Preparation of organozirconium aromatic compounds in mixed aqueous-organic solvents: X-ray structures of [Cp2ZrCl(μ2-O′,O′′C-C6H5)], [(CpZr)3(μ2-O′,O′′C-C6H3Cl2)3(μ3-OH)(μ2-OH)3](Cl2C6H3COO)2, and [(CpZr)3(μ2-O′,O′′C-C6H4Cl)3(μ3-OH)(μ2-OH)3]Cl2·CH2Cl2

2009 ◽  
Vol 694 (21) ◽  
pp. 3444-3451 ◽  
Author(s):  
Jinling Li ◽  
Ziwei Gao ◽  
Li Han ◽  
Lingxiang Gao ◽  
Caiyun Zhang ◽  
...  
Keyword(s):  
Organic Solvents ◽  
Aromatic Compounds ◽  
X Ray

The Design of Organic Gelators Based on a Family of Bis-Ureas

1999 ◽  
Vol 604 ◽  
Author(s):  
Rosa E. Meléndez ◽  
Andrew J. Carn ◽  
Kazuki Sada ◽  
Andrew D. Hamilton
Keyword(s):  
Thermodynamic Properties ◽  
Organic Solvents ◽  
Organic Molecules ◽  
Materials Science ◽  
Crystallographic Data ◽  
Porous Solids ◽  
X Ray ◽  
Molecule Structure ◽  
Structure Activity ◽  
Potential Applications

AbstractThe use of organic molecules as gelators in certain organic solvents has been the target of recent research in materials science. The types of structures formed in the gel matrix have potential applications as porous solids that can be used as absorbents or in catalysis. We will present and discuss the organogelation properties of a family of bis-ureas. Studies presented will include a molecule structure activity relationship, thermodynamic properties, comparison to x-ray crystallographic data and potential functionalization of the gels formed by this class of compounds

Evaluation of Aspects Controlling Crystallization of Nitrofurantoin

2019 ◽  
Vol 800 ◽  
pp. 9-13
Author(s):  
Aija Trimdale ◽  
Agris Bērziņš
Keyword(s):  
Gibbs Energy ◽  
Quantum Chemical Calculations ◽  
Organic Solvents ◽  
Quantum Chemical ◽  
Polymer Additives ◽  
Factors Affecting ◽  
X Ray

Nitrofurantoin was crystallized from multiple mixtures of water and organic solvents with and without additives to try to find and identify factors affecting phase obtained in crystallization and provide possible information on crystallization control. Obtained crystals were identified with powder X-ray diffractometry. Crystallization control possibilities were evaluated by using polymer additives and crystallization additives, by also using quantum chemical calculations to investigate the association of nitrofurantoin and additive molecules and calculate Gibbs energy of association.

scholarly journals Investigation of the Effects of Various Organic Solvents on the PCBM Electron Transport Layer of Perovskite Solar Cells

Coatings ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 237
Author(s):  
Chih-Hung Tsai ◽  
Chia-Ming Lin ◽  
Cheng-Hao Kuei
Keyword(s):  
Surface Roughness ◽  
Solar Cells ◽  
Electron Transport ◽  
Organic Solvents ◽  
Electrochemical Impedance ◽  
Perovskite Solar Cells ◽  
Acid Methyl Ester ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
X Ray

In this study, four organic solvents including 1,2-dichlorobenzene (DCB), chlorobenzene (CB), methylbenzene (MB), and chloroform (CF) were used as solvents in the [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) electron transport layer (ETL) of perovskite solar cells (PSCs). This study observed the effects of various solvents on the surface morphology of the ETL by using an optical microscope (OM) and scanning electron microscope (SEM). The surface roughness, crystal structure, and surface element bonding of the ETL were observed using an atomic force microscope (AFM), X-ray diffractometer (XRD), and X-ray photoelectron spectroscope (XPS), respectively. The absorption spectrum of the perovskite layer was explored using an ultraviolet-visible (UV-Vis) spectrometer. The characteristics of the PSC device were analyzed in terms of its current density–voltage (J–V) curve, external quantum efficiency (EQE), and electrochemical impedance spectroscopy (EIS) measurements. The results showed that DCB is a solvent with a high boiling point, low vapor pressure, and high dielectric constant, and using DCB as the solvent for ETL, the uniformity, coverage, and surface roughness of the ETL showed better properties. The power conversion efficiency of the PSC in which DCB was used as the solvent achieved a value of 11.07%, which was higher than that of the PSCs in which other solvents were used.

