Electrochemical Behaviour of LiCl-KCl Eutectic Melts Containing Moisture as Impurity. Part II: Uranium Electrode

Absorption spectra of tetrahydro[3,2-b]indolo-carbazoles (THICZs) with various molecular size and alkyl tails have been recorded in various solvents in the range between 200 to 600 nm. The photo physical behaviour of dissolved THICZs depends on the nature of its environment. The solvatochromic behaviours of THICZs and solvent solute interactions can be analysed by means of linear solvation energy relationships concept proposed by Kamlet and Taft. Compound 4 show excellent properties for sensing small molecules. The electrochemical behaviour of some THICZs was investigated at carbon paste electrode where two electrode reactions were involved, irreversible oxidation-one electron transfer and quasi-reversible redox reactions forming phenolic followed by quinolone moiety electro active species. The DFT-calculated molecular orbital energies (B3LYP/6-31G) and HOMO-LUMO gaps for some presented indolocarbazoles have been performed.

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Electrochemical behaviour and ESR spectra of nitro substituted mono- and dibenzoylmethylenebenzthiazolines and selenazolines

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19791540 ◽

1979 ◽

Vol 44 (5) ◽

pp. 1540-1551 ◽

Cited By ~ 3

Author(s):

Jaro Komenda ◽

Jiří Huzlík

Keyword(s):

Electron Transfer ◽

Esr Spectroscopy ◽

Electrochemical Behaviour ◽

Spectroscopic Studies ◽

Esr Spectra ◽

Slow Electron

Compounds of the type of 2-(4'-nitrobenzoyl)methylene-3-ethylbenzothiazoline (I) and 2-bis-(p-nitrobenzoyl)methylene-3-ethylbenzothiazoline (II) were studied polarographically and by ESR spectroscopy to obtain informations about their electrochemical and follow-up reactions and their conformation. Whereas with compounds of the type I the conjugation in their molecules is preserved, with type II the coplanarity of the molecules is disturbed, which is manifested in the values of the splitting constants of the ESR spectra and a slow electron transfer between both nitrophenyl substituents. These conclusions are supported by NMR spectroscopic studies.

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Properties of electrochemically generated primary cationradicals of phenyl- and 2-(4-tolyl)-1,3,4,7-tetramethylisoindoles

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19801669 ◽

1980 ◽

Vol 45 (6) ◽

pp. 1669-1676 ◽

Cited By ~ 3

Author(s):

Pavel Kubáček

Keyword(s):

Electrochemical Oxidation ◽

Spin Polarization ◽

High Spin ◽

Epr Spectroscopy ◽

Half Life ◽

Electrochemical Behaviour ◽

Epr Spectra ◽

Electrochemical Generation ◽

Splitting Constant ◽

Reduced Temperature

The first step of electrochemical oxidation of 2-phenyl- and 2-(4-tolyl)-1,3,4,7-tetramethylisoindoles in anhydrous acetonitrile produces relatively stable cationradicals which have been studied by means of EPR spectroscopy using the method of internal electrochemical generation of radicals under reduced temperature. The same electrochemical behaviour of the both studied derivatives and identical EPR spectra of their cationradicals can be explained within the Huckel MO method. The largest contribution to the magnitude of splitting constant of nitrogen nucleus is due to π-σ-spin polarization of C-N bonds caused by high spin abundance of pz-AO of carbon atoms. Half-life of decomposition of the studied cationradicals is 4 min at -30°C.

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On the electroreduction mechanism of halobenzenes: Detection of intermediates in reduction of monohalobenzenes

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19890900 ◽

1989 ◽

Vol 54 (4) ◽

pp. 900-910 ◽

Cited By ~ 2

Author(s):

Juan Casado ◽

Iluminada Gallardo

Keyword(s):

Cyclic Voltammetry ◽

Electrochemical Behaviour ◽

Experimental Results ◽

Disk Electrode ◽

Rotating Ring Disk Electrode ◽

Mercury Cathode

Experimental results from electrochemical behaviour of halobenzenes in DMF at a mercury cathode are used to discuss alternative mechanisms of reduction. Intermediates of these mechanisms, such as phenyl anion, phenylmercury radical and phenylmercury cation have been detected at the electrode by using cyclic voltammetry and a rotating ring-disk electrode.

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Electrochemical behaviour of chromium–graphene composite coating

RSC Advances ◽

10.1039/c6ra06509k ◽

2016 ◽

Vol 6 (67) ◽

pp. 62083-62090 ◽

Cited By ~ 24

Author(s):

Rekha M. Y. ◽

M. K. Punith Kumar ◽

Chandan Srivastava

Keyword(s):

Composite Coating ◽

Zno Nanoparticles ◽

Electrochemical Behaviour ◽

Chromium Coating ◽

Corrosion Resistant ◽

Graphene Composite ◽

Pure Chromium

This work illustrates the role of graphene in enhancing the corrosion resistant properties of chromium–graphene composite coating when compared to the corrosion resistant properties of pure chromium coating containing ZnO nanoparticles.

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