NMR characterization of the role of silane precursors on the catalytic activity of sol–gel encapsulated lipase

2006 ◽  
Vol 352 (32-35) ◽  
pp. 3469-3477 ◽  
Author(s):  
Cleide M.F. Soares ◽  
Onélia A.A. dos Santos ◽  
Heizir F. de Castro ◽  
Juliana E. Itako ◽  
Flavio F. de Moraes ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Sol Gel ◽  
Nmr Characterization

scholarly journals Evidence that the TRPV1 S1-S4 Membrane Domain Contributes to Thermosensing

2019 ◽  
Author(s):  
Minjoo Kim ◽  
Nicholas J. Sisco ◽  
Jacob K. Hilton ◽  
Camila M. Montano ◽  
Manuel A. Castro ◽  
...  
Keyword(s):  
Conformational Changes ◽  
Solution Nmr ◽  
Membrane Domain ◽  
Temperature Dependent ◽  
Nmr Characterization ◽  
Significant Interest ◽  
Pore Domain ◽  
Coupling Mechanisms

AbstractSensing and responding to temperature is crucial in biology. The TRPV1 ion channel is a well-studied heat-sensing receptor that is also activated by vanilloid compounds including capsaicin. Despite significant interest, the molecular underpinnings of thermosensing have remained elusive. The TRPV1 S1-S4 membrane domain couples chemical ligand binding to the pore domain during channel gating. However, the role of the S1-S4 domain in thermosensing is unclear. Evaluation of the isolated human TRPV1 S1-S4 domain by solution NMR, Far-UV CD, and intrinsic fluorescence shows that this domain undergoes a non-denaturing temperature-dependent transition with a high thermosensitivity. Further NMR characterization of the temperature-dependent conformational changes suggests the contribution of the S1-S4 domain to thermosensing shares features with known coupling mechanisms between this domain with ligand and pH activation. Taken together, this study shows that the TRPV1 S1-S4 domain contributes to TRPV1 temperature-dependent activation.

scholarly journals Role of annealing temperature on the sol–gel synthesis of VO2 nanowires with in situ characterization of their metal–insulator transition

RSC Advances ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 5158-5165 ◽  
Author(s):  
Y.-R. Jo ◽  
S.-H. Myeong ◽  
B.-J. Kim
Keyword(s):  
Sol Gel ◽  
Insulator Transition ◽  
In Situ Characterization ◽  
Metal Insulator Transition ◽  
Metal Insulator ◽  
Nanowire Device ◽  
Sol Gel Synthesis

The single-VO2 nanowire device synthesized via sequential morphological evolutions with oxygen reduction during annealing features a sharp metal-insulator transition.

How does the Support Influence the Catalytic Activity of the Keggin Ion?

1996 ◽  
Vol 454 ◽  
Author(s):  
Zakiyyah Smith ◽  
Michael Palmieri ◽  
Nancy Buecheler ◽  
Susan A. Jansen
Keyword(s):  
Catalytic Activity ◽  
Carbon Materials ◽  
Solid Acid ◽  
Sol Gel ◽  
Catalytic Performance ◽  
Heteropoly Acids ◽  
Keggin Ion ◽  
Oxide Substrates ◽  
Silica Matrices

AbstractHeteropoly acids, HPA are well known solid acid and oxidation catalysts that find application in hetergeneous and homogeneous reactions. In the former, surface area and stability problems are diminshed by supporting the HPA. Typical supports include oxide substrates and porous carbon materials. The HPA's show some instability on these supports however. In this work, we demonstrate that HPA encapsulated in sol-gel silica matrices show enhanced catalytic performance without compromising the catalytic activity of the HPA. In addition, the specific role of the support in the catalytic process is described as well.

Insights into the role of strontium in toluene catalytic combustion over La1-xSrxCoO3 perovskites catalysts

2022 ◽  
Author(s):  
Mo Liu ◽  
Xiaoli Yang ◽  
ZiMeng Tian ◽  
Huimin Wang ◽  
Liangtao Yin ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Catalytic Combustion ◽  
Sol Gel ◽  
Gel Method ◽  
Sol Gel Method ◽  
A Site

A series of LaCoO3 pervoskite catalysts substituted by Sr in A site (La1-xSrxCoO3) were prepared via a facile sol-gel method. The catalytic activity of these pervoskite catalysts for the deep...

Characterization of sulfated TiO2 prepared by the sol–gel method and its catalytic activity in the n-hexane isomerization reaction

2005 ◽  
Vol 225 (1) ◽  
pp. 39-46 ◽  
Author(s):  
Lúcia K. Noda ◽  
Rusiene M. de Almeida ◽  
Luiz Fernando D. Probst ◽  
Norberto S. Gonçalves
Keyword(s):  
Catalytic Activity ◽  
Sol Gel ◽  
Isomerization Reaction ◽  
Gel Method ◽  
Sol Gel Method ◽  
Sulfated Tio2

scholarly journals Correction: Role of annealing temperature on the sol–gel synthesis of VO2 nanowires with in situ characterization of their metal–insulator transition

RSC Advances ◽  
2018 ◽  
Vol 8 (56) ◽  
pp. 31984-31984
Author(s):  
Y.-R. Jo ◽  
S.-H. Myeong ◽  
B.-J. Kim
Keyword(s):  
Annealing Temperature ◽  
Sol Gel ◽  
Insulator Transition ◽  
In Situ Characterization ◽  
Metal Insulator Transition ◽  
Metal Insulator ◽  
Sol Gel Synthesis

Correction for ‘Role of annealing temperature on the sol–gel synthesis of VO2 nanowires with in situ characterization of their metal–insulator transition’ by Y.-R. Jo et al., RSC Adv., 2018, 8, 5158–5165.

Investigation of ZnO/CuO/Nanographene Platelets Composites Catalyst for the Degradation of Methylene Blue from Aqueous Solution

2016 ◽  
Vol 864 ◽  
pp. 117-122 ◽  
Author(s):  
Hesni Shabrany ◽  
Hendry Tju ◽  
Ardiansyah Taufik ◽  
Rosari Saleh
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Catalytic Activity ◽  
Visible Light ◽  
Sol Gel ◽  
Nitrogen Adsorption ◽  
Ultrasound Irradiation ◽  
X Ray Diffraction ◽  
X Ray

This paper discusses the catalytic activity of ZnO/CuO/nanographene platelets composites under visible light and ultrasound irradiation separately. The ZnO/CuO/nanographene platelets composites were synthesized using a sol-gel method. X-ray diffraction and nitrogen adsorption spectroscopy were employed to investigate the structural and surface area of the catalyst. The catalytic activity results showed that the presence of nanographene platelets in ZnO/CuO nanocomposites improved its efficiency in degrading methylene blue. A scavenger method was also used to understand the role of charged carriers and the active radical involved in the catalytic activity.

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