Pyrolytic Oil Yield from Waste Plastic in Quezon City, Philippines: Optimization Using Response Surface Methodology

Plastics play an essential role in packaging materials because of their durability to different environmental conditions. With its importance in the community lies the problem with waste disposal. Plastic is a non-biodegradable material, making it a big problem, especially when thrown in dumpsites. In solving the plastic problem, one efficient way to reduce its volume is through thermal processing such as pyrolysis. This study used the pyrolysis method to recover energy from plastic waste. Liquid oil from plastic was comparable to regular fuel used in powering engines. Before the pyrolysis process, a 3k factorial Box-Behnken Design was used in determining the number of experiments to be used. The output oil yield in each pyrolysis runs was optimized in different parameters, such as temperature, residence time, and particle size using response surface methodology to determine the optimum oil yield. Between polyethylene (PE), mixed plastic, and polystyrene (PS), PS produced its highest oil yield of 90 %. In comparison, mixed plastic produced only its highest oil yield of 45 % in 500 ºC temperature, 120 min residence time, and 3 cm particle size. The produced quadratic mathematical models in PE, mixed, and PS plastic were significant in which the p-values were less than 0.05. Using mathematical models, the optimum oil yield for PE (467.68 ºC, 120 min residence time, 2 cm particle size), mixed (500 ºC, 120 min residence time, 2.75 cm particle size) and PS plastic (500 ºC, 120 min residence time, 2 cm particle size) were 75.39 %, 46.74 %, and 91.38 %, respectively

Improvement of performance and emission characteristic of waste plastic pyrolytic oil blended diesel fuel in variable compression diesel engine using graphene nano additive

A growing interest in extracting oil from waste plastics has converged with rising demand for petro-fuels and issues in disposing of waste plastics. The characteristics of pyrolytic oil produced from plastic wastes were compared to diesel and found to be sufficiently similar to be used as an alternative fuel. In this paper, an attempt has been taken to enhance the combustion properties of waste plastic oil blended diesel following dispersion of nanographene particles. The performance and emissions of a single-cylinder direct injection compression ignition engine with compression ratios ranging from 16:1 to 18:1 was evaluated using 50, 70, and 100 ppm by using 50, 70, and 100 ppm by mass of nanographene dispersed in 20% waste plastic oil blended diesel without any engine modification. By supercharging the engine with nanographene at various compression ratios, the performance of a 20% plastic oil blended diesel is compared to that of a neat diesel. The brake thermal efficiency of 20% plastic oil blended 100 ppm graphene dispersed diesel fuel increased by 1.16% at a compression ratio of 17:1 when compared to diesel. The CO, HC, NOx emissions also dropped significantly by adding 100 ppm nanographene to WPO as compared to the other combinations of fuels.

Pengaruh Temperatur Pada Microwave Pirolisis Cangkang Kelapa Sawit dan Low Density Polyethylene Dengan Katalis Zeolite/Kalsium Oksida

In general, the use of oil palm parts can be utilized by industry, but it is different from oil palm shells which become waste. The high use of plastic is proportional to the waste generated. So far, both types of waste are problems that have not been resolved. The utilization of waste shell waste and low-density polyethylene using the pyrolysis method. Microwave technology has been widely used as a heat source in the pyrolysis process. The advantages of using microwaves in pyrolysis are fast and selective heating, efficient energy use, and control of pyrolysis products. This study aimed to determine the characteristics of Pyrolytic-oil from the pyrolysis of waste oil palm shells and Low-density polyethylene. The research was conducted using a microwave with temperature variations of 400oC, 450oC, 500oC, 550oC and 600oC. The composition of the main ingredients consisted of 75 grams of palm shells, 75 grams of low-density polyethylene plastic, 56.25 grams of a zeolite catalyst, 56.25 grams of calcium oxide and 131.25 grams of charcoal carbon absorber. The results showed the effect of temperature on pyrolytic-oil productivity; as the temperature increases, the product gas increases. The lowest density value at a temperature of 400oC is 966.8 Kg/m. The lowest viscosity at a temperature variation of 500oC is 2.1 Mpa.s. The highest acidity value is at a temperature of 550oC.

