Effect of density-driven flow on the through-diffusion experiment

2009 ◽  
Vol 106 (3-4) ◽  
pp. 166-172 ◽  
Author(s):  
Yusuke Kirino ◽  
Tadashi Yokoyama ◽  
Tetsuro Hirono ◽  
Takashi Nakajima ◽  
Satoru Nakashima
Keyword(s):  
Diffusion Experiment ◽  
Density Driven Flow ◽  
Through Diffusion

scholarly journals Measurement on Diffusion Coefficients and Isotope Fractionation Factors by a Through-Diffusion Experiment

Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 208
Author(s):  
Takuma Hasegawa ◽  
Kotaro Nakata ◽  
Rhys Gwynne
Keyword(s):  
Groundwater Flow ◽  
Diffusion Coefficients ◽  
Isotope Fractionation ◽  
Free Water ◽  
Effective Porosity ◽  
Diffusion Experiment ◽  
Fractionation Factor ◽  
Through Diffusion ◽  
Geological Formations ◽  
Fractionation Factors

For radioactive waste disposal, it is important that local groundwater flow is slow as groundwater flow is the main transport medium for radioactive nuclides in geological formations. When the groundwater flow is very slow, diffusion is the dominant transport mechanism (diffusion-dominant domain). Key pieces of evidence indicating a diffusion-dominant domain are the separation of components and the fractionation of isotopes by diffusion. To prove this, it is necessary to investigate the different diffusion coefficients for each component and the related stable isotope fractionation factors. Thus, in this study, through-diffusion and effective-porosity experiments were conducted on selected artificial materials and natural rocks. We also undertook measurements relating to the isotope fractionation factors of Cl and Br isotopes for natural samples. For natural rock samples, the diffusion coefficients of water isotopes (HDO and H218O) were three to four times higher than those of monovalent anions (Cl−, Br- and NO3−), and the isotope fractionation factor of 37Cl (1.0017–1.0021) was slightly higher than that of free water. It was experimentally confirmed that the isotope fractionation factor of 81Br was approximately 1.0007–1.0010, which is equivalent to that of free water. The enrichment factor of 81Br was almost half that of 37Cl. The effective porosity ratios of HDO and Cl were slightly different, but the difference was not significant compared to the ratio of their diffusion coefficients. As a result, component separation was dominated by diffusion. For artificial samples, the diffusion coefficients and effective porosities of HDO and Cl were almost the same; it was thus difficult to assess the component separation by diffusion. However, isotope fractionation of Cl and Br was confirmed using a through-diffusion experiment. The results show that HDO and Cl separation and isotope fractionation of Cl and Br can be expected in diffusion-dominant domains in geological formations.

REPRO: Through Diffusion Experiment (TDE) - Diffusion and Porosity Properties of Rock Matrix in Stress Field of Repository Level

2020 ◽  
Author(s):  
Kalle Rahkola ◽  
Antti Poteri ◽  
Lasse Koskinen ◽  
Peter Andersson ◽  
Kersti Nilsson ◽  
...  
Keyword(s):  
Stress Field ◽  
Performance Assessment ◽  
Spent Nuclear Fuel ◽  
Diffusion Experiment ◽  
Spent Fuel ◽  
Tracer Transport ◽  
Rock Matrix ◽  
Safety Case ◽  
Through Diffusion

<p>Radionuclides usually migrate slower than the flowing water due to sorption and matrix diffusion. The performance assessment assumes that retention takes place mostly in the vicinity of the deposition holes. REPRO (<em>REtention Properties of ROck matrix</em>) experiments analyzed the matrix retention properties of the rock matrix under realistic conditions deep in the bedrock in ONKALO underground characterization facility at Olkiluoto, Finland. The objective was to investigate tracer transport in the rock matrix, which was representative to the near-field of the final disposal repository of the spent nuclear fuel, and to demonstrate that the assumptions made in the safety case of the deep geological spent fuel repository were in line with site evidence.</p><p>REPRO is composed of several supporting laboratory and <em>in-situ</em> experiments which investigate the retention properties under different experimental configurations. The first <em>in-situ</em> experiments were water phase diffusion experiments performed 2012-2013. Through Diffusion Experiment (TDE) studies diffusion and porosity properties of rock matrix in stress field of repository level and sorption properties of nuclides in intact rock circumstances.</p><p>The TDE experiment has been performed in three parallel drillholes drilled near to each other. Breakthrough of the radioactive tracer is monitored with on-line measurements and samplings along and perpendicular to the foliation. The non-sorbing radioactive isotope traces of HTO and <sup>36</sup>Cl, as well as slightly sorbing <sup>22</sup>Na and strongly sorbing <sup>133</sup>Ba and <sup>134</sup>Cs were used. TDE was designed to control advective flow, as it had caused problems in previous <em>in-situ</em> tests.</p><p>Supporting laboratory studies were performed for drillcore samples sampled from the experimental drillholes. In these laboratory experiments, i.e. porosity, permeability and diffusion coefficients of the drillcores were determined using different methods.</p><p>The TDE experiment was carried out from 2016 to 2019. A breakthrough was seen in the timeframe predicted by scoping calculations carried out. REPRO has produced data and knowledge to the safety case and the performance assessment. According to the preliminary results, values measured in the laboratory are applicable also in larger scale and <em>in-situ</em> conditions.</p>

