Zinc acetate activation-enhanced performance of hollow nano silica/carbon composite nanofibers for lithium-sulfur batteries

2018 ◽  
Vol 823 ◽  
pp. 287-295 ◽  
Author(s):  
Jing Li ◽  
Ya Guo ◽  
Peng Wen ◽  
Jinghui Zhu ◽  
Zhonggui Liu ◽  
...  
2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Ning Kang ◽  
Yuxiao Lin ◽  
Li Yang ◽  
Dongping Lu ◽  
Jie Xiao ◽  
...  

Abstract While high sulfur loading has been pursued as a key parameter to build realistic high-energy lithium-sulfur batteries, less attention has been paid to the cathode porosity, which is much higher in sulfur/carbon composite cathodes than in traditional lithium-ion battery electrodes. For high-energy lithium-sulfur batteries, a dense electrode with low porosity is desired to minimize electrolyte intake, parasitic weight, and cost. Here we report the profound impact on the discharge polarization, reversible capacity, and cell cycling life of lithium-sulfur batteries by decreasing cathode porosities from 70 to 40%. According to the developed mechanism-based analytical model, we demonstrate that sulfur utilization is limited by the solubility of lithium-polysulfides and further conversion from lithium-polysulfides to Li2S is limited by the electronically accessible surface area of the carbon matrix. Finally, we predict an optimized cathode porosity to maximize the cell level volumetric energy density without sacrificing the sulfur utilization.


2014 ◽  
Vol 2 (12) ◽  
pp. 4316-4323 ◽  
Author(s):  
W. G. Wang ◽  
X. Wang ◽  
L. Y. Tian ◽  
Y. L. Wang ◽  
S. H. Ye

Sulfur–carbon composites were prepared by an in situ sulfur deposition route developed for the heterogeneous nucleation of sulfur into nanopores of conductive carbon black (CCB) by fumigation of Na2S4/CCB powder with HCl. The sulfur–carbon composites demonstrate enhanced reversible capacity and stable cycle performance.


RSC Advances ◽  
2015 ◽  
Vol 5 (117) ◽  
pp. 96862-96869 ◽  
Author(s):  
Zhijie Gong ◽  
Qixing Wu ◽  
Fang Wang ◽  
Xu Li ◽  
Xianping Fan ◽  
...  

Increasing the sulfur loading in the cathode of a lithium–sulfur battery is an important way to improve its capacity for practical applications.


2014 ◽  
Vol 137 ◽  
pp. 411-415 ◽  
Author(s):  
Long-Yan Li ◽  
Yan-Xiao Chen ◽  
Xiao-Dong Guo ◽  
Ben-He Zhong ◽  
Yan-Jun Zhong

2015 ◽  
Vol 19 (11) ◽  
pp. 3373-3379 ◽  
Author(s):  
LinYan Li ◽  
Xiaoyan Liu ◽  
Kunlei Zhu ◽  
Jianhua Tian ◽  
Xuesheng Liu ◽  
...  

2020 ◽  
Vol 8 (14) ◽  
pp. 6902-6907 ◽  
Author(s):  
Y. X. Ren ◽  
H. R. Jiang ◽  
C. Xiong ◽  
C. Zhao ◽  
T. S. Zhao

An in situ encapsulation strategy is adopted for protecting sulfur/carbon composite cathodes, extending the cycle life with a minor sacrifice in the rate capability.


APL Materials ◽  
2014 ◽  
Vol 2 (12) ◽  
pp. 124109 ◽  
Author(s):  
Renjie Chen ◽  
Teng Zhao ◽  
Tian Tian ◽  
Shuai Cao ◽  
Paul R. Coxon ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document