Pirolisis Campuran PET dan LDPE Menggunakan Oven Microwave

Meningkatnya kebutuhan manusia terhadap produk plastik khususnya yang berbahan PET dan LDPE berdampak pada sampah yang dihasilkan. Penelitian ini bertujuan mengetahui pengaruh daya keluaran microwave (600 W dan 800 W) pada proses microwave-assisted pyrolysis sampah PET dan LDPE. Penelitian ini mencakup tiga langkah: preparasi sampel, analisis termogravimetri, dan analisis studi kinetik. Hasil studi kinetik menunjukan bahwa peningkatan daya keluaran microwave mengakibatkan peningkatan temperatur maksimum, laju kenaikan temperatur, laju kehilangan massa, dan nilai kalor. Energi aktivasi pirolisis LDPE lebih rendah dibandingkan PET. Hasil uji GC-MS menunjukan pyrolytic oil PET didominasi oleh senyawa asetaldehid, sedangkan pada LDPE didominasi senyawa fenol. Daya keluaran microwave paling efektif yang digunakan untuk memperoleh pyrolytic oil dari PET adalah 800 W, sedangkan LDPE adalah 600 W.

Co-Pyrolysis of Neem Wood Bark and Low-Density Polyethylene: Lnfluence of Plastic on Pyrolysis Product Distribution and Bio-Oil Characterization

In this study, the investigation on effect of plastic during co-pyrolysis with biomass has been carried out in a fixed reactor. Pyrolysis of neem wood bark (NB), low density polyethylene (LDPE) and their blends at different ratios is performed in order to evaluate the product distribution. The effects of reaction temperature, NB-to-LDPE blend ratio on product distribution and chemical compositions of bio-oil are examined. The co-pyrolysis of NB and LDPE increased the yield and quality of the bio-oil. The experiments are conducted under different LDPE addition percentage such as 20%, 40%, 50%, 60% and 80%. Under the optimum experimental condition of 60% addition of LDPE and temperature of 450°C, the maximum yield of bio-oil (64.8 wt%) and hydrocarbon (75.2%) are achieved with the lowest yield of oxygenated compounds. The calorific value of the co-pyrolytic oil is found to be higher than that of NB pyrolytic oil. The relation between NB and LDPE during co-pyrolysis has been validated by GC–MS analysis, which shows in decrease of oxygenated compounds.

Sustainable Valorization of Olive Pomace Waste to Renewable Biofuels, Biomaterials and Biochemicals Via Pyrolysis Process: Experimental and Numerical Investigation

This work demonstrates, experimentally and numerically, the potential of Olive Pomace Waste (OPW) to produce renewable biofuels (pyrolytic oil and gas), bio-chemicals (tars as source of bioactive molecules) and bio-fertilizers (chars) through slow pyrolysis. Experimental pyrolysis runs were conducted at 500, 600 and 700°C as final pyrolysis temperature, 15, 20 and 25°C/min as heating rate and 1h as residence time, in a fixed bed pyrolyzer. In the optimum pyrolysis conditions (600°C and 15°C/min), 33 wt.% of oil, 30.00 wt.% of char and 37 wt.% of gas were produced. Recovered pyrolytic oil presents good energy value (HHV between 15.96 and 20.94 MJ/kg) with a great bioactive potential. The released permanent gases show an interesting energy content (LHV up to 11 MJ/Kg) which emphasizes their application in a gas engine to provide renewable electricity in rural olive groves area. The recovered OPW biochar presents a high carbon (C 72.54 wt.%) and nutrients contents (up to 8.42 mg/g of Ca, up to 8.69 mg/g of K and up to 2.02 % of total N) which make it suitable for soil amendment and for long-term carbon sequestration. Kinetic study of OPW pyrolysis, performed using the Distributed Activation Energy Model (DAEM), gives an activation energy values ranging from 121.6 to 151.6 kJ/mol. The investigation of the OPW thermal behavior and reactivity under pyrolysis conditions is useful approach to design and operate slow pyrolysis process at commercial scale, which could be useful by farmers for OPW in olive fields.