scholarly journals Influence of sulfate ion concentration and pH on the corrosion of Mg-Al-Zn-Mn (GA9) magnesium alloy

2015 ◽  
Vol 3 (3) ◽  
pp. 258-270 ◽  
Author(s):  
Sudarshana Shetty ◽  
Jagannath Nayak ◽  
A. Nityananda Shetty
2019 ◽  
Vol 14 (1) ◽  
Author(s):  
Ashok Kumar M ◽  
Thirumalaikumarasamy D ◽  
Paventhan R ◽  
Thirumal P

An investigation was carried out to quantify and characterize the corrosion behaviour of AZ31B magnesium alloy joints. Extruded Mg alloy plates of 6 mm thick of AZ31B grade were butt welded using a solid state, environmentally cleaner welding process, friction stir welding process. The weld specimens were underwent immersion, salt spray, pitting and galvanic corrosion tests in order to quantify and characterize the corrosion rates of the welds with the influence of different pH values, chloride ion concentration and the corrosion time. The corrosion rates, microstructure, scanning electron microscopy and X-ray diffraction analysis concludes the optimum parameter for the usage of the magnesium alloy welds for the best service applications. Keywords: Keywords: EDM, Alumina and Genetic Algorithm


2013 ◽  
Vol 742 ◽  
pp. 197-201
Author(s):  
Feng Lan Li ◽  
Li Yun Pan ◽  
Yan Wei Guo

The paper introduces the experiments of sulfate attack on concrete under stress state. The concrete (MSFAC) was made with machine-made sand and fly ash. Before immersed in sodium solution with sulfate-ion concentration of 50000mg/L, the concrete beams with 100mm×100mm ×400mm dimension were in flexural tensile stress at levels of 20%, 40% and 60% of flexural tensile strength by the special designed stress devices. The sulfate-ion content in different erosion depths of concrete was measured at attack age of 30, 90, 180, 270, 360, 540 and 720 days by the chemical titration method. The results show that the apparent damage such as rough surface and cement past peeling off became more serious with the increasing tensile stress level and the prolongation of attack age, while much more obvious crystallization of gypsum was in surface cracks, the sulfate-ion content in the first layer near surface did not reflect the real status of concrete affected by tensile stress levels. The sulfate-ion contents of inside layers increased basically with the attack age at stress levels lower than 60% of tensile strength of concrete. In conditions of the experiment, the sulfate-ion content reduced when the attack age was longer than 540 days at the stress level of 60%.


Sensors ◽  
2021 ◽  
Vol 21 (3) ◽  
pp. 954
Author(s):  
Liyun Ding ◽  
Panfeng Gong ◽  
Bing Xu ◽  
Qingjun Ding

A new optical fiber sensor based on the fluorescence lifetime was prepared for specific detection of sulfate ion concentration, where 1,1′-(anthracene-9,10-diylbis(methylene))bis(3-(dodecylcarbamoyl)pyridin-1-ium) acted as the sulfate fluorescent probe. The probe was immobilized in a porous cellulose acetate membrane to form the sensitive membrane by the immersion precipitation method, and polyethylene glycol 400 acted as a porogen. The sensing principle was proven, as a sulfate ion could form a complex with the probe through a hydrogen bond, which led to structural changes and fluorescence for the probe. The signals of the fluorescence lifetime data were collected by the lock-in amplifier and converted into the phase delay to realize the detection of sulfate ions. Based on the phase-modulated fluorometry, the relationship between the phase delay of the probe and the sulfate ion concentration was described in the range from 2 to 10 mM. The specificity and response time of this optical fiber sensor were also researched.


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