scholarly journals Comparison between in situ and laboratory diffusion studies of HTO and halides in Opalinus Clay from the Mont Terri

2004 ◽  
Vol 92 (9-11) ◽  
Author(s):  
Etienne Tevissen ◽  
J. M. Soler ◽  
P. Montarnal ◽  
A. Gautschi ◽  
Luc R. Van Loon
Keyword(s):  
Tritiated Water ◽  
Opalinus Clay ◽  
Diffusion Experiment ◽  
Diffusion Technique ◽  
Diffusion Studies ◽  
Through Diffusion ◽  
Mont Terri

SummaryA long-term single-borehole diffusion experiment (DI) using tritiated water (HTO) and stable iodide (All HTO results obtained with a through diffusion technique are within the same range as those obtained in the

A comparative study on sorption and diffusion of Cs in crushed argillite and granite investigated in batch and through-diffusion experiment

2016 ◽  
Vol 311 (2) ◽  
pp. 1155-1162
Author(s):  
Chuan-Pin Lee ◽  
Shih-Chin Tsai ◽  
Ming-Chee Wu ◽  
Tsuey-Lin Tsai ◽  
Yu-Lin Tu ◽  
...  
Keyword(s):  
Comparative Study ◽  
Diffusion Experiment ◽  
Through Diffusion ◽  
And Diffusion

scholarly journals Analysis of 3H, 36Cl, 133Ba, 134Cs and 22Na from synthetic granitic groundwater: an in situ through diffusion experiment at ONKALO

2018 ◽  
Vol 318 (2) ◽  
pp. 1161-1169 ◽  
Author(s):  
H. Aromaa ◽  
K. Helariutta ◽  
J. Ikonen ◽  
M. Yli-Kaila ◽  
L. Koskinen ◽  
...  
Keyword(s):  
Diffusion Experiment ◽  
Through Diffusion ◽  
Granitic Groundwater

Development of simplified biofilm sorption and diffusion experiment method using Bacillus sp. isolated from Horonobe Underground Research Laboratory

2014 ◽  
Vol 1665 ◽  
pp. 171-177
Author(s):  
Kotaro Ise ◽  
Tomofumi Sato ◽  
Yoshito Sasaki ◽  
Hideki Yoshikawa
Keyword(s):  
Bacillus Cereus ◽  
Diffusion Method ◽  
Cellulose Acetate Membrane ◽  
Diffusion Experiment ◽  
Biofilm Growth ◽  
Experiment Method ◽  
Measure Diffusion Coefficient ◽  
Through Diffusion ◽  
Underground Research Laboratory ◽  
And Diffusion

ABSTRACTWe developed a simplified biofilm sorption and diffusion experiment method. The biofilms of the Bacillus cereus were incubated on cellulose acetate membrane filters (pore size 0.2 µm, diameter 47 mm) placed on thick NB broth agar medium (thickness was about 30 mm) to support sufficient biofilm growth of the Bacillus cereus. The thickness of the formed biofilms was about 1 mm. The formed biofilms were applied to through-diffusion method, which has been used to measure diffusion coefficient of crystalline and sedimentary rocks and clay minerals. The obtained copper sorption coefficient by batch experiments was about 100 ml/g (wet weight) at the case of the concentration of cupper ion was over 0.074mmol/L. And diffusion coefficients by through diffusion experiment was De=1.1 x 10-10 (m2/s). From these results, this simplified biofilm sorption and diffusion experiment may make possible to obtain these parameters with ease.

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