scholarly journals Preparation of Nanoparticles Including Antisolvent Drugs by the Combination of Roll Milling and High-pressure Homogenization

2018 ◽  
Vol 14 (2) ◽  
pp. 143-147 ◽  
Author(s):  
Seitaro Kamiya ◽  
Maya Yamada ◽  
Miki Washino ◽  
Kenichiro Nakashima
Keyword(s):  
Particle Size ◽  
High Pressure ◽  
Organic Solvent ◽  
Organic Solvents ◽  
Peak Shift ◽  
Diffraction Peak ◽  
High Pressure Homogenization ◽  
X Ray Diffraction ◽  
X Ray ◽  
Wet Process

Description: Design methods of nanoparticle formulations are divided into break-down methods and build-up methods. The former is further divided into dry and wet processes. For drug nanoparticle preparations, the wet process is generally employed, and organic solvents are used in most formulations. Method: In this study, we investigate the preparation of nifedipine (IB) and griseofulvin (GF) nanoparticles without using organic solvent. Both IB and GF nanoparticles, with a mean particle size of approximately 50 nm, were prepared without organic solvent by employing a combination of roll milling and high-pressure homogenization. Result: The X-ray diffraction peak of the IB and GF samples prepared by roll milling was present at a position (2θ) identical to that of IB and GF crystals, indicating that no peak shift was induced by interaction with phospholipids. Conclusion: These findings demonstrate that most IB and GF nanoparticles exist as crystals in phospholipids.

Feasibility Study of the Properties of Clay Chocobofe Removal of Lead in Synthetic Wastewater

2014 ◽  
Vol 805 ◽  
pp. 284-290
Author(s):  
José Vanderley do Nascimento Silva ◽  
Guilherme Costa de Oliveira ◽  
Meiry Gláucia Freire Rodrigues
Keyword(s):  
Adsorption Capacity ◽  
Organic Solvents ◽  
Adsorption Process ◽  
Exchange Capacity ◽  
Synthetic Wastewater ◽  
Natural Clay ◽  
X Ray Diffraction ◽  
Solution Ph ◽  
Natural Form ◽  
X Ray

As minimization process control pollution by heavy metals, adsorption can play an important environmental role. Therefore, many adsorbents can be used as effective alternatives. This work presents a study that aims to evaluate the removal of lead in liquid effluent through adsorption process using a finite bath system and with the adsorbent clay Chocobofe. The clay in its natural form was characterized by the techniques of X-Ray Diffraction (XRD), Cation Exchange Capacity (CEC), Chemical Analysis by X-Ray Spectrometry by Energy Dispersive (EDX), moreover, the natural clay was subjected to test adsorption capacity to analyze the behavior the same in certain organic solvents. Was performed to assess the effectiveness of the natural clay in the process of removal of Pb2+ present in solutions based on a factorial design 23 + 3 replicates at the central point, with the analysis variables solution pH (3.0, 4.0 and 5.0) and the initial concentration of lead (10, 30 and 50 ppm). The studies showed this material as promising in the removal of Pb2+ ions in synthetic wastewater and that the adsorption capacity showed that the organic solvents tested.

Solvation dependence of valence electronic states of water diluted in organic solvents probed by soft X-ray spectroscopy

2014 ◽  
Vol 16 (22) ◽  
pp. 10753-10761 ◽  
Author(s):  
Takashi Tokushima ◽  
Yuka Horikawa ◽  
Osamu Takahashi ◽  
Hidemi Arai ◽  
Koichiro Sadakane ◽  
...  
Keyword(s):  
Organic Solvents ◽  
Emission Spectroscopy ◽  
Electronic States ◽  
Absorption And Emission ◽  
X Ray ◽  
Organic Solutions ◽  
X Ray Absorption ◽  
Absorption And Emission Spectroscopy

The variety of occupied and unoccupied valence electronic states of water in organic solutions detected by X-ray absorption and emission spectroscopy.

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