BaCeO3 has attracted great interest in research worldwide, whether doped with other elements on the site A and / or B of perovskite ABO3 or not, thus enabling its use in different applications. However, the properties exhibited by perovskite depend on partial or total replacement at the site, as well as the applied synthesis method. In this work we studied crystal structure, crystallographic parameters, morphology and textural properties of BaPrO3 perovskite synthesized by EDTA-Citrate complexation process. The adopted methodology makes it possible to obtain powders with orthorhombic crystal structure ( a=6.07 Å; b=6.3 Å e c=8.7 Å) and crystallite size of approximately 100 nm. That perovskite has dense and irregular agglomerates with surface area and pore volume of about 2.37 m2 g-1 and 0.7x10-8m3g-1, respectively. Finally, the methodology has demonstrated effectiveness in achieving crystalline phase with similar characteristics and properties obtained by different methods.