Adsorptive removal of imidacloprid by potassium hydroxide activated magnetic sugarcane bagasse biochar: Adsorption efficiency, mechanism and regeneration

2021 ◽  
Vol 292 ◽  
pp. 126005
Author(s):  
Yongfei Ma ◽  
Yong Qi ◽  
Lie Yang ◽  
Li Wu ◽  
Ping Li ◽  
...  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Shazia Perveen ◽  
Raziya Nadeem ◽  
Shaukat Ali ◽  
Yasir Jamil

Abstract Biochar caged zirconium ferrite (BC-ZrFe2O5) nanocomposites were fabricated and their adsorption capacity for Reactive Blue 19 (RB19) dye was evaluated in a fixed-bed column and batch sorption mode. The adsorption of dye onto BC-ZrFe2O5 NCs followed pseudo-second-order kinetics (R 2 = 0.998) and among isotherms, the experimental data was best fitted to Sips model as compared to Freundlich and Langmuir isotherms models. The influence of flow-rate (3–5 mL min−1), inlet RB19 dye concentration (20–100 mg L−1) and quantity of BC-ZrFe2O5 NCs (0.5–1.5 g) on fixed-bed sorption was elucidated by Box-Behnken experimental design. The saturation times (C t /C o  = 0.95) and breakthrough (C t /C o  = 0.05) were higher at lower flow-rates and higher dose of BC-ZrFe2O5 NCs. The saturation times decreased, but breakthrough was increased with the initial RB19 dye concentration. The treated volume was higher at low sorbent dose and influent concentration. Fractional bed utilization (FBU) increased with RB19 dye concentration and flow rates at low dose of BC-ZrFe2O5 NCs. Yan model was fitted best to breakthrough curves data as compared to Bohart-Adams and Thomas models. Results revealed that BC-ZrFe2O5 nanocomposite has promising adsorption efficiency and could be used for the adsorption of dyes from textile effluents.


Pedosphere ◽  
2021 ◽  
Vol 31 (4) ◽  
pp. 572-582
Author(s):  
Barbara Samartini Queiroz ALVES ◽  
Katherin Prissila Sevilla ZELAYA ◽  
Fernando COLEN ◽  
Ledivan Almeida FRAZÃO ◽  
Alfredo NAPOLI ◽  
...  

2021 ◽  
Vol 6 (2) ◽  
pp. 337-352
Author(s):  
Arif Hidayat ◽  
Winarto Kurniawan ◽  
Hirofumi Hinode

In this study, the utilization of sugarcane bagasse biochar (SCBB) as a solid catalyst was investigated for biodiesel production from palm oil industry waste residue. The catalyst was synthesized by sulfonation of SCBB to attach sulfonate functional group. Several analyses such as Nitrogen Gas Sorption Analysis, acidity, Fourier Transform Infra-Red spectroscopy, and X-ray powder diffraction (XRD) were applied to determine the properties of SCBB catalyst. The SCBB catalysts were tested to esterify the palm oil industry waste residue which contains of Free Fatty Acids (FFAs). The SCBB catalyst activity test revealed that the variables including catalyst amount, methanol to PFAD mass ratio, and temperature influenced the FFAs conversion. The highest of FFAs of 86.1% was reached at reaction temperature of 65 °C with the PFAD to methanol mass ratio of 4:1, and catalyst amount of 5 wt.% PFAD. The E-R kinetic model as developed can be described the mechanism of esterification reaction


Author(s):  
Marcos da Silva ◽  
Maria de Queiroz ◽  
Antônio Neves ◽  
Antônio da Silva ◽  
André de Oliveira ◽  
...  

2019 ◽  
Vol 48 (5) ◽  
pp. 464-471
Author(s):  
Fatma Abdelghaffar ◽  
Rehab A. Abdelghaffar ◽  
Safia A. Mahmoud ◽  
Badria M. Youssef

Purpose This paper aims to improve the adsorption capacity of sugarcane bagasse (SCB) as a low-cost, attractive and effective adsorbent for dye removal from wastewater. Design/methodology/approach SCB is a cellulosic material; it was chemically modified with compounds containing cationic groups. The adsorption efficiency of unmodified and modified SCB was investigated with anionic dyes by studying various factors that affect modified SCB and adsorption. Findings X-ray diffraction, FT-IR spectra and nitrogen content were used to confirm the effect of existence of quaternary ammonium groups on modified SCB. The morphological structure of the modified and unmodified SCB has been demonstrated using electronic scanning microscopy. Research limitations/implications The modified SCB was chemically treated by Quat 188, which is commercially available in the solution of 3-chloro-2-hydroxypropyltrimethyl ammonium chloride. Practical implications Grafting cationic function groups on the surface of sugarcane by cationization treatment enhances its adsorption efficiency for anionic dyes. Originality/value The main value of this research was indicating a clear difference in the appearance of unmodified and modified SCB surfaces. Furthermore, it can be determined that the modified SCB absorbs more of the dyes.


2017 ◽  
Vol 494 ◽  
pp. 223-241 ◽  
Author(s):  
Luide Rodrigo Martins ◽  
Josilene Aparecida Vieira Rodrigues ◽  
Oscar Fernando Herrera Adarme ◽  
Tânia Márcia Sacramento Melo ◽  
Leandro Vinícius Alves Gurgel ◽  
...  

2016 ◽  
Vol 95 ◽  
pp. 101-111 ◽  
Author(s):  
Laleh Divband Hafshejani ◽  
Abdolrahim Hooshmand ◽  
Abd Ali Naseri ◽  
Amir Soltani Mohammadi ◽  
Fariborz Abbasi ◽  
...  

Agronomy ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 156 ◽  
Author(s):  
Ping Yu ◽  
Lan Huang ◽  
Qiansheng Li ◽  
Isabel M. Lima ◽  
Paul M. White ◽  
...  

Biochar (BC) has the potential to replace bark-based commercial substrates in the production of container plants. A greenhouse experiment was conducted to evaluate the potential of mixed hardwood biochar (HB) and sugarcane bagasse biochar (SBB) to replace the bark-based commercial substrate. A bark-based commercial substrate was incorporated with either HB at 50% (vol.) or SBB at 50% and 70% (vol.), with a bark-based commercial substrate being used as the control. The total porosity (TP) and container capacity (CC) of all SBB-incorporated mixes were slightly higher than the recommended value, while, the others were within the recommended range. Both tomato and basil plants grown in the BC-incorporated mixes had a similar or higher growth index (GI), leaf greenness (indicated by soil-plant analyses development), and yield than the control. The leachate of all mixes had the highest NO3–N concentration in the first week after transplantation (1 WAT). All BC-incorporated mixes grown with both tomato and basil had similar NO3–N concentration to the control (except 50% SBB at 1 and 5 WAT, and 50% HB at 5 WAT with tomato plants; 50% SBB at 5 WAT with basil plants). In conclusion, HB could replace bark-based substrates at 50% and SBB at 70% for both tomato and basil plant growth, without negative effects.


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