plastics. The process was conducted to obtain the temperature of 425 °C in the pyrolytic chamber. Such a value was chosen on the basis of my own previous research and literature analysis. The focus was on the migration of sulfur and nitrogen, as in some processes these substances may pose a certain problem. Studies have shown high possibilities of migration of these elements in products of pyrolysis process. It has been shown that the migration of sulfur is similar in the case of homogeneous and mixed waste plastics—it immobilizes mainly in pyrolytic oil. Different results were obtained for nitrogen. For homogeneous plastics, nitrogen immobilizes mainly in char and oil, whereas for mixed plastics, nitrogen immobilizes in pyrolytic gas.

Processes ◽  
2021 ◽  
Vol 9 (5) ◽  
pp. 764
Author(s):  
Renato Sarc

ReWaste4.0 is an innovative and cooperative K-Project in the period 2017–2021. Through ReWaste4.0 the transformation of the non-hazardous mixed municipal and commercial waste treatment industry towards a circular economy has started by investigating and applying the new approaches of the Industry 4.0. Vision of the ReWaste4.0 is, among others, the development of treatment plants for non-hazardous waste into a “Smart Waste Factory” in which a digital communication and interconnection between material quality and machine as well as plant performance is reached. After four years of research and development, various results have been gained and the present review article summarizes, links and discuss the outputs (especially from peer-reviewed papers) of seven sub-projects, in total, within the K-project and discusses the main findings and their relevance and importance for further development of the waste treatment sector. Results are allocated into three areas, namely: contaminants in mixed waste and technical possibilities for their reduction as well as removal; secondary raw and energy materials in mixed waste and digitalization in waste characterization and treatment processes for mixed waste. The research conducted in ReWaste4.0 will be continued in ReWaste F for further development towards a particle-, sensor- and data-based circular economy in the period 2021–2025.


2021 ◽  
Vol 291 ◽  
pp. 125857
Author(s):  
Xiaodong Jing ◽  
Junqian Dong ◽  
Hanlin Huang ◽  
Yanxi Deng ◽  
Hao Wen ◽  
...  

Author(s):  
Dan Li ◽  
Shijun Lei ◽  
Ping Wang ◽  
Lei Zhong ◽  
Wenchao Ma ◽  
...  
Keyword(s):  

2021 ◽  
Author(s):  
Jun Xie ◽  
Chengqian Zhang ◽  
Yuhan Jia ◽  
Jianzhong Fu ◽  
Peng Zhao

2021 ◽  
Author(s):  
MANZHI LIU ◽  
Jixin Wen ◽  
Linlin Zhang ◽  
Jixin Wu ◽  
Xiaotao Yang ◽  
...  

Abstract Recycling waste plastics is one of the important ways to save petroleum resources and reduce carbon emissions. However, the current recycling rate of waste plastics is still low. Material flow analysis can help determine the flow of waste plastics, and life cycle assessment (LCA) can be used to quantify environmental impacts. The present study integrates these two methods into the model construction of the residents’ waste plastics recycling decision-support system. This model construction is followed by sensitivity analysis of the relevant parameters affecting the performance of the waste plastics recycling system. Finally, present study forecasts the recycling system’s performance and environmental impacts by setting four optimization scenarios based on sensitivity analysis. The results show that in 2019, A total of 8.39 million tons of high-end applications were recovered, carbon emissions during the recycling process were 34.9 million tons, and dioxin emissions were 316.11 g TEQ, with a total emission reduction of 24.47 million tons of CO2 compared to the original production. In the scenario of comprehensive improvement, in 2035, the recycling volume of high-end applications will rise to 33.96 million tons, the carbon emissions will rise to 64.73 million tons, the dioxin emissions will drop to 165.98 g TEQ, and the carbon emission reduction will rise to 99.06 million tons. This research has a certain guiding role for policy makers to formulate industry norms and related policies for waste plastic recycling.


2014 ◽  
Vol 26 (4) ◽  
pp. 367-380 ◽  
Author(s):  
Beatriz Concepción Tracanna ◽  
Silvia Nelly Martínez De Marco ◽  
María de los Ángeles Taboada ◽  
Virginia Mirande ◽  
María de Lourdes Gultemirian ◽  
...  

