Removal of biological effects of organic pollutants in municipal wastewater by a novel advanced oxidation system

2021 ◽  
Vol 280 ◽  
pp. 111855
Author(s):  
Yuhe He ◽  
Laura Patterson-Fortin ◽  
Jenny Boutros ◽  
Richard Smith ◽  
Greg G. Goss
Chemosphere ◽  
2021 ◽  
pp. 130482
Author(s):  
Sheng Guo ◽  
Mengdie Liu ◽  
Liming You ◽  
Gang Cheng ◽  
Jun Li ◽  
...  

Industrialization and modernization in recent times have led to a water crisis across the world. Conventional methods of water treatment like physical, chemical and biological methods which comprise of many commonly used techniques like membrane separation, adsorption, chemical treatment etc. have been in use for many decades. However, problems like sludge disposal, high operating costs etc. have led to increased focus on Advanced Oxidation Processes (AOPs) as alternative treatment methods. AOPs basically involve reactions relying on the high oxidation potential of the hydroxyl (OH•) free radical. They have the potential to efficiently treat various toxic, organic pollutants and complete degradation of contaminants (mineralization) of emerging concern. Many different types of homogenous as well as heterogenous AOPs have been studied viz: UV/H2O2, Fenton, Photo-Fenton, Sonolysis, Photocatalysis etc. for treatment of a wide variety of organic pollutants. Different AOPs are suitable for different types of wastewater and hence proper selection of the right technique for a particular type of pollutant is required. The inherent advantages offered by AOPs like elimination of sludge disposal problems, operability under mild conditions, ability to harness sunlight, non selective nature (ability to degrade all organic and microbial contamination) etc. have made it one of the most actively researched areas in recent times for wastewater treatment. Despite the benefits and intense research, commercial applicability of AOPs as a practical technique for treating wastewater on a large scale is still far from satisfactory. Nevertheless, positive results in lab scale and pilot plant studies make them a promising water treatment technique for the future. In the present chapter, an attempt has been made to discuss all aspects of AOPs beginning with the fundamental concepts, classification, underlying mechanism, comparison, commercialization to the latest developments in AOPs.


Industrialization and modernization in recent times have led to a water crisis across the world. Conventional methods of water treatment like physical, chemical and biological methods which comprise of many commonly used techniques like membrane separation, adsorption, chemical treatment etc. have been in use for many decades. However, problems like sludge disposal, high operating costs etc. have led to increased focus on Advanced Oxidation Processes (AOPs) as alternative treatment methods. AOPs basically involve reactions relying on the high oxidation potential of the hydroxyl (OH•) free radical. They have the potential to efficiently treat various toxic, organic pollutants and complete degradation of contaminants (mineralization) of emerging concern. Many different types of homogenous as well as heterogenous AOPs have been studied viz: UV/H2O2, Fenton, Photo-Fenton, Sonolysis, Photocatalysis etc. for treatment of a wide variety of organic pollutants. Different AOPs are suitable for different types of wastewater and hence proper selection of the right technique for a particular type of pollutant is required. The inherent advantages offered by AOPs like elimination of sludge disposal problems, operability under mild conditions, ability to harness sunlight, non selective nature (ability to degrade all organic and microbial contamination) etc. have made it one of the most actively researched areas in recent times for wastewater treatment. Despite the benefits and intense research, commercial applicability of AOPs as a practical technique for treating wastewater on a large scale is still far from satisfactory. Nevertheless, positive results in lab scale and pilot plant studies make them a promising water treatment technique for the future. In the present chapter, an attempt has been made to discuss all aspects of AOPs beginning with the fundamental concepts, classification, underlying mechanism, comparison, commercialization to the latest developments in AOPs.


Catalysts ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1299
Author(s):  
Donatos Manos ◽  
Kleopatra Miserli ◽  
Ioannis Konstantinou

Since environmental pollution by emerging organic contaminants is one of the most important problems, gaining ground year after year, the development of decontamination technologies of water systems is now imperative. Advanced oxidation processes (AOPs) with the formation of highly reactive radicals can provide attractive technologies for the degradation of organic pollutants in water systems. Among several AOPs that can be applied for the formation of active radicals, this review study focus on sulfate radical based-AOPs (SR-AOPs) through the heterogeneous catalytic activation of persulfate (PS) or peroxymonosulfate (PMS) using perovskite and spinel oxides as catalysts. Perovskites and spinels are currently receiving high attention and being used in substantial applications in the above research area. The widespread use of these materials is based mainly in the possibilities offered by their structure as it is possible to introduce into their structures different metal cations or to partially substitute them, without however destroying their structure. In this way a battery of catalysts with variable catalytic activities can be obtained. Due to the fact that Co ions have been reported to be one of the best activators of PMS, special emphasis has been placed on perovskite/spinel catalysts containing cobalt in their structure for the degradation of organic pollutants through heterogeneous catalysis. Among spinel materials, spinel ferrites (MFe2O4) are the most used catalysts for heterogeneous activation of PMS. Specifically, catalysts with cobalt ion in the A position were reported to be more efficient as PMS activators for the degradation of most organic pollutants compared with other transition metal catalysts. Substituted or immobilized catalysts show high rates of degradation, stability over a wider pH area and also address better the phenomena of secondary contamination by metal leaching, thus an effective method to upgrade catalytic performance.


1975 ◽  
Vol 189 (1096) ◽  
pp. 459-477 ◽  

The laboratory estimation of the toxic effects of organic pollutants relies on successive investigations of increasing sensitivity. Acute toxicity tests are useful in providing an index of relative toxicity between compounds but are of limited value for making ecological predictions. Many factors can influence the assessment of acute toxicity, with chemical stability of the test solutions and the species of test organisms employed being perhaps the most important of these. Many sub-lethal tests are also of limited value because the importance of the measured response for the well-being of the animal community as a whole is not established. The basic requirements of sub-lethal techniques are discussed, especially in relation to compounds which may exert their toxic action through accumulation in the tissues in the long term. The possibility of relating the toxicity of a compound to its chemical structure is considered.


Sign in / Sign up

Export Citation Format

Share Document