AIM: The Escaba dam is located in the south of the Tucumán province, Argentina, at 650 m above sea level. It has an extension of 541 ha. and a depth of 65 m and its tributaries are the Chavarría, Las Moras, El Chorro and Singuil rivers. The climate is mild with dry winters and rainy summers. The objective of this study was to characterize physicochemical parameters in the limnetic zone of the dam and the mouths of the tributaries to determine the water quality. METHODS: Seasonal sampling was carried out between August 2010 and May 2012. Temperature, transparency, pH and electrical conductivity were field measured, whereas dissolved oxygen, biochemical oxygen demand (BOD5), major ion constituents and nitrogen and phosphate compounds were analyzed at the laboratory. RESULTS: The water was classified as sodium-calcium-bicarbonate with neutral to alkaline pH, and thermal stratification during spring and summer. The water assayed was well oxygenated except for the bottom of the limnetic zone during the summer months. Lowest transparency was measured in the El Chorro River in November 2011 (0.12 m) and highest degree of transparency in the Singuil River during the winter of 2010 (4.1 m). The waters assayed showed weak mineralization with conductivities between 83 and 218 µS.cm-1. Maximum BOD5 value (183 mg.L-1) was measured in the Singuil River in spring 2010. Highest values for the different nitrogen compounds were as follows: 7 mg NO3-.L-1 at the bottom of the limnetic zone in August 2010, 0.07 mg NO2-.L-1 in the Las Moras River in May 2011 and 1.8 mg NH4+.L-1 in the Chavarría River in March 2011. During the summer of 2012 orthophosphate reached a value of 0.22 mg.L-1 at the bottom of the limnetic zone. The TN/TP ratio revealed that phosphate was generally the limiting factor and rarely nitrogen. CONCLUSIONS: Considering the TN, TP and transparency parameters the ecosystem was classified as hypertrophic. PCA allowed a seasonal differentiation of the sites, and components 1 and 2 classified the samples according to nutrient gradient, dissolved oxygen, BOD5 and temperature.


2019 ◽  
Vol 377 ◽  
pp. 34-41 ◽  
Author(s):  
Maozhi Luo ◽  
Hui Wang ◽  
Yingshuang Zhang ◽  
Yiwei Zhong ◽  
Kangyu Wang

Materials ◽  
2020 ◽  
Vol 13 (14) ◽  
pp. 3188
Author(s):  
Paweł Kazimierski ◽  
Paulina Hercel ◽  
Katarzyna Januszewicz ◽  
Dariusz Kardaś

The aim of this study was to assess the possibility of using furniture waste for smokeless fuel production using the pyrolysis process. Four types of wood-based wastes were used in the pyrolysis process: pine sawdust (PS), chipboard (CB), medium-density fiberboard (MDF), and oriented strand board (OSB). Additionally, the slow and fast types of pyrolysis were compared, where the heating rates were 15 °C/min and 100 °C/min, respectively. Chemical analyses of the raw materials and the pyrolysis product yields are presented. A significant calorific value rise was observed for the solid pyrolysis products (from approximately 17.5 MJ/kg for raw materials up to approximately 29 MJ/kg for slow pyrolysis products and 31 MJ/kg for fast pyrolysis products). A higher carbon content of char was observed in raw materials (from approximately 48% for raw materials up to approximately 75% for slow pyrolysis products and approximately 82% for fast pyrolysis products) than after the pyrolysis process. This work presents the possibility of utilizing waste furniture material that is mostly composed of wood, but is not commonly used as a substrate for conversion into low-emission fuel. The results prove that the proposed solution produced char characterized by the appropriate properties to be classified as smokeless coal.


2020 ◽  
Vol 2 (1) ◽  
Author(s):  
R. Sandhiya ◽  
Seeram Ramakrishna

AbstractAs the plastic industries aim at minimizing the environmental impact caused by mass production, growing consumption and relatively short utility span of materials and products related to plastics, they focus on circular economy (CE) principles as a feasible solution. To facilitate enhanced recycling rates and circularity of plastics, herein, we propose a model named ZERO, to implement the recycling of plastics through the emerging blockchain technology and ontology. We believe these proposed strategies will be key in building a circular economy for the plastic industries and sustainable development.


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